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• 1. [Article] Close-Spaced Vapor Transport and Photoelectrochemistry of Gallium Arsenide for Photovoltaic Applications

  The high balance-of-system costs of photovoltaic installations indicate that reductions in absorber cost alone are likely insufficient for photovoltaic electricity to reach grid parity unless energy conversion ...

  Citation × Citation Citation Abstract Copy Title: Close-Spaced Vapor Transport and Photoelectrochemistry of Gallium Arsenide for Photovoltaic Applications Author: Ritenour, Andrew Year: 2015 The high balance-of-system costs of photovoltaic installations indicate that reductions in absorber cost alone are likely insufficient for photovoltaic electricity to reach grid parity unless energy conversion efficiency is also increased. Technologies which both yield high-efficiency cells (>25%) and maintain low costs are needed. GaAs and related III-V semiconductors are used in the highest-efficiency single- and multi-junction photovoltaics, but the technology is too expensive for non-concentrated terrestrial applications. This is due in part to the limited scalability of traditional syntheses, which rely on expensive reactors and employ toxic and pyrophoric gas-phase precursors such as arsine and trimethyl gallium. This work describes GaAs films made by close-spaced vapor transport, a potentially scalable technique which is carried out at atmospheric pressure and requires only bulk GaAs, water vapor, and a temperature gradient to deposit crystalline films with similar electronic properties to GaAs prepared using traditional syntheses. Although close-spaced vapor transport of GaAs was first developed in 1963, there were few examples of GaAs photovoltaic devices made using this method in the literature at the onset of this project. Furthermore, it was unclear whether close-spaced vapor transport could produce GaAs films appropriate for use in photovoltaics. The goal of this project was to create and study GaAs devices made using close-spaced vapor transport and determine whether the technique could be used for production of grid-connected GaAs photovoltaics. In Chapter I the design of the vapor transport reactor, the chemistry of crystal growth, and optoelectronic characterization techniques are discussed. Chapter II focuses on compositional measurements, doping, and improved electronic quality in CSVT GaAs. Chapter III describes several aspects of the interplay between structure and electronic properties of photoelectrochemical devices. Chapter IV addresses heteroepitaxial growth of GaAs on "virtual" Ge-on-Si substrates. This is a topic of importance for the broader III-V community as well as the photovoltaic community, as Si is the substrate of choice in many areas of industry. This dissertation includes unpublished and previously published co-authored material. Title: Close-Spaced Vapor Transport and Photoelectrochemistry of Gallium Arsenide for Photovoltaic Applications Author: Ritenour, Andrew Year: 2015 The high balance-of-system costs of photovoltaic installations indicate that reductions in absorber cost alone are likely insufficient for photovoltaic electricity to reach grid parity unless energy conversion efficiency is also increased. Technologies which both yield high-efficiency cells (>25%) and maintain low costs are needed. GaAs and related III-V semiconductors are used in the highest-efficiency single- and multi-junction photovoltaics, but the technology is too expensive for non-concentrated terrestrial applications. This is due in part to the limited scalability of traditional syntheses, which rely on expensive reactors and employ toxic and pyrophoric gas-phase precursors such as arsine and trimethyl gallium. This work describes GaAs films made by close-spaced vapor transport, a potentially scalable technique which is carried out at atmospheric pressure and requires only bulk GaAs, water vapor, and a temperature gradient to deposit crystalline films with similar electronic properties to GaAs prepared using traditional syntheses. Although close-spaced vapor transport of GaAs was first developed in 1963, there were few examples of GaAs photovoltaic devices made using this method in the literature at the onset of this project. Furthermore, it was unclear whether close-spaced vapor transport could produce GaAs films appropriate for use in photovoltaics. The goal of this project was to create and study GaAs devices made using close-spaced vapor transport and determine whether the technique could be used for production of grid-connected GaAs photovoltaics. In Chapter I the design of the vapor transport reactor, the chemistry of crystal growth, and optoelectronic characterization techniques are discussed. Chapter II focuses on compositional measurements, doping, and improved electronic quality in CSVT GaAs. Chapter III describes several aspects of the interplay between structure and electronic properties of photoelectrochemical devices. Chapter IV addresses heteroepitaxial growth of GaAs on "virtual" Ge-on-Si substrates. This is a topic of importance for the broader III-V community as well as the photovoltaic community, as Si is the substrate of choice in many areas of industry. This dissertation includes unpublished and previously published co-authored material. Close

• 2. [Article] Essays on Economic Development and Climate Change

  The first essay considers the relative effectiveness of government and non-governmental organizations (NGOs) as channels to allocate resources. I use a catastrophic climate-related shock--Hurricane Mitch--to ...

  Citation × Citation Citation Abstract Copy Title: Essays on Economic Development and Climate Change Author: Fitch-Fleischmann, Benjamin Year: 2015 The first essay considers the relative effectiveness of government and non-governmental organizations (NGOs) as channels to allocate resources. I use a catastrophic climate-related shock--Hurricane Mitch--to examine the political economy of these channels of aid distribution at the micro level. I combine extensive data on aid received by Nicaraguan households with data on municipal election outcomes and an exogenous, precipitation-based measure of hurricane impact. I find that the hurricane had long-lasting effects on the aid received by households from both NGOs and the government. In the short term, however, the government did not provide aid according to the objective measure of hurricane damage but instead provided aid along political lines. The second essay presents estimates of a relationship between extreme hot temperatures during gestation and a child's subsequent physical well-being in a sample of children in Peru, thus extending existing evidence constructed from U.S. data. Estimates are constructed using high-resolution gridded climate data and geo-coded household surveys. The results suggest that a period of extreme heat (a month whose average temperature is more than 2 standard deviations above the local average) in the period 1 to 3 months before birth is associated with lower weight at birth and a reduction in height (measured 1 to 59 months after birth) that cannot be fully explained by birth weight. There is no evidence of differential maternal investment, as measured by duration of breastfeeding, according to a child's exposure to extreme heat during gestation. The third essay asks whether improved treatment of HIV/AIDS in Africa can be achieved simply by paying health workers to do more. I present estimates of the impact of financial incentives paid to individual workers at public health facilities in Mozambique. The results suggest that piece-rate incentives increased the delivery of five out of fourteen health services for which treatment effects can be identified, with estimated increases ranging from 34 to 157 percent, depending on the particular service. I find no evidence of a corresponding decrease in the delivery of services that are not financially incentivized, suggesting that there is no "crowding out" of intrinsic motivation. Title: Essays on Economic Development and Climate Change Author: Fitch-Fleischmann, Benjamin Year: 2015 The first essay considers the relative effectiveness of government and non-governmental organizations (NGOs) as channels to allocate resources. I use a catastrophic climate-related shock--Hurricane Mitch--to examine the political economy of these channels of aid distribution at the micro level. I combine extensive data on aid received by Nicaraguan households with data on municipal election outcomes and an exogenous, precipitation-based measure of hurricane impact. I find that the hurricane had long-lasting effects on the aid received by households from both NGOs and the government. In the short term, however, the government did not provide aid according to the objective measure of hurricane damage but instead provided aid along political lines. The second essay presents estimates of a relationship between extreme hot temperatures during gestation and a child's subsequent physical well-being in a sample of children in Peru, thus extending existing evidence constructed from U.S. data. Estimates are constructed using high-resolution gridded climate data and geo-coded household surveys. The results suggest that a period of extreme heat (a month whose average temperature is more than 2 standard deviations above the local average) in the period 1 to 3 months before birth is associated with lower weight at birth and a reduction in height (measured 1 to 59 months after birth) that cannot be fully explained by birth weight. There is no evidence of differential maternal investment, as measured by duration of breastfeeding, according to a child's exposure to extreme heat during gestation. The third essay asks whether improved treatment of HIV/AIDS in Africa can be achieved simply by paying health workers to do more. I present estimates of the impact of financial incentives paid to individual workers at public health facilities in Mozambique. The results suggest that piece-rate incentives increased the delivery of five out of fourteen health services for which treatment effects can be identified, with estimated increases ranging from 34 to 157 percent, depending on the particular service. I find no evidence of a corresponding decrease in the delivery of services that are not financially incentivized, suggesting that there is no "crowding out" of intrinsic motivation. Close

• 3. [Article] Modeling the Effects of Geologic Heterogeneity and Metamorphic Dehydration on Slow Slip and Shallow Deformation in Subduction Zones

  Slow slip and tectonic tremor in subduction zones take place at depths (~20 - 50 km) where there is abundant evidence for distributed shear over broad zones (~10 - 10^3 m) composed of rocks with marked ...

  Citation × Citation Citation Abstract Copy Title: Modeling the Effects of Geologic Heterogeneity and Metamorphic Dehydration on Slow Slip and Shallow Deformation in Subduction Zones Author: Skarbek, Robert Year: 2015 Slow slip and tectonic tremor in subduction zones take place at depths (~20 - 50 km) where there is abundant evidence for distributed shear over broad zones (~10 - 10^3 m) composed of rocks with marked differences in mechanical properties and for near lithostatic pore pressures along the plate interface where the main source of fluids must be attributed to chemical dehydration reactions. In Chapter II, I model quasi-dynamic rupture along faults composed of material mixtures characterized by different rate-and-state-dependent frictional properties to determine the parameter regime capable of producing slow slip in an idealized subduction zone setting. Keeping other parameters fixed, the relative proportions of velocity-weakening (VW) and velocity-strengthening (VS) materials control the sliding character (stable, slow, or dynamic) along the fault. The stability boundary between slow and dynamic is accurately described by linear analysis of a double spring-slider system with VW and VS blocks. In Chapter III, I model viscoelastic compaction of material subducting through the slow slip and tremor zone in the presence of pressure and temperature-dependent dehydration reactions. A dehydration fluid source is included using 1) a generalized basalt dehydration reaction in subducting oceanic crust or 2) a general nonlinear kinetic reaction rate law parameterized for an antigorite dehydration reaction. Pore pressures in excess of lithostatic values are a robust feature of simulations that employ parameters consistent with the geometry of the Cascadia subduction margin. Simulations that include viscous deformation uniformly generate traveling porosity waves that transport increased fluid pressures within the slow slip region. Slow slip and tremor also occur in shallow (< 10 km depth) accretionary prism sections of subduction zones. In Chapter IV, I examine how geologic heterogeneities affect the mechanics of accretionary prisms in subduction zones by showing how spatial variations in pore pressure, porosity, and internal friction coefficient affect predictions of basal shear stress, taper angle, and internal slip surface geometry. My results suggest that assuming average porosity throughout the prism may be a good approximation in many cases, but assuming an average value for the pore pressure can cause significant errors. This dissertation includes previously published and unpublished coauthored material. Title: Modeling the Effects of Geologic Heterogeneity and Metamorphic Dehydration on Slow Slip and Shallow Deformation in Subduction Zones Author: Skarbek, Robert Year: 2015 Slow slip and tectonic tremor in subduction zones take place at depths (~20 - 50 km) where there is abundant evidence for distributed shear over broad zones (~10 - 10^3 m) composed of rocks with marked differences in mechanical properties and for near lithostatic pore pressures along the plate interface where the main source of fluids must be attributed to chemical dehydration reactions. In Chapter II, I model quasi-dynamic rupture along faults composed of material mixtures characterized by different rate-and-state-dependent frictional properties to determine the parameter regime capable of producing slow slip in an idealized subduction zone setting. Keeping other parameters fixed, the relative proportions of velocity-weakening (VW) and velocity-strengthening (VS) materials control the sliding character (stable, slow, or dynamic) along the fault. The stability boundary between slow and dynamic is accurately described by linear analysis of a double spring-slider system with VW and VS blocks. In Chapter III, I model viscoelastic compaction of material subducting through the slow slip and tremor zone in the presence of pressure and temperature-dependent dehydration reactions. A dehydration fluid source is included using 1) a generalized basalt dehydration reaction in subducting oceanic crust or 2) a general nonlinear kinetic reaction rate law parameterized for an antigorite dehydration reaction. Pore pressures in excess of lithostatic values are a robust feature of simulations that employ parameters consistent with the geometry of the Cascadia subduction margin. Simulations that include viscous deformation uniformly generate traveling porosity waves that transport increased fluid pressures within the slow slip region. Slow slip and tremor also occur in shallow (< 10 km depth) accretionary prism sections of subduction zones. In Chapter IV, I examine how geologic heterogeneities affect the mechanics of accretionary prisms in subduction zones by showing how spatial variations in pore pressure, porosity, and internal friction coefficient affect predictions of basal shear stress, taper angle, and internal slip surface geometry. My results suggest that assuming average porosity throughout the prism may be a good approximation in many cases, but assuming an average value for the pore pressure can cause significant errors. This dissertation includes previously published and unpublished coauthored material. Close

• 4. [Article] Optomechanical Light Storage and Related Transient Optomechanical Phenomena

  An optomechanical system consists of an optical cavity coupled to a mechanical oscillator. The system used for this work was a silica microsphere. In a silica microsphere, the optical cavity is formed ...

  Citation × Citation Citation Abstract Copy Title: Optomechanical Light Storage and Related Transient Optomechanical Phenomena Author: Fiore, Victor Year: 2015 An optomechanical system consists of an optical cavity coupled to a mechanical oscillator. The system used for this work was a silica microsphere. In a silica microsphere, the optical cavity is formed by light that is confined by total internal reflection while circulating around the equator of the sphere. The mechanical oscillator is the mechanical breathing motion of the sphere itself. The optical cavity and mechanical oscillator are coupled by radiation pressure and by the mechanical oscillator physically changing the length of the optical cavity. The optomechanical analog to electromagnetically induced transparency (EIT), known as optomechanically induced transparency (OMIT), has previously been studied in its steady state. One topic of this dissertation is an experimental study of OMIT in the time domain. The results of these experimental demonstrations continue comparisons between EIT and OMIT, while also building a foundation for optomechanical light storage. In OMIT, an off-resonance control laser controls the interaction between on-resonance light and the mechanical oscillator. Optomechanical light storage makes use of this arrangement to store an optical signal as a mechanical excitation, which is then retrieved at a later time as an optical signal. This is done by using two temporally separated off-resonance control laser pulses. This technique is extremely flexible in frequency and displays a storage lifetime on the order of microseconds. Use of optomechanical systems for quantum mechanical applications is hindered by the thermal background noise of the mechanical oscillator. Addressing this issue by first cooling the mechanical oscillator is costly and fraught with difficulties. The final topic presented in this dissertation deals with this issue through the use of an optomechanical dark mode. Two optical modes can interact with the same mechanical mode. The dark mode is a state that couples the two optical modes but is decoupled from the mechanical oscillator. While our specific optomechanical system is limited by its somewhat modest optomechanical cooperativity, this conversion process can, in principle, preserve the quantum state of the signal, even at room temperature, opening the possibility for this technique to be applied in quantum information processing. Title: Optomechanical Light Storage and Related Transient Optomechanical Phenomena Author: Fiore, Victor Year: 2015 An optomechanical system consists of an optical cavity coupled to a mechanical oscillator. The system used for this work was a silica microsphere. In a silica microsphere, the optical cavity is formed by light that is confined by total internal reflection while circulating around the equator of the sphere. The mechanical oscillator is the mechanical breathing motion of the sphere itself. The optical cavity and mechanical oscillator are coupled by radiation pressure and by the mechanical oscillator physically changing the length of the optical cavity. The optomechanical analog to electromagnetically induced transparency (EIT), known as optomechanically induced transparency (OMIT), has previously been studied in its steady state. One topic of this dissertation is an experimental study of OMIT in the time domain. The results of these experimental demonstrations continue comparisons between EIT and OMIT, while also building a foundation for optomechanical light storage. In OMIT, an off-resonance control laser controls the interaction between on-resonance light and the mechanical oscillator. Optomechanical light storage makes use of this arrangement to store an optical signal as a mechanical excitation, which is then retrieved at a later time as an optical signal. This is done by using two temporally separated off-resonance control laser pulses. This technique is extremely flexible in frequency and displays a storage lifetime on the order of microseconds. Use of optomechanical systems for quantum mechanical applications is hindered by the thermal background noise of the mechanical oscillator. Addressing this issue by first cooling the mechanical oscillator is costly and fraught with difficulties. The final topic presented in this dissertation deals with this issue through the use of an optomechanical dark mode. Two optical modes can interact with the same mechanical mode. The dark mode is a state that couples the two optical modes but is decoupled from the mechanical oscillator. While our specific optomechanical system is limited by its somewhat modest optomechanical cooperativity, this conversion process can, in principle, preserve the quantum state of the signal, even at room temperature, opening the possibility for this technique to be applied in quantum information processing. Close

• 5. [Article] Comprehensive examination of the differences in thermoregulatory and ventilatory responses between humans with and without a PFO under different environmental conditions

  The existence of a patent foramen ovale (PFO) has been known about for nearly 2,000 years. The prevalence of a PFO has been shown to be 25-40% in the general population. Despite the fact that blood flowing ...

  Citation × Citation Citation Abstract Copy Title: Comprehensive examination of the differences in thermoregulatory and ventilatory responses between humans with and without a PFO under different environmental conditions Author: Davis, James Year: 2016 The existence of a patent foramen ovale (PFO) has been known about for nearly 2,000 years. The prevalence of a PFO has been shown to be 25-40% in the general population. Despite the fact that blood flowing through a PFO acts as a shunt, there has been little research looking at the effect a PFO has on physiology in otherwise healthy humans. In Chapter IV, the effect of a PFO on core temperature (Tcore) prior to, and during exercise, was investigated. The design of this experiment included appropriate controls for a thermoregulatory study (i.e. measuring at same time of day, appropriate hydration and food intake, etc.). Results from this study indicate that subjects with a PFO (PFO+) have a Tcore that is ~0.4°C higher at rest and during exercise than subjects without a PFO (PFO–). Additionally, this study showed that PFO– subjects do not increase Tcore to the same extent breathing cold air as they do breathing ambient air during a 10-minute exercise bout, whereas there was no difference in Tcore increase between these two conditions for PFO+ subjects. These findings suggest that the difference in Tcore between PFO+ and PFO– subjects is potentially due to differences in respiratory heat loss. The studies for Chapter V examined differences in thermoregulatory and ventilatory responses during hot water (40°C) and cold water (20°C) immersion. This study found that compared to PFO– subjects, PFO+ subjects 1) increase Tcore at the same rate during hot water immersion and 2) do not cool off as quickly during cold water immersion. Additionally, in subjects who reached a ventilatory threshold, PFO+ subjects had blunted ventilatory responses to increased Tcore compared to PFO– subjects. Finally, in Chapter VI it was shown that PFO+ subjects have blunted ventilatory responses during acute exposure to hyperoxic and normoxic hypercapnia. However, there were no differences in ventilatory responses between PFO+ and PFO– subjects during exposure to either isocapnic or poikilocapnic hypoxia. These findings suggest that PFO+ subjects have a blunted central chemoreflex. This dissertation contains previously, unpublished co-authored material. Title: Comprehensive examination of the differences in thermoregulatory and ventilatory responses between humans with and without a PFO under different environmental conditions Author: Davis, James Year: 2016 The existence of a patent foramen ovale (PFO) has been known about for nearly 2,000 years. The prevalence of a PFO has been shown to be 25-40% in the general population. Despite the fact that blood flowing through a PFO acts as a shunt, there has been little research looking at the effect a PFO has on physiology in otherwise healthy humans. In Chapter IV, the effect of a PFO on core temperature (Tcore) prior to, and during exercise, was investigated. The design of this experiment included appropriate controls for a thermoregulatory study (i.e. measuring at same time of day, appropriate hydration and food intake, etc.). Results from this study indicate that subjects with a PFO (PFO+) have a Tcore that is ~0.4°C higher at rest and during exercise than subjects without a PFO (PFO–). Additionally, this study showed that PFO– subjects do not increase Tcore to the same extent breathing cold air as they do breathing ambient air during a 10-minute exercise bout, whereas there was no difference in Tcore increase between these two conditions for PFO+ subjects. These findings suggest that the difference in Tcore between PFO+ and PFO– subjects is potentially due to differences in respiratory heat loss. The studies for Chapter V examined differences in thermoregulatory and ventilatory responses during hot water (40°C) and cold water (20°C) immersion. This study found that compared to PFO– subjects, PFO+ subjects 1) increase Tcore at the same rate during hot water immersion and 2) do not cool off as quickly during cold water immersion. Additionally, in subjects who reached a ventilatory threshold, PFO+ subjects had blunted ventilatory responses to increased Tcore compared to PFO– subjects. Finally, in Chapter VI it was shown that PFO+ subjects have blunted ventilatory responses during acute exposure to hyperoxic and normoxic hypercapnia. However, there were no differences in ventilatory responses between PFO+ and PFO– subjects during exposure to either isocapnic or poikilocapnic hypoxia. These findings suggest that PFO+ subjects have a blunted central chemoreflex. This dissertation contains previously, unpublished co-authored material. Close

• 6. [Article] Community assembly of benthic invertebrates on island-like marine hard substrata

  Most of the seafloor is soft sediment, so hard substrata are isolated and island-like. In this dissertation, I explore how species distribution patterns on isolated marine hard substrata resemble terrestrial ...

  Citation × Citation Citation Abstract Copy Title: Community assembly of benthic invertebrates on island-like marine hard substrata Author: Meyer, Kirstin Year: 2016 Most of the seafloor is soft sediment, so hard substrata are isolated and island-like. In this dissertation, I explore how species distribution patterns on isolated marine hard substrata resemble terrestrial island communities, drawing on classical island biogeography theory and assembly rules, and describe how benthic invertebrate communities assemble in these island-like habitats. Higher species richness occurred on larger substrata (dropstones and shipwrecks), paralleling terrestrial island communities. However, while larger islands have greater habitat diversity and primary productivity, marine hard substrata are simpler habitats. Greater elevation in the benthic boundary layer may expose fauna to faster current, higher food supply and larval flux. Substrata located closer together had more similar communities, another pattern that resembles terrestrial islands. Dropstone fauna had a clumped distribution, indicating that larvae may disperse among substrata located close together, resulting in similar communities. In Svalbard fjords, benthic megafaunal communities were significantly different between Arctic- and Atlantic-influenced fjords. Depth and temperature had the greatest influence, with the highest diversity occurring in cold Rijpfjorden and on the north Svalbard shelf. Recruitment in Svalbard fjords was spatially and temporally variable, with lower recruitment in Rijpfjorden than in Atlantic-influenced fjords and lower recruitment at greater depth. Most of the recruits in Svalbard fjords were fast-growing, poor-competitive opportunists. On shipwrecks, communities showed two mechanisms of colonization: mobile fauna with long-dispersing planktotrophic larvae, and encrusting fauna with lecithotrophic larvae. Encrusting species reproduce asexually to cover the wreck surface, and philopatry may build up dense populations, leading to uneven communities. On terrestrial islands, non-random co-occurrence is attributed to interspecific competition, but for marine substrata, there may not be a relationship. Fauna were distributed randomly on settlement plates in Svalbard fjords, even when interspecific competition was observed. On dropstones, some morphotypes co-occurred non-randomly in the absence of overgrowth competition. Non-random co-occurrence on isolated marine hard substrata may be a result of restricted larval dispersal (for pairs co-occurring less than by chance) or epibiontism (for pairs co-occurring more often than by chance). While species distribution patterns on island-like marine hard substrata resemble terrestrial islands, the mechanisms are not necessarily the same. Title: Community assembly of benthic invertebrates on island-like marine hard substrata Author: Meyer, Kirstin Year: 2016 Most of the seafloor is soft sediment, so hard substrata are isolated and island-like. In this dissertation, I explore how species distribution patterns on isolated marine hard substrata resemble terrestrial island communities, drawing on classical island biogeography theory and assembly rules, and describe how benthic invertebrate communities assemble in these island-like habitats. Higher species richness occurred on larger substrata (dropstones and shipwrecks), paralleling terrestrial island communities. However, while larger islands have greater habitat diversity and primary productivity, marine hard substrata are simpler habitats. Greater elevation in the benthic boundary layer may expose fauna to faster current, higher food supply and larval flux. Substrata located closer together had more similar communities, another pattern that resembles terrestrial islands. Dropstone fauna had a clumped distribution, indicating that larvae may disperse among substrata located close together, resulting in similar communities. In Svalbard fjords, benthic megafaunal communities were significantly different between Arctic- and Atlantic-influenced fjords. Depth and temperature had the greatest influence, with the highest diversity occurring in cold Rijpfjorden and on the north Svalbard shelf. Recruitment in Svalbard fjords was spatially and temporally variable, with lower recruitment in Rijpfjorden than in Atlantic-influenced fjords and lower recruitment at greater depth. Most of the recruits in Svalbard fjords were fast-growing, poor-competitive opportunists. On shipwrecks, communities showed two mechanisms of colonization: mobile fauna with long-dispersing planktotrophic larvae, and encrusting fauna with lecithotrophic larvae. Encrusting species reproduce asexually to cover the wreck surface, and philopatry may build up dense populations, leading to uneven communities. On terrestrial islands, non-random co-occurrence is attributed to interspecific competition, but for marine substrata, there may not be a relationship. Fauna were distributed randomly on settlement plates in Svalbard fjords, even when interspecific competition was observed. On dropstones, some morphotypes co-occurred non-randomly in the absence of overgrowth competition. Non-random co-occurrence on isolated marine hard substrata may be a result of restricted larval dispersal (for pairs co-occurring less than by chance) or epibiontism (for pairs co-occurring more often than by chance). While species distribution patterns on island-like marine hard substrata resemble terrestrial islands, the mechanisms are not necessarily the same. Close

• 7. [Article] Emergent thermodynamics in a system of macroscopic, chaotic surface waves

  The properties of conventional materials are inextricably linked with their molecular composition; to make water flow like wine would require changing its molecular identity. To circumvent this restriction, ...

  Citation × Citation Citation Abstract Copy Title: Emergent thermodynamics in a system of macroscopic, chaotic surface waves Author: Welch, Kyle Year: 2016 The properties of conventional materials are inextricably linked with their molecular composition; to make water flow like wine would require changing its molecular identity. To circumvent this restriction, I have contstructed and characterized a two-dimensional metafluid, so-called because its constitutive dynamics are derived not from atoms and molecules but from macroscopic, chaotic surface waves excited on a vertically agitated fluid. Unlike in conventional fluids, the viscosity and temperature of this metafluid are independantly tunable. Despite this unconventional property, our system is surprisingly consistent with equilibrium thermodynamics, despite being constructed from macroscopic, non-equilibrium elements. As a programmable material, our metafluid represents a new platform on which to study complex phenomena such as self-assembly and pattern formation. We demonstrate one such application in our study of short-chain polymer analogs embedded in our system. Title: Emergent thermodynamics in a system of macroscopic, chaotic surface waves Author: Welch, Kyle Year: 2016 The properties of conventional materials are inextricably linked with their molecular composition; to make water flow like wine would require changing its molecular identity. To circumvent this restriction, I have contstructed and characterized a two-dimensional metafluid, so-called because its constitutive dynamics are derived not from atoms and molecules but from macroscopic, chaotic surface waves excited on a vertically agitated fluid. Unlike in conventional fluids, the viscosity and temperature of this metafluid are independantly tunable. Despite this unconventional property, our system is surprisingly consistent with equilibrium thermodynamics, despite being constructed from macroscopic, non-equilibrium elements. As a programmable material, our metafluid represents a new platform on which to study complex phenomena such as self-assembly and pattern formation. We demonstrate one such application in our study of short-chain polymer analogs embedded in our system. Close

• 8. [Article] The Performance of Four Native Perennial Forb Species Along a Climate Gradient in Pacific Northwest Prairies

  To determine how Pacific Northwest prairies are influenced by local site factors versus. regional climate, we studied the reproduction, plant size, and density of sixteen natural populations of four perennial ...

  Citation × Citation Citation Abstract Copy Title: The Performance of Four Native Perennial Forb Species Along a Climate Gradient in Pacific Northwest Prairies Author: Hendricks, Lauren Year: 2016 To determine how Pacific Northwest prairies are influenced by local site factors versus. regional climate, we studied the reproduction, plant size, and density of sixteen natural populations of four perennial forb species native to Pacific Northwest prairies: Ranunculus austro-oreganus, Sidalcea malviflora spp. virgata, Microseris laciniata, and Eriophyllum lanatum. These populations were distributed along a 700 kilometer latitudinal gradient from southern Oregon to Whidbey Island, Washington. We found significant differences in plant size and reproduction among populations for all species, but correlations among edaphic and climate variables and plant size and reproduction were weak. Instead, density was more strongly correlated with both edaphic and climate variables, suggesting that this is a better indicator of long-term demographic processes. Although a few factors are important across species (e.g., nutrient availability and minimum temperature), response is idiosyncratic at the individual species level in Pacific Northwest prairies. Title: The Performance of Four Native Perennial Forb Species Along a Climate Gradient in Pacific Northwest Prairies Author: Hendricks, Lauren Year: 2016 To determine how Pacific Northwest prairies are influenced by local site factors versus. regional climate, we studied the reproduction, plant size, and density of sixteen natural populations of four perennial forb species native to Pacific Northwest prairies: Ranunculus austro-oreganus, Sidalcea malviflora spp. virgata, Microseris laciniata, and Eriophyllum lanatum. These populations were distributed along a 700 kilometer latitudinal gradient from southern Oregon to Whidbey Island, Washington. We found significant differences in plant size and reproduction among populations for all species, but correlations among edaphic and climate variables and plant size and reproduction were weak. Instead, density was more strongly correlated with both edaphic and climate variables, suggesting that this is a better indicator of long-term demographic processes. Although a few factors are important across species (e.g., nutrient availability and minimum temperature), response is idiosyncratic at the individual species level in Pacific Northwest prairies. Close

• 9. [Article] A Hierarchical Modeling Approach to Simulating the Geomorphic Response of River Systems to Climate Change

  Anthropogenic climate change significantly affects water resources. River flows in mountainous regions are driven by snowmelt and are therefore highly sensitive to increases in temperature resulting from ...

  Citation × Citation Citation Abstract Copy Title: A Hierarchical Modeling Approach to Simulating the Geomorphic Response of River Systems to Climate Change Author: Praskievicz, Sarah Year: 2014 Anthropogenic climate change significantly affects water resources. River flows in mountainous regions are driven by snowmelt and are therefore highly sensitive to increases in temperature resulting from climate change. Climate-driven hydrological changes are potentially significant for the fluvial geomorphology of river systems. In unchanging climatic and tectonic conditions, a river's morphology will develop in equilibrium with inputs of water and sediment, but climate change represents a potential forcing on these variables that may push the system into disequilibrium and cause significant changes in river morphology. Geomorphic factors, such as channel geometry, planform, and sediment transport, are major determinants of the value of river systems, including their suitability for threatened and endangered species and for human uses of water. This dissertation research uses a hierarchical modeling approach to investigate potential impacts of anthropogenic climate change on river morphology in the interior Pacific Northwest. The research will address the following theoretical and methodological objectives: 1) Develop downscaled climate change scenarios, based on regional climate-model output, including changes in daily minimum and maximum temperature and precipitation. 2) Estimate how climate change scenarios affect river discharge and suspended-sediment load, using a basin-scale hydrologic model. 3) Examine potential impacts of climate-driven hydrologic changes on stream power and shear stress, bedload sediment transport, and river morphology, including channel geometry and planform. The downscaling approach, based on empirically-estimated local topographic lapse rates, produces high-resolution climate grids with positive forecast skill. The hydrologic modeling results indicate that projected climate change in the study rivers will change the annual cycle of hydrology, with increased winter discharge, a decrease in the magnitude of the spring snowmelt peak, and decreased summer discharge. Geomorphic modeling results suggest that changes in reach-averaged bedload transport are highly sensitive to likely changes in the recurrence interval of the critical discharge needed to mobilize bed sediments. This dissertation research makes an original contribution to the climate-change impacts literature by linking Earth processes across a wide range of spatial scales to project changes in river systems that may be significant for management of these systems for societal and ecological benefits. This dissertation includes unpublished co-authored material. Title: A Hierarchical Modeling Approach to Simulating the Geomorphic Response of River Systems to Climate Change Author: Praskievicz, Sarah Year: 2014 Anthropogenic climate change significantly affects water resources. River flows in mountainous regions are driven by snowmelt and are therefore highly sensitive to increases in temperature resulting from climate change. Climate-driven hydrological changes are potentially significant for the fluvial geomorphology of river systems. In unchanging climatic and tectonic conditions, a river's morphology will develop in equilibrium with inputs of water and sediment, but climate change represents a potential forcing on these variables that may push the system into disequilibrium and cause significant changes in river morphology. Geomorphic factors, such as channel geometry, planform, and sediment transport, are major determinants of the value of river systems, including their suitability for threatened and endangered species and for human uses of water. This dissertation research uses a hierarchical modeling approach to investigate potential impacts of anthropogenic climate change on river morphology in the interior Pacific Northwest. The research will address the following theoretical and methodological objectives: 1) Develop downscaled climate change scenarios, based on regional climate-model output, including changes in daily minimum and maximum temperature and precipitation. 2) Estimate how climate change scenarios affect river discharge and suspended-sediment load, using a basin-scale hydrologic model. 3) Examine potential impacts of climate-driven hydrologic changes on stream power and shear stress, bedload sediment transport, and river morphology, including channel geometry and planform. The downscaling approach, based on empirically-estimated local topographic lapse rates, produces high-resolution climate grids with positive forecast skill. The hydrologic modeling results indicate that projected climate change in the study rivers will change the annual cycle of hydrology, with increased winter discharge, a decrease in the magnitude of the spring snowmelt peak, and decreased summer discharge. Geomorphic modeling results suggest that changes in reach-averaged bedload transport are highly sensitive to likely changes in the recurrence interval of the critical discharge needed to mobilize bed sediments. This dissertation research makes an original contribution to the climate-change impacts literature by linking Earth processes across a wide range of spatial scales to project changes in river systems that may be significant for management of these systems for societal and ecological benefits. This dissertation includes unpublished co-authored material. Close

• 10. [Article] Synthesis, Characterization, and Electrical Properties of ([SnSe]1+δ)m(NbSe2)3 Ferecrystalline Compounds

  29 pages. A thesis presented to the Department of Chemistry and Biochemistry, and the Clark Honors College of the University of Oregon in partial fulfillment of the requirements for degree of Bachelor ...

  Citation × Citation Citation Abstract Copy Title: Synthesis, Characterization, and Electrical Properties of ([SnSe]1+δ)m(NbSe2)3 Ferecrystalline Compounds Author: Ta, Phuong Kim Year: 2015 29 pages. A thesis presented to the Department of Chemistry and Biochemistry, and the Clark Honors College of the University of Oregon in partial fulfillment of the requirements for degree of Bachelor of Science, Spring 2015. Title: Synthesis, Characterization, and Electrical Properties of ([SnSe]1+δ)m(NbSe2)3 Ferecrystalline Compounds Author: Ta, Phuong Kim Year: 2015 29 pages. A thesis presented to the Department of Chemistry and Biochemistry, and the Clark Honors College of the University of Oregon in partial fulfillment of the requirements for degree of Bachelor of Science, Spring 2015. Close