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• 1. [Article] Statistical Analysis for Groundwater / Surface Water Interaction at a Drinking Water Well

  Drinking water at a certain groundwater well is located at the confluence of a north fork and south fork of a major river. Data was collected to determine if the well is under direct influence by surface ...

  Citation × Citation Citation Abstract Copy Title: Statistical Analysis for Groundwater / Surface Water Interaction at a Drinking Water Well Author: Garlitz, John Year: 2008 Drinking water at a certain groundwater well is located at the confluence of a north fork and south fork of a major river. Data was collected to determine if the well is under direct influence by surface water. Direct influence and the extent of the correlation was determined by statistically analyzing the well turbidity with surface water flow and temperature variability. The surface water flow and was lagged per period and with a weighted average to determine the highest correlation. Logistic regression models were developed to determine if a predictive model can predict permit conditions based on the data collected. Title: Statistical Analysis for Groundwater / Surface Water Interaction at a Drinking Water Well Author: Garlitz, John Year: 2008 Drinking water at a certain groundwater well is located at the confluence of a north fork and south fork of a major river. Data was collected to determine if the well is under direct influence by surface water. Direct influence and the extent of the correlation was determined by statistically analyzing the well turbidity with surface water flow and temperature variability. The surface water flow and was lagged per period and with a weighted average to determine the highest correlation. Logistic regression models were developed to determine if a predictive model can predict permit conditions based on the data collected. Close

• 2. [Article] Convergent Surface Water Distributions in U.S. Cities

  Earth's surface is rapidly urbanizing, resulting in dramatic changes in the abundance, distribution and character of surface water features in urban landscapes. However,the scope and consequences of surface ...

  Citation × Citation Citation Abstract Copy Title: Convergent Surface Water Distributions in U.S. Cities Author: Steele, Meredith K., Heffernan, James B., Bettez, Neil D., Cavender-Bares, Jeannine, Groffman, Peter M., Grove, J. Morgan, Hall, Sharon J., Hobbie, Sarah E., Larson, Kelli L., Morse, Jennifer L., Neill, Christopher, Nelson, Kristen C., O'Neil-Dunne, Jarlath, Ogden, Laura A., Pataki, Diane E., Polsky, Colin, Chowdhury, Rinku Roy Year: 2014 Earth's surface is rapidly urbanizing, resulting in dramatic changes in the abundance, distribution and character of surface water features in urban landscapes. However,the scope and consequences of surface water redistribution at broad spatialscales are not well understood. We hypothesized that urbanization would lead to convergent surface water abundance and distribution: in other words, cities will gain or lose water such that they become more similar to each other than are their surrounding natural landscapes. Using a database of more than 1 million water bodies and 1 million km of streams, we compared the surface water of 100 US cities with their surrounding undeveloped land. We evaluated differences in areal ( A) and numeric densities ( N) of water bodies (lakes, wetlands, and so on), the morphological characteristics of water bodies (size), and the density ( D) of surface flow channels (that is, streams and rivers). The variance of urban A, N, and D across the 100 MSAs decreased, by 89, 25, and 71%, respectively, compared to undeveloped land. These data show that many cities are surface water poor relative to undeveloped land; however, in drier landscapesurbanization increases the occurrence of surface water. This convergence pattern strengthened with development intensity, such that high intensityurban development had an areal water body density 98% less than undeveloped lands. Urbanization appears to drive the convergence of hydrological features across the US, such that surface water distributions of cities are more similar to each other than to their surrounding landscapes. Title: Convergent Surface Water Distributions in U.S. Cities Author: Steele, Meredith K., Heffernan, James B., Bettez, Neil D., Cavender-Bares, Jeannine, Groffman, Peter M., Grove, J. Morgan, Hall, Sharon J., Hobbie, Sarah E., Larson, Kelli L., Morse, Jennifer L., Neill, Christopher, Nelson, Kristen C., O'Neil-Dunne, Jarlath, Ogden, Laura A., Pataki, Diane E., Polsky, Colin, Chowdhury, Rinku Roy Year: 2014 Earth's surface is rapidly urbanizing, resulting in dramatic changes in the abundance, distribution and character of surface water features in urban landscapes. However,the scope and consequences of surface water redistribution at broad spatialscales are not well understood. We hypothesized that urbanization would lead to convergent surface water abundance and distribution: in other words, cities will gain or lose water such that they become more similar to each other than are their surrounding natural landscapes. Using a database of more than 1 million water bodies and 1 million km of streams, we compared the surface water of 100 US cities with their surrounding undeveloped land. We evaluated differences in areal ( A) and numeric densities ( N) of water bodies (lakes, wetlands, and so on), the morphological characteristics of water bodies (size), and the density ( D) of surface flow channels (that is, streams and rivers). The variance of urban A, N, and D across the 100 MSAs decreased, by 89, 25, and 71%, respectively, compared to undeveloped land. These data show that many cities are surface water poor relative to undeveloped land; however, in drier landscapesurbanization increases the occurrence of surface water. This convergence pattern strengthened with development intensity, such that high intensityurban development had an areal water body density 98% less than undeveloped lands. Urbanization appears to drive the convergence of hydrological features across the US, such that surface water distributions of cities are more similar to each other than to their surrounding landscapes. Close

• 3. [Article] Groundwater-Surface Water Interactions near Mosier, Oregon

  The town of Mosier, Oregon, is located near the east, dry end of the Columbia River Gorge, and the local area is known for cherry orchards that rely heavily on groundwater for irrigation. The CRBG groundwater ...

  Citation × Citation Citation Abstract Copy Title: Groundwater-Surface Water Interactions near Mosier, Oregon Author: Jones, Cullen Brandon Year: 2016 The town of Mosier, Oregon, is located near the east, dry end of the Columbia River Gorge, and the local area is known for cherry orchards that rely heavily on groundwater for irrigation. The CRBG groundwater system in Mosier has experienced groundwater declines of up to 60 meters due to over-pumping and or commingling. Declining groundwater levels have led to concerns over the sustainability of the resource, as it is the principle water source for irrigation and domestic use. Despite numerous previous studies of groundwater flow in CRBG aquifers here and elsewhere in the Columbia River basin, an aspect that has received relatively little attention is the interaction between groundwater and surface waters at locations where interflow zones are intersected by the surface waters. The objective of my research is to investigate how CRBG interflow zone exposures in Mosier Creek may be controlling groundwater elevations in the area. The methods used include: (1) geochemical analysis of well cuttings and detailed geologic mapping along area streams to identify interflow zones of individual CRBG flows, (2) analysis of stream discharge data and groundwater elevation data to confirm exchange of groundwater and surface waters, and (3) collection and analyses of 31 water samples from area wells, streams, and springs, to determine if waters from individual CRBG aquifers can be hydrochemically identified and to further constrain understanding of surface and groundwater interactions. My study confirms that the general elevation of the Pomona Member and Basalt of Lolo interflow zone creek exposure is coincident with the elevation where a change in slope of the decline trend in 2004 is seen in Mosier area well hydrographs. Furthermore, the results of stream discharge data indicated a close connection between drawdown from groundwater pumping during irrigation season and groundwater- surface water interaction. At the time of drawdown in the upper-most CRBG aquifer (Pomona), the stream transitions from gaining to losing water into the groundwater system. Elemental chemistry data indicates the Frenchman Springs Sentinel Gap aquifer waters are the most evolved waters in this study. Stable isotopic data reinforced this determination as the Sentinel Gap waters are the lightest, or most negative, with regard to δD and δ18O. Sentinel Gap samples were more depleted than other aquifer samples by 4.38 to 6.89 0/100 for δD and 0.39 to 0.59 0/100 for δ18O. The results of the general chemistry and isotope data reveal a more evolved chemical signature in lower watershed groundwater versus a less evolved signature for waters from wells located higher up on the Columbia Hills anticline. This was interpreted to be the result of the major structural features in the area providing for a more regional pathway of recharge in lower watershed groundwaters, versus a more local source of recharge for upper watershed groundwaters. There was also a pronounced commingled signature in the elemental ratios of lower watershed aquifer waters. The suspected mechanism of recharge to lower watershed wells is through younger Cascadian deposits upslope from the local watershed. The findings of this study reveal the importance of a detailed understanding of CRBG stratigraphy and its relation to surface waters, especially for other areas within the Yakima Fold Belt or Oregon and Washington. Studies that do not consider the influence that individual CRBG flows can have on groundwater-surface water interactions, and the groundwater system as a whole, run the risk of improperly assessing the groundwater resource for a region. Title: Groundwater-Surface Water Interactions near Mosier, Oregon Author: Jones, Cullen Brandon Year: 2016 The town of Mosier, Oregon, is located near the east, dry end of the Columbia River Gorge, and the local area is known for cherry orchards that rely heavily on groundwater for irrigation. The CRBG groundwater system in Mosier has experienced groundwater declines of up to 60 meters due to over-pumping and or commingling. Declining groundwater levels have led to concerns over the sustainability of the resource, as it is the principle water source for irrigation and domestic use. Despite numerous previous studies of groundwater flow in CRBG aquifers here and elsewhere in the Columbia River basin, an aspect that has received relatively little attention is the interaction between groundwater and surface waters at locations where interflow zones are intersected by the surface waters. The objective of my research is to investigate how CRBG interflow zone exposures in Mosier Creek may be controlling groundwater elevations in the area. The methods used include: (1) geochemical analysis of well cuttings and detailed geologic mapping along area streams to identify interflow zones of individual CRBG flows, (2) analysis of stream discharge data and groundwater elevation data to confirm exchange of groundwater and surface waters, and (3) collection and analyses of 31 water samples from area wells, streams, and springs, to determine if waters from individual CRBG aquifers can be hydrochemically identified and to further constrain understanding of surface and groundwater interactions. My study confirms that the general elevation of the Pomona Member and Basalt of Lolo interflow zone creek exposure is coincident with the elevation where a change in slope of the decline trend in 2004 is seen in Mosier area well hydrographs. Furthermore, the results of stream discharge data indicated a close connection between drawdown from groundwater pumping during irrigation season and groundwater- surface water interaction. At the time of drawdown in the upper-most CRBG aquifer (Pomona), the stream transitions from gaining to losing water into the groundwater system. Elemental chemistry data indicates the Frenchman Springs Sentinel Gap aquifer waters are the most evolved waters in this study. Stable isotopic data reinforced this determination as the Sentinel Gap waters are the lightest, or most negative, with regard to δD and δ18O. Sentinel Gap samples were more depleted than other aquifer samples by 4.38 to 6.89 0/100 for δD and 0.39 to 0.59 0/100 for δ18O. The results of the general chemistry and isotope data reveal a more evolved chemical signature in lower watershed groundwater versus a less evolved signature for waters from wells located higher up on the Columbia Hills anticline. This was interpreted to be the result of the major structural features in the area providing for a more regional pathway of recharge in lower watershed groundwaters, versus a more local source of recharge for upper watershed groundwaters. There was also a pronounced commingled signature in the elemental ratios of lower watershed aquifer waters. The suspected mechanism of recharge to lower watershed wells is through younger Cascadian deposits upslope from the local watershed. The findings of this study reveal the importance of a detailed understanding of CRBG stratigraphy and its relation to surface waters, especially for other areas within the Yakima Fold Belt or Oregon and Washington. Studies that do not consider the influence that individual CRBG flows can have on groundwater-surface water interactions, and the groundwater system as a whole, run the risk of improperly assessing the groundwater resource for a region. Close

• 4. [Article] Occurrence of Synthetic Amino-Polycarboxylate Chelating Compounds in Oregon Surface Waters

  Cation sequestering compounds are contained in many industrial, commercial and personal care products. The most widely used chelating agents, EDTA and DTPA, are commonly found in natural and industrial ...

  Citation × Citation Citation Abstract Copy Title: Occurrence of Synthetic Amino-Polycarboxylate Chelating Compounds in Oregon Surface Waters Author: Hersey, Nathan A Year: 2014 Cation sequestering compounds are contained in many industrial, commercial and personal care products. The most widely used chelating agents, EDTA and DTPA, are commonly found in natural and industrial settings. When chelating compounds are present, the activity and transport of metal cations in the environment and the uptake of metals in natural systems can be affected. Surface water samples from across the United States were analyzed, as well as local collection and analysis of surface waters and wastewater treatment plant effluent from around Northwest Oregon. Results indicate presence of synthetic chelating compounds in areas with human activity, and absence in areas that are less populated. As a stable and water soluble compound, monitoring for chelates could have potential use as an effective indicator of further anthropogenic effects. Title: Occurrence of Synthetic Amino-Polycarboxylate Chelating Compounds in Oregon Surface Waters Author: Hersey, Nathan A Year: 2014 Cation sequestering compounds are contained in many industrial, commercial and personal care products. The most widely used chelating agents, EDTA and DTPA, are commonly found in natural and industrial settings. When chelating compounds are present, the activity and transport of metal cations in the environment and the uptake of metals in natural systems can be affected. Surface water samples from across the United States were analyzed, as well as local collection and analysis of surface waters and wastewater treatment plant effluent from around Northwest Oregon. Results indicate presence of synthetic chelating compounds in areas with human activity, and absence in areas that are less populated. As a stable and water soluble compound, monitoring for chelates could have potential use as an effective indicator of further anthropogenic effects. Close

• 5. [Article] Groundwater Surface Trends in the North Florence Dunal Aquifer, Oregon Coast, USA

  The North Florence Dunal Aquifer is the only feasible source for drinking water for the coastal city of Florence, Oregon and Florence's Urban Growth Boundary. High infiltration rates and a shallow groundwater ...

  Citation × Citation Citation Abstract Copy Title: Groundwater Surface Trends in the North Florence Dunal Aquifer, Oregon Coast, USA Author: Doliber, Sarah Rebecca Year: 2012 The North Florence Dunal Aquifer is the only feasible source for drinking water for the coastal city of Florence, Oregon and Florence's Urban Growth Boundary. High infiltration rates and a shallow groundwater table leave the aquifer highly susceptible to contamination from septic tank effluent, storm runoff, chemical fertilizers and recreational ATV use throughout the dunes. Public interest in the quality and quantity of the aquifer water has been sparked since the City of Florence received a grant from the Environmental Protection Agency for a watershed protection and restoration project. Delineation of the shallow groundwater surface and its relationship to the surface water bodies within the dunes is crucial in protecting this drinking water source from contamination. This thesis project created a GIS representation of the shallow groundwater elevation and associated prediction error map. Surface water bodies were confirmed as window lakes into the dunal aquifer and no signs of perched aquifer conditions were observed between Holocene and Pleistocene dunes. Ground Penetrating Radar, well data provided by the city of Florence and LiDAR were the primary sources for data collection. Title: Groundwater Surface Trends in the North Florence Dunal Aquifer, Oregon Coast, USA Author: Doliber, Sarah Rebecca Year: 2012 The North Florence Dunal Aquifer is the only feasible source for drinking water for the coastal city of Florence, Oregon and Florence's Urban Growth Boundary. High infiltration rates and a shallow groundwater table leave the aquifer highly susceptible to contamination from septic tank effluent, storm runoff, chemical fertilizers and recreational ATV use throughout the dunes. Public interest in the quality and quantity of the aquifer water has been sparked since the City of Florence received a grant from the Environmental Protection Agency for a watershed protection and restoration project. Delineation of the shallow groundwater surface and its relationship to the surface water bodies within the dunes is crucial in protecting this drinking water source from contamination. This thesis project created a GIS representation of the shallow groundwater elevation and associated prediction error map. Surface water bodies were confirmed as window lakes into the dunal aquifer and no signs of perched aquifer conditions were observed between Holocene and Pleistocene dunes. Ground Penetrating Radar, well data provided by the city of Florence and LiDAR were the primary sources for data collection. Close

• 6. [Article] Automatic Calibration of Water Quality and Hydrodynamic Model (CE-QUAL-W2)

  One of the most important purposes of surface water resource management is to develop predictive models to assist in identifying and evaluating operational and structural measures for improving water quality. ...

  Citation × Citation Citation Abstract Copy Title: Automatic Calibration of Water Quality and Hydrodynamic Model (CE-QUAL-W2) Author: Shojaei, Nasim Year: 2014 One of the most important purposes of surface water resource management is to develop predictive models to assist in identifying and evaluating operational and structural measures for improving water quality. To better understand the effects of external and internal nutrient and organic loading and the effects of reservoir operation, a model is often developed, calibrated, and used for sensitivity and management simulations. The importance of modeling and simulation in the scientific community has drawn interest towards methods for automated calibration. This study addresses using an automatic technique to calibrate the water quality model CE-QUAL-W2 (Cole and Wells, 2013). CE-QUAL-W2 is a two-dimensional (2D) longitudinal/vertical hydrodynamic and water quality model for surface water bodies, modeling eutrophication processes such as temperature-nutrient-algae-dissolved oxygen-organic matter and sediment relationships. The numerical method used for calibration in this study is the particle swarm optimization method developed by Kennedy and Eberhart (1995) and inspired by the paradigm of birds flocking. The objective of this calibration procedure is to choose model parameters and coefficients affecting temperature, chlorophyll a, dissolved oxygen, and nutrients (such as NH4, NO3, and PO4). A case study is presented for the Karkheh Reservoir in Iran with a capacity of more than 5 billion cubic meters that is the largest dam in Iran with both agricultural and drinking water usages. This algorithm is shown to perform very well for determining model parameters for the reservoir water quality and hydrodynamic model. Implications of the use of this procedure for other water quality models are also shown. Title: Automatic Calibration of Water Quality and Hydrodynamic Model (CE-QUAL-W2) Author: Shojaei, Nasim Year: 2014 One of the most important purposes of surface water resource management is to develop predictive models to assist in identifying and evaluating operational and structural measures for improving water quality. To better understand the effects of external and internal nutrient and organic loading and the effects of reservoir operation, a model is often developed, calibrated, and used for sensitivity and management simulations. The importance of modeling and simulation in the scientific community has drawn interest towards methods for automated calibration. This study addresses using an automatic technique to calibrate the water quality model CE-QUAL-W2 (Cole and Wells, 2013). CE-QUAL-W2 is a two-dimensional (2D) longitudinal/vertical hydrodynamic and water quality model for surface water bodies, modeling eutrophication processes such as temperature-nutrient-algae-dissolved oxygen-organic matter and sediment relationships. The numerical method used for calibration in this study is the particle swarm optimization method developed by Kennedy and Eberhart (1995) and inspired by the paradigm of birds flocking. The objective of this calibration procedure is to choose model parameters and coefficients affecting temperature, chlorophyll a, dissolved oxygen, and nutrients (such as NH4, NO3, and PO4). A case study is presented for the Karkheh Reservoir in Iran with a capacity of more than 5 billion cubic meters that is the largest dam in Iran with both agricultural and drinking water usages. This algorithm is shown to perform very well for determining model parameters for the reservoir water quality and hydrodynamic model. Implications of the use of this procedure for other water quality models are also shown. Close

• 7. [Article] Effects of Beaver Dams on Surface Water Flow During Storm Events in an Urban Landscape

  Urban land-use generally alters the hydrologic cycle, leading to changes in the natural flow regime of local streams. Runoff from impervious surfaces and routing of stormwater to streams causes urban streams ...

  Citation × Citation Citation Abstract Copy Title: Effects of Beaver Dams on Surface Water Flow During Storm Events in an Urban Landscape Author: Poor, Erin Year: 2017 Urban land-use generally alters the hydrologic cycle, leading to changes in the natural flow regime of local streams. Runoff from impervious surfaces and routing of stormwater to streams causes urban streams to respond quickly and more intensely to storm events-more so than then would be observed in a less urbanized landscape. The rapid pulse of water that is routed to streams during precipitation events can degrade the physical structure of the channel and alter water quality and habitat availability. To manage these common urban stream issues, agencies have been seeking alternative ways of restoring and enhancing resilience in urban stream networks within the constraints of existing infrastructure. One potential strategy may be to support beaver recolonization of urban streams. This is because beaver dam building activity has been found to attenuate streamflow in areas that have experienced minimal human impact. Currently, however, no studies have been published that examine how beaver dams affect stream flow in altered urban systems. This study seeks to determine if the presence of beaver dams and ponds in urban stream reaches in the Tualatin River basin, Oregon, modifies the stream’s response to storm events. Continuous surface water levels are being collected upstream and downstream of two beaver affected reaches in order to determine how the presence of dams and ponds affect the flow regime, and whether this more closely resembles a less degraded state. Title: Effects of Beaver Dams on Surface Water Flow During Storm Events in an Urban Landscape Author: Poor, Erin Year: 2017 Urban land-use generally alters the hydrologic cycle, leading to changes in the natural flow regime of local streams. Runoff from impervious surfaces and routing of stormwater to streams causes urban streams to respond quickly and more intensely to storm events-more so than then would be observed in a less urbanized landscape. The rapid pulse of water that is routed to streams during precipitation events can degrade the physical structure of the channel and alter water quality and habitat availability. To manage these common urban stream issues, agencies have been seeking alternative ways of restoring and enhancing resilience in urban stream networks within the constraints of existing infrastructure. One potential strategy may be to support beaver recolonization of urban streams. This is because beaver dam building activity has been found to attenuate streamflow in areas that have experienced minimal human impact. Currently, however, no studies have been published that examine how beaver dams affect stream flow in altered urban systems. This study seeks to determine if the presence of beaver dams and ponds in urban stream reaches in the Tualatin River basin, Oregon, modifies the stream’s response to storm events. Continuous surface water levels are being collected upstream and downstream of two beaver affected reaches in order to determine how the presence of dams and ponds affect the flow regime, and whether this more closely resembles a less degraded state. Close

• 8. [Article] Estimation of Surface Water Temperature of the Tigris River System in Iraq

  Monitoring surface water temperatures (Tw) in lakes, rivers, and reservoirs is a key component of environmental management and influences water quality by affecting bio-geo chemical reaction rates, altering ...

  Citation × Citation Citation Abstract Copy Title: Estimation of Surface Water Temperature of the Tigris River System in Iraq Author: Al-Murib, M., Wells, Scott A., Talke, Stefan A. Year: 2017 Monitoring surface water temperatures (Tw) in lakes, rivers, and reservoirs is a key component of environmental management and influences water quality by affecting bio-geo chemical reaction rates, altering the saturation concentration of dissolved oxygen (DO), and influencing the susceptibility of fish to disease. Temperatures in the Tigris River, one of the largest rivers in the Middle East, are influenced by factors such as heat fluxes at the air-water and human activities such as direct discharge of water to the river. However, modeling and management of water temperature is limited by a paucity of in-situ data, which prevents calibration of models. In this study, we infill data gaps by estimating Tw using the thermal bands of both the Landsat 5 TM and Landsat 7 ETM+ sensors. These satellite-based estimates, typically measured once or twice a month with 60-120m resolution, are then used to develop a regression model that relates daily water temperature to daily air temperature and river flow. These estimates are used to define the Tw boundary conditions for a hydrodynamic and water quality model of the Tigris River based on a 2D implementation of the CE-QUAL-W2 (W2) numerical model. Initial results suggest that there is a significant agreement between modeled and remotely estimated data of Tw. Results suggest that short-wave solar radiation is the most important factor that controls seasonal Tw variations. However, anthropogenic influence is observed as a result of return irrigation flows and flows from Tharthar Lake. Title: Estimation of Surface Water Temperature of the Tigris River System in Iraq Author: Al-Murib, M., Wells, Scott A., Talke, Stefan A. Year: 2017 Monitoring surface water temperatures (Tw) in lakes, rivers, and reservoirs is a key component of environmental management and influences water quality by affecting bio-geo chemical reaction rates, altering the saturation concentration of dissolved oxygen (DO), and influencing the susceptibility of fish to disease. Temperatures in the Tigris River, one of the largest rivers in the Middle East, are influenced by factors such as heat fluxes at the air-water and human activities such as direct discharge of water to the river. However, modeling and management of water temperature is limited by a paucity of in-situ data, which prevents calibration of models. In this study, we infill data gaps by estimating Tw using the thermal bands of both the Landsat 5 TM and Landsat 7 ETM+ sensors. These satellite-based estimates, typically measured once or twice a month with 60-120m resolution, are then used to develop a regression model that relates daily water temperature to daily air temperature and river flow. These estimates are used to define the Tw boundary conditions for a hydrodynamic and water quality model of the Tigris River based on a 2D implementation of the CE-QUAL-W2 (W2) numerical model. Initial results suggest that there is a significant agreement between modeled and remotely estimated data of Tw. Results suggest that short-wave solar radiation is the most important factor that controls seasonal Tw variations. However, anthropogenic influence is observed as a result of return irrigation flows and flows from Tharthar Lake. Close

• 9. [Article] Stable Isotope Variations (δ18O and δD) in Modern Waters Across the Andean Plateau

  Environmental parameters that influence the isotopic composition of meteoric water (δ18O and δD) are well characterized up the windward side of mountains, where orographic precipitation results in a predictable ...

  Citation × Citation Citation Abstract Copy Title: Stable Isotope Variations (δ18O and δD) in Modern Waters Across the Andean Plateau Author: Bershaw, John, Saylor, Joel E., Garzione, Carmala N., Leier, Andrew Year: 2016 Environmental parameters that influence the isotopic composition of meteoric water (δ18O and δD) are well characterized up the windward side of mountains, where orographic precipitation results in a predictable relationship between the isotopic composition of precipitation and elevation. The topographic and climatic evolution of the Andean Plateau and surrounding regions has been studied extensively by exploiting this relationship through the use of paleowater proxies. However, interpretation on the plateau itself is challenged by a poor understanding of processes that fractionate isotopes during vapor transport and rainout, and by the relative contribution of unique moisture sources. Here, we present an extensive dataset of modern surface water samples for the northern Andean Plateau and surrounding regions to elucidate patterns and causes of isotope fractionation in this continental environment. These data show a progressive increase in δ18O of stream water west of the Eastern Cordillera (∼1‰/70 km), almost identical to the rate observed across the Tibetan Plateau, attributed to a larger fraction of recycled water in precipitation and/or increased evaporative enrichment downwind. This may lead to underestimates of paleoelevation, particularly for sites deep into the rainshadow of the Eastern Cordilleran crest. That said, elevation is a primary control on the isotopic composition of surface waters across the entire Andean Plateau and its flanks when considering the most negative δ18O values, highlighting the need for sufficiently large datasets to distinguish minimally evaporated samples. There is a general increase in δ18O on the plateau from north to south, concomitant with an increase in aridity and decrease in convective moistening (amount effect). Lastly, stable isotope and seasonal precipitation patterns suggest easterlies provide the vast majority of moisture that falls as precipitation across the Andean Plateau and Western Cordillera, from Peru to northern Bolivia (−13° to −20° latitude), with Pacific-derived moisture contributing a minor amount at low elevations near the coast. Title: Stable Isotope Variations (δ18O and δD) in Modern Waters Across the Andean Plateau Author: Bershaw, John, Saylor, Joel E., Garzione, Carmala N., Leier, Andrew Year: 2016 Environmental parameters that influence the isotopic composition of meteoric water (δ18O and δD) are well characterized up the windward side of mountains, where orographic precipitation results in a predictable relationship between the isotopic composition of precipitation and elevation. The topographic and climatic evolution of the Andean Plateau and surrounding regions has been studied extensively by exploiting this relationship through the use of paleowater proxies. However, interpretation on the plateau itself is challenged by a poor understanding of processes that fractionate isotopes during vapor transport and rainout, and by the relative contribution of unique moisture sources. Here, we present an extensive dataset of modern surface water samples for the northern Andean Plateau and surrounding regions to elucidate patterns and causes of isotope fractionation in this continental environment. These data show a progressive increase in δ18O of stream water west of the Eastern Cordillera (∼1‰/70 km), almost identical to the rate observed across the Tibetan Plateau, attributed to a larger fraction of recycled water in precipitation and/or increased evaporative enrichment downwind. This may lead to underestimates of paleoelevation, particularly for sites deep into the rainshadow of the Eastern Cordilleran crest. That said, elevation is a primary control on the isotopic composition of surface waters across the entire Andean Plateau and its flanks when considering the most negative δ18O values, highlighting the need for sufficiently large datasets to distinguish minimally evaporated samples. There is a general increase in δ18O on the plateau from north to south, concomitant with an increase in aridity and decrease in convective moistening (amount effect). Lastly, stable isotope and seasonal precipitation patterns suggest easterlies provide the vast majority of moisture that falls as precipitation across the Andean Plateau and Western Cordillera, from Peru to northern Bolivia (−13° to −20° latitude), with Pacific-derived moisture contributing a minor amount at low elevations near the coast. Close

• 10. [Article] Impact of Groundwater Contamination in East Multnomah County on the Interlachen Community

  The Friends of Blue and Fairview Lake through the Environmental Protection Agency (EPA) Technical Assistance Grant (TAG) program contracted with Portland State University faculty and staff to provide an ...

  Citation × Citation Citation Abstract Copy Title: Impact of Groundwater Contamination in East Multnomah County on the Interlachen Community Author: Wells, Scott A., Li, ShuGuang, Beeson, Marvin, Cummings, Michael, Pratt, Richard, Annear, Robert Leslie, Brandt, Karann Year: 1996 The Friends of Blue and Fairview Lake through the Environmental Protection Agency (EPA) Technical Assistance Grant (TAG) program contracted with Portland State University faculty and staff to provide an independent review of the groundwater contamination problem at the Boeing-Cascade site in East Multnomah County. An independent consultant, Karann Brandt, of PRC Environmental Management, Inc., was also assisting the panel with the review. The region of groundwater contamination is a 2.5 square mile region bounded by NE Halsey Blvd. to the Columbia River and NE 178th to NE 223rd (see Figure 1). The groundwater contamination is primarily of volatile organic compounds (like trichloroethylene or TCE). The approximate plume extent is shown in Figure 2 in one of the principal aquifers, the Troutdale Sandstone Aquifer (TSA). Since the Interlachen community in the area of Blue and Fairview Lakes uses groundwater as a community water supply and the lakes as a recreation resource, there are concerns that the groundwater contamination could seriously affect the community by contaminating their water supply and surface water bodies (Fairview Lake, Blue Lake, Columbia Slough) in their vicinity. Much work has been accomplished already by responsible parties (Boeing and Cascade Corporations and their conconsultants. The community was able to secure the EPA TAG to provide an independent review of the contamination problem facing their community and to assist the community in understanding the nature of the contamination problem. Issues of concern identified from this review will be recommended for incorporation in the Department of Environmental Quality’s (DEQ) final Record of Decision concerning site remediation efforts. This review will help assure remediation strategies that protect groundwater and surface water for the Interlachen community will be pursued by the responsible parties. Title: Impact of Groundwater Contamination in East Multnomah County on the Interlachen Community Author: Wells, Scott A., Li, ShuGuang, Beeson, Marvin, Cummings, Michael, Pratt, Richard, Annear, Robert Leslie, Brandt, Karann Year: 1996 The Friends of Blue and Fairview Lake through the Environmental Protection Agency (EPA) Technical Assistance Grant (TAG) program contracted with Portland State University faculty and staff to provide an independent review of the groundwater contamination problem at the Boeing-Cascade site in East Multnomah County. An independent consultant, Karann Brandt, of PRC Environmental Management, Inc., was also assisting the panel with the review. The region of groundwater contamination is a 2.5 square mile region bounded by NE Halsey Blvd. to the Columbia River and NE 178th to NE 223rd (see Figure 1). The groundwater contamination is primarily of volatile organic compounds (like trichloroethylene or TCE). The approximate plume extent is shown in Figure 2 in one of the principal aquifers, the Troutdale Sandstone Aquifer (TSA). Since the Interlachen community in the area of Blue and Fairview Lakes uses groundwater as a community water supply and the lakes as a recreation resource, there are concerns that the groundwater contamination could seriously affect the community by contaminating their water supply and surface water bodies (Fairview Lake, Blue Lake, Columbia Slough) in their vicinity. Much work has been accomplished already by responsible parties (Boeing and Cascade Corporations and their conconsultants. The community was able to secure the EPA TAG to provide an independent review of the contamination problem facing their community and to assist the community in understanding the nature of the contamination problem. Issues of concern identified from this review will be recommended for incorporation in the Department of Environmental Quality’s (DEQ) final Record of Decision concerning site remediation efforts. This review will help assure remediation strategies that protect groundwater and surface water for the Interlachen community will be pursued by the responsible parties. Close

• 11. [Article] Influence of light on algal growth in the lower Willamette River

  During the summer of 1974 chemical conditions in the lower reaches of the Willamette River, Oregon were similar to those in other rivers currently experiencing nuisance algal growth problems. Temperature ...

  Citation × Citation Citation Abstract Copy Title: Influence of light on algal growth in the lower Willamette River Author: Wille, Stephen Arthur Year: 1976 During the summer of 1974 chemical conditions in the lower reaches of the Willamette River, Oregon were similar to those in other rivers currently experiencing nuisance algal growth problems. Temperature and chemical nutrients are not limiting. Relatively high populations of phytoplankton and productivity values for upstream periphyton beds and surface waters suggest moderately eutrophic conditions. However, with increased depth in the lower river, and a constant euphotic zone, the amount of photosynthetically available light is reduced. With sufficient depth and complete mixing the critical depth is exceeded. Primary productivity rates are subsequently limited by low light availability in the lower river. Title: Influence of light on algal growth in the lower Willamette River Author: Wille, Stephen Arthur Year: 1976 During the summer of 1974 chemical conditions in the lower reaches of the Willamette River, Oregon were similar to those in other rivers currently experiencing nuisance algal growth problems. Temperature and chemical nutrients are not limiting. Relatively high populations of phytoplankton and productivity values for upstream periphyton beds and surface waters suggest moderately eutrophic conditions. However, with increased depth in the lower river, and a constant euphotic zone, the amount of photosynthetically available light is reduced. With sufficient depth and complete mixing the critical depth is exceeded. Primary productivity rates are subsequently limited by low light availability in the lower river. Close

• 12. [Article] Hydrogeochemical Evaluation of the Uinta Formation and Green River Formation, Piceance Creek Basin, Northwestern Colorado, USA

  The Piceance Creek Basin in northwestern Colorado contains extensive oil shale deposits that produce natural gas and which could potentially yield ~1.5 trillion barrels of shale oil. However, much of the ...

  Citation × Citation Citation Abstract Copy Title: Hydrogeochemical Evaluation of the Uinta Formation and Green River Formation, Piceance Creek Basin, Northwestern Colorado, USA Author: Masterson, Megan E. Year: 2016 The Piceance Creek Basin in northwestern Colorado contains extensive oil shale deposits that produce natural gas and which could potentially yield ~1.5 trillion barrels of shale oil. However, much of the oil shale lies at depths too great for traditional mining practices and various innovative approaches for in situ conversion of kerogen to oil have been proposed. A firm understanding of the existing hydrogeochemistry is needed as resulting mineralogical changes or rock-fluid reactions may affect rock porosity and permeability. Using an existing database complied by the USGS, the water chemistry of 267 surface and groundwater samples in the Piceance Creek primary drainage basin have been evaluated by mapping major ion concentrations and mineral saturation indicies with respect to hydrostratigraphic units and geologic structures. Controlling processes have been further assessed using statistical correlation and factor analysis. Results indicate that shallow waters in recharge zones are dominated by mixed cations (Na, Ca, Mg) and bicarbonate anions but with increased depth, groundwater transition to nearly 100% sodium bicarbonate type water. The chemistry of lower aquifer waters are principally controlled by nahcolite dissolution, but evidence of sulfate reduction and cation exchange aid in maintaining a sodium-bicarbonate water type. Ion evolution in surface and upper aquifer waters are influenced by an increase in sulfate concentration which is necessary to evolve water to an intermediate stage with sulfate-dominant anions. The source of sulfate is speculative, but likely due in part to the oxidation of sulfide-enriched groundwater and possible dissolution of sulfate-bearing carbonates. Surface and upper aquifer water chemistry in the northern portion of the basin is the result of discharge of deeper groundwater which is controlled to some degree by preferential pathways created by faults. Lower aquifer water migrates upward and mixes with the less-concentrated near-surface water, resulting in sodium bicarbonate type water in all hydrologic units. Title: Hydrogeochemical Evaluation of the Uinta Formation and Green River Formation, Piceance Creek Basin, Northwestern Colorado, USA Author: Masterson, Megan E. Year: 2016 The Piceance Creek Basin in northwestern Colorado contains extensive oil shale deposits that produce natural gas and which could potentially yield ~1.5 trillion barrels of shale oil. However, much of the oil shale lies at depths too great for traditional mining practices and various innovative approaches for in situ conversion of kerogen to oil have been proposed. A firm understanding of the existing hydrogeochemistry is needed as resulting mineralogical changes or rock-fluid reactions may affect rock porosity and permeability. Using an existing database complied by the USGS, the water chemistry of 267 surface and groundwater samples in the Piceance Creek primary drainage basin have been evaluated by mapping major ion concentrations and mineral saturation indicies with respect to hydrostratigraphic units and geologic structures. Controlling processes have been further assessed using statistical correlation and factor analysis. Results indicate that shallow waters in recharge zones are dominated by mixed cations (Na, Ca, Mg) and bicarbonate anions but with increased depth, groundwater transition to nearly 100% sodium bicarbonate type water. The chemistry of lower aquifer waters are principally controlled by nahcolite dissolution, but evidence of sulfate reduction and cation exchange aid in maintaining a sodium-bicarbonate water type. Ion evolution in surface and upper aquifer waters are influenced by an increase in sulfate concentration which is necessary to evolve water to an intermediate stage with sulfate-dominant anions. The source of sulfate is speculative, but likely due in part to the oxidation of sulfide-enriched groundwater and possible dissolution of sulfate-bearing carbonates. Surface and upper aquifer water chemistry in the northern portion of the basin is the result of discharge of deeper groundwater which is controlled to some degree by preferential pathways created by faults. Lower aquifer water migrates upward and mixes with the less-concentrated near-surface water, resulting in sodium bicarbonate type water in all hydrologic units. Close

• 13. [Article] Nonstationary Internal Tides Observed Using Dual-Satellite Altimetry

  Dual-satellite crossover data from the Jason-2 and Cryosat-2 altimeter missions are used in a novel approach to quantify stationary and nonstationary tides from time-lagged mean square sea surface height ...

  Citation × Citation Citation Abstract Copy Title: Nonstationary Internal Tides Observed Using Dual-Satellite Altimetry Author: Zaron, Edward D. Year: 2015 Dual-satellite crossover data from the Jason-2 and Cryosat-2 altimeter missions are used in a novel approach to quantify stationary and nonstationary tides from time-lagged mean square sea surface height (SSH) differences, computed for lags from 1 to 1440 h (60 days). The approach is made feasible by removing independent estimates of the stationary tide and mesoscale SSH variance, which greatly reduces the sampling error of the SSH statistics. For the semidiurnal tidal band, the stationary tidal variance is approximately 0.73 cm(2), and the nonstationary variance is about 0.33 cm(2), or 30% of the total. The temporal correlation of the nonstationary tide is examined by complex demodulation and found to be oscillatory with first 0 crossing at 400 h (17 days). Because a significant fraction of the time-variable mesoscale signal is resolved at time scales of roughly 150 h by the present constellation of satellite altimeters, the results suggest that it may be feasible to predict the nonstationary tide from modulations of the resolved mesoscale, thus enhancing the efficacy of tidal corrections for planned wide-swath altimeters such as the Surface Water and Ocean Topography (SWOT) mission. Title: Nonstationary Internal Tides Observed Using Dual-Satellite Altimetry Author: Zaron, Edward D. Year: 2015 Dual-satellite crossover data from the Jason-2 and Cryosat-2 altimeter missions are used in a novel approach to quantify stationary and nonstationary tides from time-lagged mean square sea surface height (SSH) differences, computed for lags from 1 to 1440 h (60 days). The approach is made feasible by removing independent estimates of the stationary tide and mesoscale SSH variance, which greatly reduces the sampling error of the SSH statistics. For the semidiurnal tidal band, the stationary tidal variance is approximately 0.73 cm(2), and the nonstationary variance is about 0.33 cm(2), or 30% of the total. The temporal correlation of the nonstationary tide is examined by complex demodulation and found to be oscillatory with first 0 crossing at 400 h (17 days). Because a significant fraction of the time-variable mesoscale signal is resolved at time scales of roughly 150 h by the present constellation of satellite altimeters, the results suggest that it may be feasible to predict the nonstationary tide from modulations of the resolved mesoscale, thus enhancing the efficacy of tidal corrections for planned wide-swath altimeters such as the Surface Water and Ocean Topography (SWOT) mission. Close

• 14. [Article] Application of Mathematical Modeling and Computer Simulation for Solving Water Quality Problems

  Deteriorated water resources in Central and Eastern Europe call for actions that should be undertaken to improve current conditions and to protect human and environmental health. Mathematical modeling ...

  Citation × Citation Citation Abstract Copy Title: Application of Mathematical Modeling and Computer Simulation for Solving Water Quality Problems Author: Makinia, Jacek, Wells, Scott A., Crawford, David, Kulbik, Marian Year: 1998 Deteriorated water resources in Central and Eastern Europe call for actions that should be undertaken to improve current conditions and to protect human and environmental health. Mathematical modeling and computer simulation is often an integral part of the decision-making process. Models and simulations allow rapid and varied evaluation of causes and effects and the principal advantage is that they enable an analysis of even long-term actions with limited investment costs. This paper provides an overview of popular models used for simulation of major elements of a water quality system: surface water quality (QUAL2E), wastewater treatment (Activated Sludge Model No.1), sewer network (SWMM), and water distribution network (EPANET). Model uses are illustrated by specific examples both in the U.S. or in Central and Eastern Europe. Title: Application of Mathematical Modeling and Computer Simulation for Solving Water Quality Problems Author: Makinia, Jacek, Wells, Scott A., Crawford, David, Kulbik, Marian Year: 1998 Deteriorated water resources in Central and Eastern Europe call for actions that should be undertaken to improve current conditions and to protect human and environmental health. Mathematical modeling and computer simulation is often an integral part of the decision-making process. Models and simulations allow rapid and varied evaluation of causes and effects and the principal advantage is that they enable an analysis of even long-term actions with limited investment costs. This paper provides an overview of popular models used for simulation of major elements of a water quality system: surface water quality (QUAL2E), wastewater treatment (Activated Sludge Model No.1), sewer network (SWMM), and water distribution network (EPANET). Model uses are illustrated by specific examples both in the U.S. or in Central and Eastern Europe. Close

• 15. [Article] CE-QUAL-W2, Version 3

  CE-QUAL-W2 is a two-dimensional water quality and hydrodynamic code supported by the U.S. Army Engineer Research and Development Center (Cole and Buchak 1995). The model has been widely applied to stratified ...

  Citation × Citation Citation Abstract Copy Title: CE-QUAL-W2, Version 3 Author: Wells, Scott A., Cole, Thomas M. Year: 2000 CE-QUAL-W2 is a two-dimensional water quality and hydrodynamic code supported by the U.S. Army Engineer Research and Development Center (Cole and Buchak 1995). The model has been widely applied to stratified surface water systems such as lakes, reservoirs, and estuaries and computes water levels, horizontal and vertical velocities, temperature, and 21 other water quality parameters (such as dissolved oxygen, nutrients, organic matter, algae, pH, the carbonate cycle, bacteria, and dissolved and suspended solids). A typical model grid is shown in Figure 1 where the vertical axis is aligned with gravity. This technical note documents the development of CE-QUAL-W2, Version 3, which incorporates sloping riverine sections. Version 3 has the capability of modeling entire river basins with rivers and interconnected lakes, reservoirs, and/or estuaries. Four example applications illustrate the use of Version 3. Title: CE-QUAL-W2, Version 3 Author: Wells, Scott A., Cole, Thomas M. Year: 2000 CE-QUAL-W2 is a two-dimensional water quality and hydrodynamic code supported by the U.S. Army Engineer Research and Development Center (Cole and Buchak 1995). The model has been widely applied to stratified surface water systems such as lakes, reservoirs, and estuaries and computes water levels, horizontal and vertical velocities, temperature, and 21 other water quality parameters (such as dissolved oxygen, nutrients, organic matter, algae, pH, the carbonate cycle, bacteria, and dissolved and suspended solids). A typical model grid is shown in Figure 1 where the vertical axis is aligned with gravity. This technical note documents the development of CE-QUAL-W2, Version 3, which incorporates sloping riverine sections. Version 3 has the capability of modeling entire river basins with rivers and interconnected lakes, reservoirs, and/or estuaries. Four example applications illustrate the use of Version 3. Close

• 16. [Article] Hydrogeologic Investigation of a Pumice Aquifer, Fremont/Winema National Forest, Oregon

  The middle Holocene cataclysmic eruption of Mount Mazama blanketed Walker Rim, in south central Oregon, with 270 cm to 300 cm of pumice, causing capture of surface water systems by groundwater, stream ...

  Citation × Citation Citation Abstract Copy Title: Hydrogeologic Investigation of a Pumice Aquifer, Fremont/Winema National Forest, Oregon Author: Weatherford, Jonathan Michael Year: 2015 The middle Holocene cataclysmic eruption of Mount Mazama blanketed Walker Rim, in south central Oregon, with 270 cm to 300 cm of pumice, causing capture of surface water systems by groundwater, stream relocation, and the formation of biologically diverse fens and seasonal wetlands. The pumice aquifer at Round Meadow, an 8.6 km2 basin, hosts both a fen and seasonally ponded wetlands. The Round Meadow watershed lies within a closed basin between the upper Klamath and Deschutes river basins. As the highest meadow at Walker Rim, it is a relatively well-constrained system to study the effects of hydrological disruption. A water budget was calculated for the basin, hydraulic conductivity was evaluated for the three main sediment layers in the meadow, recharge sources and evaporative trends were studied using stable isotope analysis, and aquifer residence times were estimated using CFC tracer water age dating. Water year 2014 was a drought year and observation of the system under stressed conditions allowed discrimination of four independently functioning components of the hydrogeologic system. These were the meadow, which is by far the largest component in terms of water storage, the fen where iron cementation and up to 1 m of peat holds water in a berm above the meadow, three springs which are sourced from deeper groundwater hosted in the bedrock which underlies the pumice deposit, and the outflow area. In all cases, the aquifer material is pumice, but the influence of the pre-eruption landscape and post-eruption modifications of the aquifer material have resulted in partial isolation of the components. The water budget analysis indicated that the basin lost 44 cm of water storage during WY 2014. Hydraulic conductivity values of 1x10-6, 2x10-2, and 4x10-5 cm/s, were determined for the diatomaceous silt underlying the pumice, the Plinian pumice fall aquifer, and for the diatomaceous silt overlying the pumice, respectively. The pumice is characterized as a perched, weakly confined aquifer and residence times in the pumice are much longer (decades) than for water near the surface of the meadow. Water discharging at the springs is isotopically different (lighter) than either the surface water or groundwater in the pumice aquifer. The fen at Round Meadow appears dependent on seasonal precipitation to recharge water, and responds to fluctuations in annual precipitation. The wetland meadows are volumetrically the main water-storing features at Round Meadow, and these are not homogenous features, but a combination of discrete components. Title: Hydrogeologic Investigation of a Pumice Aquifer, Fremont/Winema National Forest, Oregon Author: Weatherford, Jonathan Michael Year: 2015 The middle Holocene cataclysmic eruption of Mount Mazama blanketed Walker Rim, in south central Oregon, with 270 cm to 300 cm of pumice, causing capture of surface water systems by groundwater, stream relocation, and the formation of biologically diverse fens and seasonal wetlands. The pumice aquifer at Round Meadow, an 8.6 km2 basin, hosts both a fen and seasonally ponded wetlands. The Round Meadow watershed lies within a closed basin between the upper Klamath and Deschutes river basins. As the highest meadow at Walker Rim, it is a relatively well-constrained system to study the effects of hydrological disruption. A water budget was calculated for the basin, hydraulic conductivity was evaluated for the three main sediment layers in the meadow, recharge sources and evaporative trends were studied using stable isotope analysis, and aquifer residence times were estimated using CFC tracer water age dating. Water year 2014 was a drought year and observation of the system under stressed conditions allowed discrimination of four independently functioning components of the hydrogeologic system. These were the meadow, which is by far the largest component in terms of water storage, the fen where iron cementation and up to 1 m of peat holds water in a berm above the meadow, three springs which are sourced from deeper groundwater hosted in the bedrock which underlies the pumice deposit, and the outflow area. In all cases, the aquifer material is pumice, but the influence of the pre-eruption landscape and post-eruption modifications of the aquifer material have resulted in partial isolation of the components. The water budget analysis indicated that the basin lost 44 cm of water storage during WY 2014. Hydraulic conductivity values of 1x10-6, 2x10-2, and 4x10-5 cm/s, were determined for the diatomaceous silt underlying the pumice, the Plinian pumice fall aquifer, and for the diatomaceous silt overlying the pumice, respectively. The pumice is characterized as a perched, weakly confined aquifer and residence times in the pumice are much longer (decades) than for water near the surface of the meadow. Water discharging at the springs is isotopically different (lighter) than either the surface water or groundwater in the pumice aquifer. The fen at Round Meadow appears dependent on seasonal precipitation to recharge water, and responds to fluctuations in annual precipitation. The wetland meadows are volumetrically the main water-storing features at Round Meadow, and these are not homogenous features, but a combination of discrete components. Close

• 17. [Article] A Method for Processing Acoustic Doppler Current Profiler Velocity Data from Towed, Undulating Vehicles

  The utility of the acoustic Doppler current profiler (ADCP) for sampling small time and space scales of coastal environments can be enhanced by mounting a high-frequency (1200 kHz) ADCP on an oscillating ...

  Citation × Citation Citation Abstract Copy Title: A Method for Processing Acoustic Doppler Current Profiler Velocity Data from Towed, Undulating Vehicles Author: Jay, David A., Pan, Jiayi Year: 2008 The utility of the acoustic Doppler current profiler (ADCP) for sampling small time and space scales of coastal environments can be enhanced by mounting a high-frequency (1200 kHz) ADCP on an oscillating towed body. This approach requires both an external reference to convert the measured shears to velocities in the earth coordinates and a method to determine the towed body velocities. During the River Influence on the Shelf Ecosystems (RISE) project cruise, a high-frequency (1200 kHz) and narrowbeam ADCP with mode 12 sampling was mounted on a TRIAXUS oscillating towfish, which steers a 3D path behind the ship. This deployment approach extended the vertical range of the ADCP and allowed it to sample near-surface waters outside the ship?s wake. The measurements from a ship-mounted 1200-kHz narrowbeam ADCP are used as references for TRIAXUS ADCP data, and a method of overlapping bins is employed to recover the entire vertical range of the TRIAXUS ADCP. The TRIAXUS vehicle horizontal velocities are obtained by removing the derived ocean current velocity from the TRIAXUS ADCP measurements. The results show that the method is practical. Title: A Method for Processing Acoustic Doppler Current Profiler Velocity Data from Towed, Undulating Vehicles Author: Jay, David A., Pan, Jiayi Year: 2008 The utility of the acoustic Doppler current profiler (ADCP) for sampling small time and space scales of coastal environments can be enhanced by mounting a high-frequency (1200 kHz) ADCP on an oscillating towed body. This approach requires both an external reference to convert the measured shears to velocities in the earth coordinates and a method to determine the towed body velocities. During the River Influence on the Shelf Ecosystems (RISE) project cruise, a high-frequency (1200 kHz) and narrowbeam ADCP with mode 12 sampling was mounted on a TRIAXUS oscillating towfish, which steers a 3D path behind the ship. This deployment approach extended the vertical range of the ADCP and allowed it to sample near-surface waters outside the ship?s wake. The measurements from a ship-mounted 1200-kHz narrowbeam ADCP are used as references for TRIAXUS ADCP data, and a method of overlapping bins is employed to recover the entire vertical range of the TRIAXUS ADCP. The TRIAXUS vehicle horizontal velocities are obtained by removing the derived ocean current velocity from the TRIAXUS ADCP measurements. The results show that the method is practical. Close

• 18. [Article] Restriction mapping and expression of recombinant plasmids containing the arsenic resistance genes of the plasmid R45

  The trivalent (arsenite) and pentavalent (arsenate) forms of arsenic are introduced into the environment through the use of arsenic in herbicides, pesticides, fertilizers, and the smelting of arsenic-bearing ...

  Citation × Citation Citation Abstract Copy Title: Restriction mapping and expression of recombinant plasmids containing the arsenic resistance genes of the plasmid R45 Author: Coons, Terry M. Year: 1986 The trivalent (arsenite) and pentavalent (arsenate) forms of arsenic are introduced into the environment through the use of arsenic in herbicides, pesticides, fertilizers, and the smelting of arsenic-bearing ores. Bacteria resistant to arsenic are readily isolated from surface waters, sewage, and clinical infections. Although some bacterial resistance is provided by inducible phosphate transport systems that discriminate against arsenate, marked resistance is carried on bacterial plasmids. A 6.9 kilobase fragment previously derived from one such plasmid, R45, and containing the genes for inducible resistance to arsenite and arsenate was ligated into the cloning vectors puce and pUC9 in opposite orientations and transformed into Escherichia coli JM 105. Insertion into the multiple cloning site of the pUC vectors places the inserted fragment under the inducible control of the lac operon promoter. An attempt was made to determine the direction of transcription in the fragment by growth in 10-3 M isopropyl-β-D-thiogalactoside prior to challenge with arsenite. Title: Restriction mapping and expression of recombinant plasmids containing the arsenic resistance genes of the plasmid R45 Author: Coons, Terry M. Year: 1986 The trivalent (arsenite) and pentavalent (arsenate) forms of arsenic are introduced into the environment through the use of arsenic in herbicides, pesticides, fertilizers, and the smelting of arsenic-bearing ores. Bacteria resistant to arsenic are readily isolated from surface waters, sewage, and clinical infections. Although some bacterial resistance is provided by inducible phosphate transport systems that discriminate against arsenate, marked resistance is carried on bacterial plasmids. A 6.9 kilobase fragment previously derived from one such plasmid, R45, and containing the genes for inducible resistance to arsenite and arsenate was ligated into the cloning vectors puce and pUC9 in opposite orientations and transformed into Escherichia coli JM 105. Insertion into the multiple cloning site of the pUC vectors places the inserted fragment under the inducible control of the lac operon promoter. An attempt was made to determine the direction of transcription in the fragment by growth in 10-3 M isopropyl-β-D-thiogalactoside prior to challenge with arsenite. Close

• 19. [Article] Characterization of the Shallow Subsurface Geohydrology of the Ni-les'tun Unit on the Bandon Marsh National Wildlife Refuge

  The Bandon Marsh is a large marsh restoration project located in southwest Oregon. The land has been previously used for dairy farms and much of the marsh was used for cattle grazing. The goal of the restoration ...

  Citation × Citation Citation Abstract Copy Title: Characterization of the Shallow Subsurface Geohydrology of the Ni-les'tun Unit on the Bandon Marsh National Wildlife Refuge Author: Beard, Christopher Madison Year: 2013 The Bandon Marsh is a large marsh restoration project located in southwest Oregon. The land has been previously used for dairy farms and much of the marsh was used for cattle grazing. The goal of the restoration is to recreate a natural habitat for shorebirds and fish. The purpose of this thesis is to gather and analyze data on the geology of the marsh and both ground and surface water quality to evaluate its ability to support biology. The US Fish and Wildlife Service began restoration on the Bandon marsh in 2005. Research on the Ni-les'tun Unit began in that same year with Geoprobe coring, Ground Penetrating Radar (GPR), piezometer well installation, and surface water analysis. Twelve cores were taken with the Geoprobe in 2006 and later analyzed for this thesis. A total of 50 GPR lines were run across the marsh ranging from ~25 m to 1,200 m in length for a total of about 9,700 meters (9.7 km). The ten piezometer wells were sampled to collect groundwater pH, oxidation-reduction potential, salinity, temperature, and well water elevation. Twelve channel sampling sites were chosen to be sampled in three field runs taking place in winter 2011, summer 2011, and winter 2012. The summer 2011 and winter 2012 sampling runs were done after tide gates had been removed from the marsh. The Geoprobe core samples were retrieved for extensive lab analysis. Analyses included; bulk density, porosity, permeability, and grain size studies. Lab results revealed a low permeability fine grained upper sedimentary unit ranging from ~0.5 to ~2.5 meters depth with a coarser grained higher permeability lower unit. GPR lines were analyzed for groundwater surface depths and buried channel cut and fill features (Peterson et. al., 2004). GPR results showed a fairly shallow groundwater surface around 0.5 meters in the north down to 2.0 meters in the south. The piezometer wells showed a seasonal variation in well water elevation with higher elevations in the winter and lower in the summer. Well water chemistry showed both seasonal and spatial variations. Values for pH and dissolved oxygen were lower in the north side of the marsh and higher in the south side, and pH was higher in the summer than in the winter. Wells that were more proximal (within ~400 m) to the Coquille River Estuary showed higher conductivity (salinity) values than those that were more distal (greater than ~400 m). Channel sampling results showed similar trends as the groundwater results. The lower pH values tended to be in the north side of the marsh as well as lower dissolved oxygen values. Again, there was a spatial variability in conductivity with the higher values found closer to the Coquille River. Conductivity in the channel water showed a great seasonal variability with the highest values occurring in the summer time and much lower values in the winter. As expected, channel water increased about 10 °C on average from winter to summer. The results of all of these observations and analyses are combined to put together a generalized flow model showing the different water inputs into the channel waters on the Ni-les'tun Unit. Once these inputs were derived, conclusions can be made on the quality of the water and its ability to support small aquatic life. Title: Characterization of the Shallow Subsurface Geohydrology of the Ni-les'tun Unit on the Bandon Marsh National Wildlife Refuge Author: Beard, Christopher Madison Year: 2013 The Bandon Marsh is a large marsh restoration project located in southwest Oregon. The land has been previously used for dairy farms and much of the marsh was used for cattle grazing. The goal of the restoration is to recreate a natural habitat for shorebirds and fish. The purpose of this thesis is to gather and analyze data on the geology of the marsh and both ground and surface water quality to evaluate its ability to support biology. The US Fish and Wildlife Service began restoration on the Bandon marsh in 2005. Research on the Ni-les'tun Unit began in that same year with Geoprobe coring, Ground Penetrating Radar (GPR), piezometer well installation, and surface water analysis. Twelve cores were taken with the Geoprobe in 2006 and later analyzed for this thesis. A total of 50 GPR lines were run across the marsh ranging from ~25 m to 1,200 m in length for a total of about 9,700 meters (9.7 km). The ten piezometer wells were sampled to collect groundwater pH, oxidation-reduction potential, salinity, temperature, and well water elevation. Twelve channel sampling sites were chosen to be sampled in three field runs taking place in winter 2011, summer 2011, and winter 2012. The summer 2011 and winter 2012 sampling runs were done after tide gates had been removed from the marsh. The Geoprobe core samples were retrieved for extensive lab analysis. Analyses included; bulk density, porosity, permeability, and grain size studies. Lab results revealed a low permeability fine grained upper sedimentary unit ranging from ~0.5 to ~2.5 meters depth with a coarser grained higher permeability lower unit. GPR lines were analyzed for groundwater surface depths and buried channel cut and fill features (Peterson et. al., 2004). GPR results showed a fairly shallow groundwater surface around 0.5 meters in the north down to 2.0 meters in the south. The piezometer wells showed a seasonal variation in well water elevation with higher elevations in the winter and lower in the summer. Well water chemistry showed both seasonal and spatial variations. Values for pH and dissolved oxygen were lower in the north side of the marsh and higher in the south side, and pH was higher in the summer than in the winter. Wells that were more proximal (within ~400 m) to the Coquille River Estuary showed higher conductivity (salinity) values than those that were more distal (greater than ~400 m). Channel sampling results showed similar trends as the groundwater results. The lower pH values tended to be in the north side of the marsh as well as lower dissolved oxygen values. Again, there was a spatial variability in conductivity with the higher values found closer to the Coquille River. Conductivity in the channel water showed a great seasonal variability with the highest values occurring in the summer time and much lower values in the winter. As expected, channel water increased about 10 °C on average from winter to summer. The results of all of these observations and analyses are combined to put together a generalized flow model showing the different water inputs into the channel waters on the Ni-les'tun Unit. Once these inputs were derived, conclusions can be made on the quality of the water and its ability to support small aquatic life. Close

• 20. [Article] Investigating the Link Between Surface Water and Groundwater in the Tule Lake Subbasin, Oregon and California

  Water allocation in the upper Klamath Basin of Oregon and California has been challenging. Irrigators have increasingly turned to groundwater to make up for surface water shortages because of shifts in ...

  Citation × Citation Citation Abstract Copy Title: Investigating the Link Between Surface Water and Groundwater in the Tule Lake Subbasin, Oregon and California Author: Pischel, Esther Maria Year: 2014 Water allocation in the upper Klamath Basin of Oregon and California has been challenging. Irrigators have increasingly turned to groundwater to make up for surface water shortages because of shifts in allocation toward in-stream flows for Endangered Species Act listed fishes. The largest increase in groundwater pumping has been in and around the Bureau of Reclamation's Klamath Irrigation Project, which includes the Tule Lake subbasin in the southern part of the upper Klamath Basin. Previous groundwater flow model simulations indicate that water level declines from pumping may result in decreased flow to agricultural drains in the Tule Lake subbasin. Agricultural drains on the Klamath Project are an important source of water for downstream irrigators and for the Tule Lake and Lower Klamath Lake National Wildlife Refuges. To better assess the impact of increased pumping on drain flow and on the water balance of the groundwater system, flow data from agricultural drains were evaluated to investigate the changes that have taken place in groundwater discharge to drains since pumping volumes increased. Additionally, a fine-grid groundwater model of the Tule Lake subbasin was developed based on the existing regional flow model. The fine-grid model has sufficient vertical and horizontal resolution to simulate vertical head gradients, takes advantage of time-series data from 38 observation wells for model calibration, and allows agricultural drains to be more explicitly represented. Results of the drain flow analysis show that the groundwater discharge to agricultural drains has decreased by approximately 4000 hectare-meters from the 1997-2000 average discharge. Most of this decrease takes place in the northern and southeastern portions of the subbasin. Results of the groundwater model show that the initial source of water to wells is groundwater storage. By 2006, approximately 56% of the water from wells is sourced from agricultural drains. Title: Investigating the Link Between Surface Water and Groundwater in the Tule Lake Subbasin, Oregon and California Author: Pischel, Esther Maria Year: 2014 Water allocation in the upper Klamath Basin of Oregon and California has been challenging. Irrigators have increasingly turned to groundwater to make up for surface water shortages because of shifts in allocation toward in-stream flows for Endangered Species Act listed fishes. The largest increase in groundwater pumping has been in and around the Bureau of Reclamation's Klamath Irrigation Project, which includes the Tule Lake subbasin in the southern part of the upper Klamath Basin. Previous groundwater flow model simulations indicate that water level declines from pumping may result in decreased flow to agricultural drains in the Tule Lake subbasin. Agricultural drains on the Klamath Project are an important source of water for downstream irrigators and for the Tule Lake and Lower Klamath Lake National Wildlife Refuges. To better assess the impact of increased pumping on drain flow and on the water balance of the groundwater system, flow data from agricultural drains were evaluated to investigate the changes that have taken place in groundwater discharge to drains since pumping volumes increased. Additionally, a fine-grid groundwater model of the Tule Lake subbasin was developed based on the existing regional flow model. The fine-grid model has sufficient vertical and horizontal resolution to simulate vertical head gradients, takes advantage of time-series data from 38 observation wells for model calibration, and allows agricultural drains to be more explicitly represented. Results of the drain flow analysis show that the groundwater discharge to agricultural drains has decreased by approximately 4000 hectare-meters from the 1997-2000 average discharge. Most of this decrease takes place in the northern and southeastern portions of the subbasin. Results of the groundwater model show that the initial source of water to wells is groundwater storage. By 2006, approximately 56% of the water from wells is sourced from agricultural drains. Close

• 21. [Article] Investigation and Evaluation of Current and Emerging Whole-Water Sampling Technologies for U.S. Geological Survey National Water Quality Assessment Program

  An investigation was conducted into current and emerging surface water sampling technologies. These technologies were compared and recommendations given to the United States Geological Survey (USGS) for ...

  Citation × Citation Citation Abstract Copy Title: Investigation and Evaluation of Current and Emerging Whole-Water Sampling Technologies for U.S. Geological Survey National Water Quality Assessment Program Author: Gareau, Keith D. Year: 2011 An investigation was conducted into current and emerging surface water sampling technologies. These technologies were compared and recommendations given to the United States Geological Survey (USGS) for adoption by the National Water Quality Assessment (NAWQA) Program. The goal is to reduce labor costs and increase information content. This paper examines lotic system samplers, portable autonomous whole-water samplers, and autonomous submergible whole-water samplers. When investigating whole-water sampling technology, it was imperative to take into consideration what chemical classifications can be sampled for by each respected technology. Chemical classifications considered are: emerging contaminants, major ions, nutrients, polychlorinated biphenyls, pesticides, volatile and semi-volatile organic compounds, and trace elements. The result of this project shows that USGS is currently using the best technology available for lotic systems. For portable autonomous whole-water samplers it is recommended that USGS incorporate certain brands and models to reduce cost and improve data collection for their sampling events. Autonomous submergible whole-water samplers are primarily advertised for oceanic research; however, if deployed in fresh water systems, USGS can reduce labor cost and increase data collection. In terms of emerging technology, it has been recommended to USGS to consider recent patents. Title: Investigation and Evaluation of Current and Emerging Whole-Water Sampling Technologies for U.S. Geological Survey National Water Quality Assessment Program Author: Gareau, Keith D. Year: 2011 An investigation was conducted into current and emerging surface water sampling technologies. These technologies were compared and recommendations given to the United States Geological Survey (USGS) for adoption by the National Water Quality Assessment (NAWQA) Program. The goal is to reduce labor costs and increase information content. This paper examines lotic system samplers, portable autonomous whole-water samplers, and autonomous submergible whole-water samplers. When investigating whole-water sampling technology, it was imperative to take into consideration what chemical classifications can be sampled for by each respected technology. Chemical classifications considered are: emerging contaminants, major ions, nutrients, polychlorinated biphenyls, pesticides, volatile and semi-volatile organic compounds, and trace elements. The result of this project shows that USGS is currently using the best technology available for lotic systems. For portable autonomous whole-water samplers it is recommended that USGS incorporate certain brands and models to reduce cost and improve data collection for their sampling events. Autonomous submergible whole-water samplers are primarily advertised for oceanic research; however, if deployed in fresh water systems, USGS can reduce labor cost and increase data collection. In terms of emerging technology, it has been recommended to USGS to consider recent patents. Close

• 22. [Article] The Atmosphere can be a Source of Certain Water Soluble Volatile Organic Compounds in Urban Streams

  Surface water and air volatile organic compound (VOC) data from 10 U. S. Geological Survey monitoring sites were used to evaluate the potential for direct transport of VOCs from the atmosphere to urban ...

  Citation × Citation Citation Abstract Copy Title: The Atmosphere can be a Source of Certain Water Soluble Volatile Organic Compounds in Urban Streams Author: Kenner, Scott J, Bender, David A., Pankow, James F., Zogorski, John S. Year: 2014 Surface water and air volatile organic compound (VOC) data from 10 U. S. Geological Survey monitoring sites were used to evaluate the potential for direct transport of VOCs from the atmosphere to urban streams. Analytical results of 87 VOC compounds were screened by evaluating the occurrence and detection levels in both water and air, and equilibrium concentrations in water (C-w(s)) based on the measured air concentrations. Four compounds (acetone, methyl tertiary butyl ether, toluene, and m- & p-xylene) were detected in more than 20% of water samples, in more than 10% of air samples, and more than 10% of detections in air were greater than long-term method detection levels (LTMDL) in water. Benzene was detected in more than 20% of water samples and in more than 10% of air samples. Two percent of benzene detections in air were greater than one-half the LTMDL in water. Six compounds (chloroform, p-isopropyltoluene, methylene chloride, perchloroethene, 1,1,1-trichloroethane, and trichloroethene) were detected in more than 20% of water samples and in more than 10% of air samples. Five VOCs, toluene, m- & p-xylene, methyl tert-butyl ether (MTBE), acetone, and benzene were identified as having sufficiently high concentrations in the atmosphere to be a source to urban streams. MTBE, acetone, and benzene exhibited behavior that was consistent with equilibrium concentrations in the atmosphere. Title: The Atmosphere can be a Source of Certain Water Soluble Volatile Organic Compounds in Urban Streams Author: Kenner, Scott J, Bender, David A., Pankow, James F., Zogorski, John S. Year: 2014 Surface water and air volatile organic compound (VOC) data from 10 U. S. Geological Survey monitoring sites were used to evaluate the potential for direct transport of VOCs from the atmosphere to urban streams. Analytical results of 87 VOC compounds were screened by evaluating the occurrence and detection levels in both water and air, and equilibrium concentrations in water (C-w(s)) based on the measured air concentrations. Four compounds (acetone, methyl tertiary butyl ether, toluene, and m- & p-xylene) were detected in more than 20% of water samples, in more than 10% of air samples, and more than 10% of detections in air were greater than long-term method detection levels (LTMDL) in water. Benzene was detected in more than 20% of water samples and in more than 10% of air samples. Two percent of benzene detections in air were greater than one-half the LTMDL in water. Six compounds (chloroform, p-isopropyltoluene, methylene chloride, perchloroethene, 1,1,1-trichloroethane, and trichloroethene) were detected in more than 20% of water samples and in more than 10% of air samples. Five VOCs, toluene, m- & p-xylene, methyl tert-butyl ether (MTBE), acetone, and benzene were identified as having sufficiently high concentrations in the atmosphere to be a source to urban streams. MTBE, acetone, and benzene exhibited behavior that was consistent with equilibrium concentrations in the atmosphere. Close

• 23. [Article] A New Era of Water Quality Management in Agriculture: From Best Management Practices to Watershed-based Whole Farm Approaches

  Why is reducing water pollution from agriculture such a stubbornly slow process? Despite several policy initiatives since the 1970s, farms and ranches rank as the primary contributors to impairments of ...

  Citation × Citation Citation Abstract Copy Title: A New Era of Water Quality Management in Agriculture: From Best Management Practices to Watershed-based Whole Farm Approaches Author: Ervin, David E. Year: 1995 Why is reducing water pollution from agriculture such a stubbornly slow process? Despite several policy initiatives since the 1970s, farms and ranches rank as the primary contributors to impairments of the nation's surface waters [U.S.EPA, 1994b]. Emerging research also points to agricultural chemicals in many cases of groundwater contamination [Barbash and Resek; Mueller, et al.]. After a little reflection, the industry's negative distinction may not be surprising. Covering nearly half the U.S. land base, crop and livestock production inevitably alter natural vegetative cover, apply fertilizers, pesticides and irrigation water, and involve animal wastes. All of these processes can degrade water quality. Without question, cases of water quality improvement as well as degradation occur within agriculture's number one ranking. Stream, lake, and groundwater success stories have come from federal, state, and local efforts. However, the overall weight of the evidence indicates the industry's performance needs to improve rather sharply if the nation's water quality is to advance to a higher plateau in line with broad public preference. This paper's central thesis is that dramatic changes in program approaches are necessary for that advance because of powerful budget, economic, and political forces. Continued reliance on programs subsidizing or regulating best management practices (BMPs) conflicts with those forces in fundamental ways. Moreover, promising technologies and improved water quality science support more flexible, whole farm approaches for targeted priority watersheds. Title: A New Era of Water Quality Management in Agriculture: From Best Management Practices to Watershed-based Whole Farm Approaches Author: Ervin, David E. Year: 1995 Why is reducing water pollution from agriculture such a stubbornly slow process? Despite several policy initiatives since the 1970s, farms and ranches rank as the primary contributors to impairments of the nation's surface waters [U.S.EPA, 1994b]. Emerging research also points to agricultural chemicals in many cases of groundwater contamination [Barbash and Resek; Mueller, et al.]. After a little reflection, the industry's negative distinction may not be surprising. Covering nearly half the U.S. land base, crop and livestock production inevitably alter natural vegetative cover, apply fertilizers, pesticides and irrigation water, and involve animal wastes. All of these processes can degrade water quality. Without question, cases of water quality improvement as well as degradation occur within agriculture's number one ranking. Stream, lake, and groundwater success stories have come from federal, state, and local efforts. However, the overall weight of the evidence indicates the industry's performance needs to improve rather sharply if the nation's water quality is to advance to a higher plateau in line with broad public preference. This paper's central thesis is that dramatic changes in program approaches are necessary for that advance because of powerful budget, economic, and political forces. Continued reliance on programs subsidizing or regulating best management practices (BMPs) conflicts with those forces in fundamental ways. Moreover, promising technologies and improved water quality science support more flexible, whole farm approaches for targeted priority watersheds. Close

• 24. [Article] Characterization of Mesoscopic Fluid-like Films with the Novel Shear-force/Acoustic Microscopy

  The shear force mechanism has been utilized as a distance regulation method in scanning probe microscopes. However, the origin of shear force is still unclear. One of the most important reasons for the ...

  Citation × Citation Citation Abstract Copy Title: Characterization of Mesoscopic Fluid-like Films with the Novel Shear-force/Acoustic Microscopy Author: Wang, Xiaohua Year: 2010 The shear force mechanism has been utilized as a distance regulation method in scanning probe microscopes. However, the origin of shear force is still unclear. One of the most important reasons for the shear-force damping is due to the presence of a water contamination layer at the sample surface in ambient conditions. Understanding the behavior of such mesoscopic fluid-like films is of significance for studies of not only scanning probe microscopy but also other complex surface phenomena, such as nanotribology, lubrication, adhesion, wetting, and the microfluidity of biological membranes. This thesis investigates, in particular, the dynamics of mesoscopic fluids confined between two sliding solid boundaries. When fluids are constrained to nanometer-sized regions, their physical properties can greatly differ from those displayed by bulk liquids. To gain an insight into the fundamental characteristics of the confined fluid films, we exploit the versatile capabilities of the novel shear-force/acoustic near-field microscope (SANM), which is able to concurrently and independently monitor the effects of the fluid-mediated interactions acting on both the microscope's probe and the sample to be analyzed. Two signals are monitored simultaneously during each experimental cycle: the tuning fork signal, which is the oscillation amplitude of the probe and gives access to the shear force; and acoustic signal, which is detected by an acoustic sensor placed under the sample. Systematic experiments are carried out to investigate the effects of probe geometry, environmental humidity, and chemical properties of probe and sample surface (water affinity: hydrophobicity or hydrophilicity) on the probe-sample interactions, expressing the influence of the fluid-like contamination films. Title: Characterization of Mesoscopic Fluid-like Films with the Novel Shear-force/Acoustic Microscopy Author: Wang, Xiaohua Year: 2010 The shear force mechanism has been utilized as a distance regulation method in scanning probe microscopes. However, the origin of shear force is still unclear. One of the most important reasons for the shear-force damping is due to the presence of a water contamination layer at the sample surface in ambient conditions. Understanding the behavior of such mesoscopic fluid-like films is of significance for studies of not only scanning probe microscopy but also other complex surface phenomena, such as nanotribology, lubrication, adhesion, wetting, and the microfluidity of biological membranes. This thesis investigates, in particular, the dynamics of mesoscopic fluids confined between two sliding solid boundaries. When fluids are constrained to nanometer-sized regions, their physical properties can greatly differ from those displayed by bulk liquids. To gain an insight into the fundamental characteristics of the confined fluid films, we exploit the versatile capabilities of the novel shear-force/acoustic near-field microscope (SANM), which is able to concurrently and independently monitor the effects of the fluid-mediated interactions acting on both the microscope's probe and the sample to be analyzed. Two signals are monitored simultaneously during each experimental cycle: the tuning fork signal, which is the oscillation amplitude of the probe and gives access to the shear force; and acoustic signal, which is detected by an acoustic sensor placed under the sample. Systematic experiments are carried out to investigate the effects of probe geometry, environmental humidity, and chemical properties of probe and sample surface (water affinity: hydrophobicity or hydrophilicity) on the probe-sample interactions, expressing the influence of the fluid-like contamination films. Close

• 25. [Article] The Small Volume Autonomous Water Sampler (SVAWS): An Innovative, Cost- Effective, Adaptable Protocol

  As of 2007, U.S. pesticide use stood at 1.1 billion pounds with 80% of all usage in agriculture. Such realities pose a potentially dangerous threat to our surface water bodies. This research provides a ...

  Citation × Citation Citation Abstract Copy Title: The Small Volume Autonomous Water Sampler (SVAWS): An Innovative, Cost- Effective, Adaptable Protocol Author: Fitzgerald, Nicholas B Year: 2014 As of 2007, U.S. pesticide use stood at 1.1 billion pounds with 80% of all usage in agriculture. Such realities pose a potentially dangerous threat to our surface water bodies. This research provides a detailed analysis of the design, operation and field testing of a prototype water sampler, the Small Volume Autonomous Water Sampler (SVAWS). The research includes a discussion of the design and construction of the SVAWS. Seven USGS employees operated the SVAWS in a number of different states and conditions in order to collect samples for pesticide analysis. Field-testing outcomes of the SVAWS were measured through a Participant Survey Request and a Likert-Scale Assessment. Overall, survey data proved the SVAWS to be an effective device for collecting water samples in different locations and conditions. Users also understood the SVAWS has significant potential for applications other than pesticide studies. While feedback did show a number of alterations or modifications could improve the design, the device proved to be effective across many of its goals, from valid water sampling to reducing costs of sample acquisition. Recommendations for future research include these and other avenues of research. A conclusion addresses the potential future of the SVAWS with respect to water sampling applications. Title: The Small Volume Autonomous Water Sampler (SVAWS): An Innovative, Cost- Effective, Adaptable Protocol Author: Fitzgerald, Nicholas B Year: 2014 As of 2007, U.S. pesticide use stood at 1.1 billion pounds with 80% of all usage in agriculture. Such realities pose a potentially dangerous threat to our surface water bodies. This research provides a detailed analysis of the design, operation and field testing of a prototype water sampler, the Small Volume Autonomous Water Sampler (SVAWS). The research includes a discussion of the design and construction of the SVAWS. Seven USGS employees operated the SVAWS in a number of different states and conditions in order to collect samples for pesticide analysis. Field-testing outcomes of the SVAWS were measured through a Participant Survey Request and a Likert-Scale Assessment. Overall, survey data proved the SVAWS to be an effective device for collecting water samples in different locations and conditions. Users also understood the SVAWS has significant potential for applications other than pesticide studies. While feedback did show a number of alterations or modifications could improve the design, the device proved to be effective across many of its goals, from valid water sampling to reducing costs of sample acquisition. Recommendations for future research include these and other avenues of research. A conclusion addresses the potential future of the SVAWS with respect to water sampling applications. Close

• 26. [Article] Hydrogeologic Investigation of the Klamath Marsh, Klamath County, Oregon

  Klamath Marsh is a wetland complex that lies in the rain shadow of the Cascade Range in the Williamson River sub-basin of the Klamath Basin. The marsh lies directly east of Crater Lake in an area inundated ...

  Citation × Citation Citation Abstract Copy Title: Hydrogeologic Investigation of the Klamath Marsh, Klamath County, Oregon Author: Melady, Jason Michael Year: 2002 Klamath Marsh is a wetland complex that lies in the rain shadow of the Cascade Range in the Williamson River sub-basin of the Klamath Basin. The marsh lies directly east of Crater Lake in an area inundated by pyroclastic-flow and -fall deposits from the Holocene eruptions of Mount Mazama. The physical characteristics of rocks of Pleistocene versus Pliocene age combined with NNW -striking fault systems divide the Williamson River basin into two distinct hydrogeologic regimes. The northwestern regime includes the east slope of the Cascades and consists of at least 150 m of interbedded sand, gravel, and stacks (15 to 45 m) of thin (3-5 m) and vesiculated basalt lava flows. Mean annual precipitation ranges from 150 cm near the crest of the Cascades to 50 cm near Klamath Marsh. Moderate to high yield (100 to 4000 gpm) water wells, springs and flowing wells suggest high permeability and ground water potential. The southeastern regime is underlain by Pliocene pyroclastic flows (∼ 40 m) and lava flows (>30 m). Mean annual precipitation ranges from 70 cm in the highlands to 50 cm in the lowlands. Low-yield (20-100 gpm) water wells and perched unconfined aquifers in Holocene pumice deposits suggest low permeability and low ground water potential in areas underlain by the pyroclastic flows. Volumetric analysis of inflows and outflows in Klamath Marsh for 2000 indicates approximately 86% of inflow is from groundwater and 14% from surface water, with nearly 200 x 10⁶ m³ of water removed by evapotranspiration Title: Hydrogeologic Investigation of the Klamath Marsh, Klamath County, Oregon Author: Melady, Jason Michael Year: 2002 Klamath Marsh is a wetland complex that lies in the rain shadow of the Cascade Range in the Williamson River sub-basin of the Klamath Basin. The marsh lies directly east of Crater Lake in an area inundated by pyroclastic-flow and -fall deposits from the Holocene eruptions of Mount Mazama. The physical characteristics of rocks of Pleistocene versus Pliocene age combined with NNW -striking fault systems divide the Williamson River basin into two distinct hydrogeologic regimes. The northwestern regime includes the east slope of the Cascades and consists of at least 150 m of interbedded sand, gravel, and stacks (15 to 45 m) of thin (3-5 m) and vesiculated basalt lava flows. Mean annual precipitation ranges from 150 cm near the crest of the Cascades to 50 cm near Klamath Marsh. Moderate to high yield (100 to 4000 gpm) water wells, springs and flowing wells suggest high permeability and ground water potential. The southeastern regime is underlain by Pliocene pyroclastic flows (∼ 40 m) and lava flows (>30 m). Mean annual precipitation ranges from 70 cm in the highlands to 50 cm in the lowlands. Low-yield (20-100 gpm) water wells and perched unconfined aquifers in Holocene pumice deposits suggest low permeability and low ground water potential in areas underlain by the pyroclastic flows. Volumetric analysis of inflows and outflows in Klamath Marsh for 2000 indicates approximately 86% of inflow is from groundwater and 14% from surface water, with nearly 200 x 10⁶ m³ of water removed by evapotranspiration Close

• 27. [Article] Greenhouse Gas Fluxes in Southeastern U.S. Coastal Plain Wetlands Under Contrasting Land Uses

  Whether through sea level rise or wetland restoration, agricultural soils in coastal areas will be inundated at increasing rates, renewing connections to sensitive surface waters and raising critical questions ...

  Citation × Citation Citation Abstract Copy Title: Greenhouse Gas Fluxes in Southeastern U.S. Coastal Plain Wetlands Under Contrasting Land Uses Author: Morse, Jennifer L., Ardón, Marcelo, Bernhardt, Emily S. Year: 2012 Whether through sea level rise or wetland restoration, agricultural soils in coastal areas will be inundated at increasing rates, renewing connections to sensitive surface waters and raising critical questions about environmental trade-offs. Wetland restoration is often implemented in agricultural catchments to improve water quality through nutrient removal. Yet flooding of soils can also increase production of the greenhouse gases nitrous oxide and methane, representing a potential environmental trade-off. Our study aimed to quantify and compare greenhouse gas emissions from unmanaged and restored forested wetlands, as well as actively managed agricultural fields within the North Carolina coastal plain, USA. In sampling conducted once every two months over a two-year comparative study, we found that soil carbon dioxide flux (range: 8000–64 800 kg CO2·ha-1· yr-1) comprised 66–100% of total greenhouse gas emissions from all sites and that methane emissions (range: -6.87 to 197 kg CH4·ha-1·yr-1) were highest from permanently inundated sites, while nitrous oxide fluxes (range: -1.07 to 139 kg N2O·ha-1·yr-1) were highest in sites with lower water tables. Contrary to predictions, greenhouse gas fluxes (as CO2 equivalents) from the restored wetland were lower than from either agricultural fields or unmanaged forested wetlands. In these acidic coastal freshwater ecosystems, the conversion of agricultural fields to flooded young forested wetlands did not result in increases in greenhouse gas emissions. Title: Greenhouse Gas Fluxes in Southeastern U.S. Coastal Plain Wetlands Under Contrasting Land Uses Author: Morse, Jennifer L., Ardón, Marcelo, Bernhardt, Emily S. Year: 2012 Whether through sea level rise or wetland restoration, agricultural soils in coastal areas will be inundated at increasing rates, renewing connections to sensitive surface waters and raising critical questions about environmental trade-offs. Wetland restoration is often implemented in agricultural catchments to improve water quality through nutrient removal. Yet flooding of soils can also increase production of the greenhouse gases nitrous oxide and methane, representing a potential environmental trade-off. Our study aimed to quantify and compare greenhouse gas emissions from unmanaged and restored forested wetlands, as well as actively managed agricultural fields within the North Carolina coastal plain, USA. In sampling conducted once every two months over a two-year comparative study, we found that soil carbon dioxide flux (range: 8000–64 800 kg CO2·ha-1· yr-1) comprised 66–100% of total greenhouse gas emissions from all sites and that methane emissions (range: -6.87 to 197 kg CH4·ha-1·yr-1) were highest from permanently inundated sites, while nitrous oxide fluxes (range: -1.07 to 139 kg N2O·ha-1·yr-1) were highest in sites with lower water tables. Contrary to predictions, greenhouse gas fluxes (as CO2 equivalents) from the restored wetland were lower than from either agricultural fields or unmanaged forested wetlands. In these acidic coastal freshwater ecosystems, the conversion of agricultural fields to flooded young forested wetlands did not result in increases in greenhouse gas emissions. Close

• 28. [Article] Streamflow Analysis and a Comparison of Hydrologic Metrics in Urban Streams

  This study investigates the hydrologic effects of urbanization in two Portland, Oregon streams through a comparison of three hydrologic metrics. Hydrologic metrics used in this study are the mean annual ...

  Citation × Citation Citation Abstract Copy Title: Streamflow Analysis and a Comparison of Hydrologic Metrics in Urban Streams Author: Wood, Matthew Lawton Year: 2012 This study investigates the hydrologic effects of urbanization in two Portland, Oregon streams through a comparison of three hydrologic metrics. Hydrologic metrics used in this study are the mean annual runoff ratio (Qa), mean seasonal runoff ratio (Qw and Qd), and the fraction of time that streamflow exceeds the mean streamflow during the year (TQmean). Additionally, the relative change in streamflow in response to storm events was examined for two watersheds. For this investigation urban development is represented by two urbanization metrics: percent impervious and road density. Descriptive and inferential statistics were used to evaluate the relationship between the hydrologic metrics and the amount of urban development in each watershed. The effect of watershed size was also investigated using nested watersheds, with watershed size ranging from 6 km2 to 138km 2. The results indicate that annual and seasonal runoff ratios have difficulty capturing the dynamic hydrologic behavior in urban watersheds. TQmean was useful at capturing the flashy behavior of the Upper Fanno watershed, however it did not perform as well in Kelley watershed possibly due to the influence of impermeable soils and steep slopes. Unexpected values for hydrologic metrics in Lower Johnson, Sycamore and Kelley watersheds could be the result water collection systems that appear to route surface water outside of their watersheds as well as permeable soils. Storm event analysis was effective at characterizing the behavior for the selected watersheds, indicating that shorter time scales may best capture the dynamic behavior of urban watersheds. Title: Streamflow Analysis and a Comparison of Hydrologic Metrics in Urban Streams Author: Wood, Matthew Lawton Year: 2012 This study investigates the hydrologic effects of urbanization in two Portland, Oregon streams through a comparison of three hydrologic metrics. Hydrologic metrics used in this study are the mean annual runoff ratio (Qa), mean seasonal runoff ratio (Qw and Qd), and the fraction of time that streamflow exceeds the mean streamflow during the year (TQmean). Additionally, the relative change in streamflow in response to storm events was examined for two watersheds. For this investigation urban development is represented by two urbanization metrics: percent impervious and road density. Descriptive and inferential statistics were used to evaluate the relationship between the hydrologic metrics and the amount of urban development in each watershed. The effect of watershed size was also investigated using nested watersheds, with watershed size ranging from 6 km2 to 138km 2. The results indicate that annual and seasonal runoff ratios have difficulty capturing the dynamic hydrologic behavior in urban watersheds. TQmean was useful at capturing the flashy behavior of the Upper Fanno watershed, however it did not perform as well in Kelley watershed possibly due to the influence of impermeable soils and steep slopes. Unexpected values for hydrologic metrics in Lower Johnson, Sycamore and Kelley watersheds could be the result water collection systems that appear to route surface water outside of their watersheds as well as permeable soils. Storm event analysis was effective at characterizing the behavior for the selected watersheds, indicating that shorter time scales may best capture the dynamic behavior of urban watersheds. Close

• 29. [Article] Dynamics of Channel Complexity and Nitrate Retention in Upper Fanno Creek, Oregon

  This study investigates the relationship between channel complexity and nutrient spiraling along 31 reaches of an urbanized watershed in Portland, Oregon. Much research shows that urbanization has an effect ...

  Citation × Citation Citation Abstract Copy Title: Dynamics of Channel Complexity and Nitrate Retention in Upper Fanno Creek, Oregon Author: Bean, Robert Allen Year: 2012 This study investigates the relationship between channel complexity and nutrient spiraling along 31 reaches of an urbanized watershed in Portland, Oregon. Much research shows that urbanization has an effect on watershed hydrology and nutrient loading at the watershed scale for various sized catchments. However, the flux of nutrients over short reaches within a stream channel has been less studied because of the effort and costs associated with fieldwork and subsequent laboratory analysis of the surface water samples. In this study I measure channel complexity and uptake velocity of nitrate to determine if this relationship is indicative of a healthy, functioning stream. I take field measurements and samples to determine the complexity and uptake velocity of each reach. Using ion-selective electrodes, the fluxes of nitrate were measured within each reach; when combined with channel geometry and velocity measurements these measurements allow for the transformation of nitrate fluxes into spiraling metrics. Results show that 18 of the 31 reaches had uptake velocity. Discharge and sinuosity were positively correlated with nitrate uptake velocity. Complexity and nitrate concentration were negatively correlated with nitrate uptake velocity. Grass landcover was positively correlated with nitrate uptake velocity and negatively correlated with nitrate concentration. These results indicate that land use and channel complexity both are related to the in-stream processing of nitrate. The implication of this study is that channel complexity is an important driver of nutrient flux in an urban watershed, and that this technique can be applied in future studies to better characterize water quality of stream channels over short reaches to entire catchments. Title: Dynamics of Channel Complexity and Nitrate Retention in Upper Fanno Creek, Oregon Author: Bean, Robert Allen Year: 2012 This study investigates the relationship between channel complexity and nutrient spiraling along 31 reaches of an urbanized watershed in Portland, Oregon. Much research shows that urbanization has an effect on watershed hydrology and nutrient loading at the watershed scale for various sized catchments. However, the flux of nutrients over short reaches within a stream channel has been less studied because of the effort and costs associated with fieldwork and subsequent laboratory analysis of the surface water samples. In this study I measure channel complexity and uptake velocity of nitrate to determine if this relationship is indicative of a healthy, functioning stream. I take field measurements and samples to determine the complexity and uptake velocity of each reach. Using ion-selective electrodes, the fluxes of nitrate were measured within each reach; when combined with channel geometry and velocity measurements these measurements allow for the transformation of nitrate fluxes into spiraling metrics. Results show that 18 of the 31 reaches had uptake velocity. Discharge and sinuosity were positively correlated with nitrate uptake velocity. Complexity and nitrate concentration were negatively correlated with nitrate uptake velocity. Grass landcover was positively correlated with nitrate uptake velocity and negatively correlated with nitrate concentration. These results indicate that land use and channel complexity both are related to the in-stream processing of nitrate. The implication of this study is that channel complexity is an important driver of nutrient flux in an urban watershed, and that this technique can be applied in future studies to better characterize water quality of stream channels over short reaches to entire catchments. Close

• 30. [Article] Drought Analysis under Climate Change by Application of Drought Indices and Copulas

  Drought is a recurrent extreme climate event with tremendous hazard for every specter of natural environment and human lives. Drought analysis usually involves characterizing drought severity, duration ...

  Citation × Citation Citation Abstract Copy Title: Drought Analysis under Climate Change by Application of Drought Indices and Copulas Author: Yang, Wen Year: 2010 Drought is a recurrent extreme climate event with tremendous hazard for every specter of natural environment and human lives. Drought analysis usually involves characterizing drought severity, duration and intensity. Similar to most of the hydrological problems, such characteristic variables are usually not independent. Copula, as a model of multivariate distribution, widely used in finance, actuarial analysis, has won increasingly popularity in hydrological study. Here, the study has two major focuses: (1) fit drought characteristics from Streamflow Drought Index (SDI) or Standardized Runoff Index (SRI) to appropriate copulas, then using fitted copulas to estimate conditional drought severity distribution and joint return periods for both historical time period 1920-2009 and future time period 2020-2090. SDI is calculated based on long term observed streamflow while SRI is based on simulated future runoff. Parameters estimation of marginal distribution and copulas are provided, with goodness fit measures as well; (2) investigate the effects of climate change on the frequency and severity of droughts. In order to quantify the impact, three drought indices have been proposed for this study to characterize the drought duration, severity and intensity changes under the climate change in Upper Klamath River Basin. Since drought can be defined as different types, such as meteorological drought, agricultural drought, hydrological drought and social economical drought, this study chooses Standardized Precipitation Index (SPI), Palmer Drought Severity Index (PDSI) and Surface Water Supply Index (SWSI) to estimate the meteorological, agricultural and hydrological drought, respectively. Climate change effects come from three sources: the inherent reason, the human activity and the GCMs uncertainties. Therefore, the results show the long term drought condition by calculating yearly drought indices, and compared in three ways: First, compare drought characteristics of future time periods with base period; second, show the uncertainties of three greenhouse gas emission scenarios; third, present the uncertainties of six General Circulation Models (GCMs). Title: Drought Analysis under Climate Change by Application of Drought Indices and Copulas Author: Yang, Wen Year: 2010 Drought is a recurrent extreme climate event with tremendous hazard for every specter of natural environment and human lives. Drought analysis usually involves characterizing drought severity, duration and intensity. Similar to most of the hydrological problems, such characteristic variables are usually not independent. Copula, as a model of multivariate distribution, widely used in finance, actuarial analysis, has won increasingly popularity in hydrological study. Here, the study has two major focuses: (1) fit drought characteristics from Streamflow Drought Index (SDI) or Standardized Runoff Index (SRI) to appropriate copulas, then using fitted copulas to estimate conditional drought severity distribution and joint return periods for both historical time period 1920-2009 and future time period 2020-2090. SDI is calculated based on long term observed streamflow while SRI is based on simulated future runoff. Parameters estimation of marginal distribution and copulas are provided, with goodness fit measures as well; (2) investigate the effects of climate change on the frequency and severity of droughts. In order to quantify the impact, three drought indices have been proposed for this study to characterize the drought duration, severity and intensity changes under the climate change in Upper Klamath River Basin. Since drought can be defined as different types, such as meteorological drought, agricultural drought, hydrological drought and social economical drought, this study chooses Standardized Precipitation Index (SPI), Palmer Drought Severity Index (PDSI) and Surface Water Supply Index (SWSI) to estimate the meteorological, agricultural and hydrological drought, respectively. Climate change effects come from three sources: the inherent reason, the human activity and the GCMs uncertainties. Therefore, the results show the long term drought condition by calculating yearly drought indices, and compared in three ways: First, compare drought characteristics of future time periods with base period; second, show the uncertainties of three greenhouse gas emission scenarios; third, present the uncertainties of six General Circulation Models (GCMs). Close

• 31. [Article] Long-Term Exposure to Fluoxetine Reduces Growth and Reproductive Potential in the Dominant Rocky Intertidal Mussel, Mytilus californianus

  Environmental stressors shape community composition and ecosystem functioning. Contaminants such as pharmaceuticals are of increasing concern as an environmental stressor due to their persistence in surface ...

  Citation × Citation Citation Abstract Copy Title: Long-Term Exposure to Fluoxetine Reduces Growth and Reproductive Potential in the Dominant Rocky Intertidal Mussel, Mytilus californianus Author: Peters, Joseph R., Granek, Elise F. Year: 2016 Environmental stressors shape community composition and ecosystem functioning. Contaminants such as pharmaceuticals are of increasing concern as an environmental stressor due to their persistence in surface waters worldwide. Limited attention has been paid to the effects of pharmaceuticals on marine life, despite widespread detection of these contaminants in the marine environment. Of the existing studies, the majority assess the negative effects of pharmaceuticals over an exposure period of 30 days or less and focus on cellular and subcellular biomarkers. Longer studies are required to determine if chronic contaminant exposure poses risks to marine life at environmentally relevant concentrations; and examination of whole organism effects are necessary to identify potential community-level consequences in estuarine and marine ecosystems. We conducted a long-term exposure study (107 days) with the anti-depressant pharmaceutical, fluoxetine (the active constituent in Prozac®) to determine whether minimal concentrations affected whole organism metrics in the California mussel, Mytilus californianus. We measured algal clearance rates, mussel growth, and the gonadosomatic index, a measure of reproductive health. We found that fluoxetine negatively affects all measured characteristics, however many effects were mediated by length of exposure. Our results fill an important data gap, highlighting organism-level effects of chronic exposure periods; such data more explicitly identify the overall impacts of pharmaceuticals and other contaminants on marine communities and ecosystems. Title: Long-Term Exposure to Fluoxetine Reduces Growth and Reproductive Potential in the Dominant Rocky Intertidal Mussel, Mytilus californianus Author: Peters, Joseph R., Granek, Elise F. Year: 2016 Environmental stressors shape community composition and ecosystem functioning. Contaminants such as pharmaceuticals are of increasing concern as an environmental stressor due to their persistence in surface waters worldwide. Limited attention has been paid to the effects of pharmaceuticals on marine life, despite widespread detection of these contaminants in the marine environment. Of the existing studies, the majority assess the negative effects of pharmaceuticals over an exposure period of 30 days or less and focus on cellular and subcellular biomarkers. Longer studies are required to determine if chronic contaminant exposure poses risks to marine life at environmentally relevant concentrations; and examination of whole organism effects are necessary to identify potential community-level consequences in estuarine and marine ecosystems. We conducted a long-term exposure study (107 days) with the anti-depressant pharmaceutical, fluoxetine (the active constituent in Prozac®) to determine whether minimal concentrations affected whole organism metrics in the California mussel, Mytilus californianus. We measured algal clearance rates, mussel growth, and the gonadosomatic index, a measure of reproductive health. We found that fluoxetine negatively affects all measured characteristics, however many effects were mediated by length of exposure. Our results fill an important data gap, highlighting organism-level effects of chronic exposure periods; such data more explicitly identify the overall impacts of pharmaceuticals and other contaminants on marine communities and ecosystems. Close

• 32. [Article] Wet Meadow Plant Associations, Malheur National Wildlife Refuge, Harney County, Oregon

  In July 2012, we sampled 131 plots in wet meadow habitat at the southern end of the Malheur National Wildlife Refuge. Analysis of the data identified eleven different plant associations: Alopecurus pratensis, ...

  Citation × Citation Citation Abstract Copy Title: Wet Meadow Plant Associations, Malheur National Wildlife Refuge, Harney County, Oregon Author: Christy, John A. Year: 2013 In July 2012, we sampled 131 plots in wet meadow habitat at the southern end of the Malheur National Wildlife Refuge. Analysis of the data identified eleven different plant associations: Alopecurus pratensis, Carex aquatilis var. aquatilis, Carex nebrascensis, Carex pellita, Carex praegracilis, Carex sheldonii, Distichlis spicata, Juncus balticus, Leymus triticoides, Phalaris arundinacea, and Sparganium eurycarpum. Plant associations spanned a wetland gradient from seasonally moist to seasonally or perennially flooded, but surface water had left most stands at time of sampling. Mean Wetland Indicator Status scores help to place the plant associations within gradients in soil moisture and alkalinity. The Alopecurus pratensis and Phalaris arundinacea associations are dominated by exotic, invasive species and appear to be outcompeting native plant associations. Phases of the Carex praegracilis association appear to be replaced by the Alopecurus pratensis association, while the Carex pellita, Juncus balticus, and Leymus triticoides associations may be replaced by the Phalaris arundinacea association. The Carex aquatilis and Sparganium eurycarpum associations were undersampled and provide only an estimate of composition. Most associations are consistent with what has been included in the National Vegetation Classification. Title: Wet Meadow Plant Associations, Malheur National Wildlife Refuge, Harney County, Oregon Author: Christy, John A. Year: 2013 In July 2012, we sampled 131 plots in wet meadow habitat at the southern end of the Malheur National Wildlife Refuge. Analysis of the data identified eleven different plant associations: Alopecurus pratensis, Carex aquatilis var. aquatilis, Carex nebrascensis, Carex pellita, Carex praegracilis, Carex sheldonii, Distichlis spicata, Juncus balticus, Leymus triticoides, Phalaris arundinacea, and Sparganium eurycarpum. Plant associations spanned a wetland gradient from seasonally moist to seasonally or perennially flooded, but surface water had left most stands at time of sampling. Mean Wetland Indicator Status scores help to place the plant associations within gradients in soil moisture and alkalinity. The Alopecurus pratensis and Phalaris arundinacea associations are dominated by exotic, invasive species and appear to be outcompeting native plant associations. Phases of the Carex praegracilis association appear to be replaced by the Alopecurus pratensis association, while the Carex pellita, Juncus balticus, and Leymus triticoides associations may be replaced by the Phalaris arundinacea association. The Carex aquatilis and Sparganium eurycarpum associations were undersampled and provide only an estimate of composition. Most associations are consistent with what has been included in the National Vegetation Classification. Close

• 33. [Article] Wet Meadow Plant Associations, Double O Unit, Malheur National Wildlife Refuge, Harney County, Oregon

  This report summarizes vegetation data collected in July 2015 in wet meadow and marshy habitats on the Double O Unit of Malheur National Wildlife Refuge (MNWR). Because vegetation sampled at the Double ...

  Citation × Citation Citation Abstract Copy Title: Wet Meadow Plant Associations, Double O Unit, Malheur National Wildlife Refuge, Harney County, Oregon Author: Christy, John A. Year: 2016 This report summarizes vegetation data collected in July 2015 in wet meadow and marshy habitats on the Double O Unit of Malheur National Wildlife Refuge (MNWR). Because vegetation sampled at the Double O was wetter and more alkaline than wet meadows sampled at the south end of the refuge in 2012 and 2013 (Christy 2014), data from the Double O Unit were analyzed and summarized separately. A total of 83 plots were sampled in 2015, and analysis of the data identified 14 plant associations: Alopecurus aequalis - Juncus balticus, Alopecurus pratensis - Potentilla anserina, Carex praegracilis - Juncus balticus, Cicuta douglasii - Carex nebrascensis, Distichlis spicata - Amphiscirpus nevadensis, Distichlis spicata - Nitrophila occidentalis, Eleocharis palustris - Juncus balticus, Eleocharis rostellata, Juncus balticus - Glaux maritima, Hippuris vulgaris - Triglochin maritima, Leymus triticoides - Juncus balticus, Schoenoplectus americanus, Spartina gracilis, and Triglochin maritima. Plant associations spanned a wetland gradient from seasonally moist to seasonally or perennially flooded, but surface water had left most stands at time of sampling. Mean Wetland Indicator Status scores and species composition help to place the plant associations within gradients in soil moisture and alkalinity. Seven of the 14 plant associations are listed in the International Vegetation Classification, and the remaining types are provisional Title: Wet Meadow Plant Associations, Double O Unit, Malheur National Wildlife Refuge, Harney County, Oregon Author: Christy, John A. Year: 2016 This report summarizes vegetation data collected in July 2015 in wet meadow and marshy habitats on the Double O Unit of Malheur National Wildlife Refuge (MNWR). Because vegetation sampled at the Double O was wetter and more alkaline than wet meadows sampled at the south end of the refuge in 2012 and 2013 (Christy 2014), data from the Double O Unit were analyzed and summarized separately. A total of 83 plots were sampled in 2015, and analysis of the data identified 14 plant associations: Alopecurus aequalis - Juncus balticus, Alopecurus pratensis - Potentilla anserina, Carex praegracilis - Juncus balticus, Cicuta douglasii - Carex nebrascensis, Distichlis spicata - Amphiscirpus nevadensis, Distichlis spicata - Nitrophila occidentalis, Eleocharis palustris - Juncus balticus, Eleocharis rostellata, Juncus balticus - Glaux maritima, Hippuris vulgaris - Triglochin maritima, Leymus triticoides - Juncus balticus, Schoenoplectus americanus, Spartina gracilis, and Triglochin maritima. Plant associations spanned a wetland gradient from seasonally moist to seasonally or perennially flooded, but surface water had left most stands at time of sampling. Mean Wetland Indicator Status scores and species composition help to place the plant associations within gradients in soil moisture and alkalinity. Seven of the 14 plant associations are listed in the International Vegetation Classification, and the remaining types are provisional Close

• 34. [Article] Mapping the Nonstationary Internal Tide with Satellite Altimetry

  t Temporal variability of the internal tide has been inferred from the 23 year long combined records of the TOPEX/Poseidon, Jason-1, and Jason-2 satellite altimeters by combining harmonic analysis with ...

  Citation × Citation Citation Abstract Copy Title: Mapping the Nonstationary Internal Tide with Satellite Altimetry Author: Zaron, Edward Year: 2017 t Temporal variability of the internal tide has been inferred from the 23 year long combined records of the TOPEX/Poseidon, Jason-1, and Jason-2 satellite altimeters by combining harmonic analysis with an analysis of along-track wavenumber spectra of sea-surface height (SSH). Conventional harmonic analysis is first applied to estimate and remove the stationary components of the tide at each point along the reference ground tracks. The wavenumber spectrum of the residual SSH is then computed, and the variance in a neighborhood around the wavenumber of the mode-1 baroclinic M2 tide is interpreted as the sum of noise, broadband nontidal processes, and the nonstationary tide. At many sites a bump in the spectrum associated with the internal tide is noted, and an empirical model for the noise and nontidal processes is used to estimate the nonstationary semidiurnal tidal variance. The results indicate a spatially inhomogeneous pattern of tidal variability. Nonstationary tides are larger than stationary tides throughout much of the equatorial Pacific and Indian Oceans Title: Mapping the Nonstationary Internal Tide with Satellite Altimetry Author: Zaron, Edward Year: 2017 t Temporal variability of the internal tide has been inferred from the 23 year long combined records of the TOPEX/Poseidon, Jason-1, and Jason-2 satellite altimeters by combining harmonic analysis with an analysis of along-track wavenumber spectra of sea-surface height (SSH). Conventional harmonic analysis is first applied to estimate and remove the stationary components of the tide at each point along the reference ground tracks. The wavenumber spectrum of the residual SSH is then computed, and the variance in a neighborhood around the wavenumber of the mode-1 baroclinic M2 tide is interpreted as the sum of noise, broadband nontidal processes, and the nonstationary tide. At many sites a bump in the spectrum associated with the internal tide is noted, and an empirical model for the noise and nontidal processes is used to estimate the nonstationary semidiurnal tidal variance. The results indicate a spatially inhomogeneous pattern of tidal variability. Nonstationary tides are larger than stationary tides throughout much of the equatorial Pacific and Indian Oceans Close

• 35. [Article] Non-Stationary Internal Tides Observed with Satellite Altimetry

  Temporal variability of the internal tide is inferred from a 17-year combined record of Topex/Poseidon and Jason satellite altimeters. A global sampling of along-track sea-surface height wavenumber spectra ...

  Citation × Citation Citation Abstract Copy Title: Non-Stationary Internal Tides Observed with Satellite Altimetry Author: Ray, R. D., Zaron, Edward D. Year: 2011 Temporal variability of the internal tide is inferred from a 17-year combined record of Topex/Poseidon and Jason satellite altimeters. A global sampling of along-track sea-surface height wavenumber spectra finds that non-stationary variance is generally 25% or less of the average variance at wavenumbers characteristic of mode-1 tidal internal waves. With some exceptions the non-stationary variance does not exceed 0.25 cm2. The mode-2 signal, where detectable, contains a larger fraction of non-stationary variance, typically 50% or more. Temporal subsetting of the data reveals interannual variability barely significant compared with tidal estimation error from 3-year records. Comparison of summer vs. winter conditions shows only one region of noteworthy seasonal changes, the northern South China Sea. Implications for the anticipated SWOT altimeter mission are briefly discussed. Title: Non-Stationary Internal Tides Observed with Satellite Altimetry Author: Ray, R. D., Zaron, Edward D. Year: 2011 Temporal variability of the internal tide is inferred from a 17-year combined record of Topex/Poseidon and Jason satellite altimeters. A global sampling of along-track sea-surface height wavenumber spectra finds that non-stationary variance is generally 25% or less of the average variance at wavenumbers characteristic of mode-1 tidal internal waves. With some exceptions the non-stationary variance does not exceed 0.25 cm2. The mode-2 signal, where detectable, contains a larger fraction of non-stationary variance, typically 50% or more. Temporal subsetting of the data reveals interannual variability barely significant compared with tidal estimation error from 3-year records. Comparison of summer vs. winter conditions shows only one region of noteworthy seasonal changes, the northern South China Sea. Implications for the anticipated SWOT altimeter mission are briefly discussed. Close

• 36. [Article] Regional Models of Internal Tides

  Internal tides are ubiquitous in the ocean, and they play an important role in a range of ocean processes, for example, particle dispersal, acoustics, and vertical buoyancy flux. The wavelength of internal ...

  Citation × Citation Citation Abstract Copy Title: Regional Models of Internal Tides Author: Carter, Glenn S., Fringer, Oliver B., Zaron, Edward D. Year: 2012 Internal tides are ubiquitous in the ocean, and they play an important role in a range of ocean processes, for example, particle dispersal, acoustics, and vertical buoyancy flux. The wavelength of internal tides can be as much as 250 km in the open ocean, but as the generation of these tides depends on the angle between the depth-averaged current and the topography, there can be considerable local spatial variability. This range of scales makes it difficult to develop a comprehensive understanding of the processes involved from observations alone. Regional numerical modeling provides a way to study the generation and early propagation of internal tides at high resolution. Here, we review the role that regional internal tide models, primarily hydrostatic models, can play in increasing our understanding. Title: Regional Models of Internal Tides Author: Carter, Glenn S., Fringer, Oliver B., Zaron, Edward D. Year: 2012 Internal tides are ubiquitous in the ocean, and they play an important role in a range of ocean processes, for example, particle dispersal, acoustics, and vertical buoyancy flux. The wavelength of internal tides can be as much as 250 km in the open ocean, but as the generation of these tides depends on the angle between the depth-averaged current and the topography, there can be considerable local spatial variability. This range of scales makes it difficult to develop a comprehensive understanding of the processes involved from observations alone. Regional numerical modeling provides a way to study the generation and early propagation of internal tides at high resolution. Here, we review the role that regional internal tide models, primarily hydrostatic models, can play in increasing our understanding. Close

• 37. [Article] Infrared-Based Measurements of Velocity, Turbulent Kinetic Energy, and Dissipation at the Water Surface in a Tidal River

  Thermal infrared (IR) based particle image velocimetry (PIV) is used to measure the evolution of velocity, turbulent kinetic energy (TKE), and the TKE dissipation rate at the water surface in the tidally ...

  Citation × Citation Citation Abstract Copy Title: Infrared-Based Measurements of Velocity, Turbulent Kinetic Energy, and Dissipation at the Water Surface in a Tidal River Author: Chickadel, C. Chris, Talke, Stefan A., Horner-Devine, Alexander R., Jessup, Andrew T. Year: 2011 Thermal infrared (IR) based particle image velocimetry (PIV) is used to measure the evolution of velocity, turbulent kinetic energy (TKE), and the TKE dissipation rate at the water surface in the tidally influenced Snohomish River. Patterns of temperature variability in the IR imagery arise from disruption of the cool skin layer and are used to estimate the 2D velocity field. Comparisons of IR based PIV mean velocity made against a collocated acoustic velocimeter demonstrate high correlation (r2 > 0.9). Over a tidal period, surface TKE computed from the IR velocity varies from 10-4 J·kg-1 to 3x10-3 J·kg-1, with an average difference from the in situ measurements of 8%. IR-derived TKE dissipation rates vary from approximately 3x10-6 W·kg-1 to 2x10-4 W·kg-1 at peak ebb, agreeing on average to within 7% of the in situ velocimeter results. Infrared-based PIV provides detailed measurements of previously inaccessible surface flow and turbulence statistics. Title: Infrared-Based Measurements of Velocity, Turbulent Kinetic Energy, and Dissipation at the Water Surface in a Tidal River Author: Chickadel, C. Chris, Talke, Stefan A., Horner-Devine, Alexander R., Jessup, Andrew T. Year: 2011 Thermal infrared (IR) based particle image velocimetry (PIV) is used to measure the evolution of velocity, turbulent kinetic energy (TKE), and the TKE dissipation rate at the water surface in the tidally influenced Snohomish River. Patterns of temperature variability in the IR imagery arise from disruption of the cool skin layer and are used to estimate the 2D velocity field. Comparisons of IR based PIV mean velocity made against a collocated acoustic velocimeter demonstrate high correlation (r2 > 0.9). Over a tidal period, surface TKE computed from the IR velocity varies from 10-4 J·kg-1 to 3x10-3 J·kg-1, with an average difference from the in situ measurements of 8%. IR-derived TKE dissipation rates vary from approximately 3x10-6 W·kg-1 to 2x10-4 W·kg-1 at peak ebb, agreeing on average to within 7% of the in situ velocimeter results. Infrared-based PIV provides detailed measurements of previously inaccessible surface flow and turbulence statistics. Close

• 38. [Article] Using Maps to Accelerate Social Movements and Reclaim Place

  Jennifer Veilleux is a geographer focused on the water security of international rivers. Jennifer earned her Ph.D. in Geography from Oregon State University. She has a background in surface and subsurface ...

  Citation × Citation Citation Abstract Copy Title: Using Maps to Accelerate Social Movements and Reclaim Place Author: Veilleux, Jennifer Year: 2017 Jennifer Veilleux is a geographer focused on the water security of international rivers. Jennifer earned her Ph.D. in Geography from Oregon State University. She has a background in surface and subsurface water science and has researched, published, and lectured on threats to humans and the environment from water development in the Nile, Mekong, Missouri, among other basins throughout the world. In addition to scholarship, Veilleux uses maps, infographics, and satellite imagery through social media to highlight spatial relationships of environmental justice and human rights issues as relates to water. As a Postdoctoral Associate with the Steven J. Green School of International and Public Affairs at Florida International University, Jennifer does research and analysis of the hydropolitics of some of the world’s major rivers. Title: Using Maps to Accelerate Social Movements and Reclaim Place Author: Veilleux, Jennifer Year: 2017 Jennifer Veilleux is a geographer focused on the water security of international rivers. Jennifer earned her Ph.D. in Geography from Oregon State University. She has a background in surface and subsurface water science and has researched, published, and lectured on threats to humans and the environment from water development in the Nile, Mekong, Missouri, among other basins throughout the world. In addition to scholarship, Veilleux uses maps, infographics, and satellite imagery through social media to highlight spatial relationships of environmental justice and human rights issues as relates to water. As a Postdoctoral Associate with the Steven J. Green School of International and Public Affairs at Florida International University, Jennifer does research and analysis of the hydropolitics of some of the world’s major rivers. Close

• 39. [Article] Potential Impacts of Climate Change on Flood-Induced Travel Disruptions: A Case Study of Portland, Oregon, USA

  This study investigated potential impacts of climate change on travel disruption resulting from road closures in two urban watersheds in the Portland, Oregon, metropolitan area. We used ensemble climate ...

  Citation × Citation Citation Abstract Copy Title: Potential Impacts of Climate Change on Flood-Induced Travel Disruptions: A Case Study of Portland, Oregon, USA Author: Chang, Heejun, Lafrenz, Martin, Jung, Il-won, Figliozzi, Miguel, Platman, Deena, Pederson, Cindy Year: 2010 This study investigated potential impacts of climate change on travel disruption resulting from road closures in two urban watersheds in the Portland, Oregon, metropolitan area. We used ensemble climate change scenarios, a hydrologic model, a stream channel survey, a hydraulic model, and a travel forecast model to develop an integrated impact assessment method. High-resolution climate change scenarios are based on the combinations of two emission scenarios and eight general circulation models. The Precipitation-Runoff Modeling System was calibrated and validated for the historical period of 1988 and 2006 and simulated for determining the probability of floods for 2020 through 2049. We surveyed stream cross-sections at five road crossings for stream channel geometry and determined flood water surface elevations using the Hydrologic Engineering Centers River Analysis System (HEC-RAS) model. Four of the surveyed bridges and roadways were lower in elevation than the current 100-year flood water surface elevation, leading to relatively frequent nuisance flooding. These roadway flooding events will become more frequent under some climate change scenarios in the future, but climate change impacts will depend on local geomorphic conditions. Whereas vehicle miles traveled was not significantly affected by road closure, vehicle hours delay demonstrated a greater impact from road closures, increasing by 10 percent in the Fanno Creek area. Our research demonstrated the usefulness of the integration of top-down and bottom-up approaches in climate change impact assessment and the need for spatially explicit modeling and participatory planning in flood management and transportation planning under increasing climate uncertainty. Title: Potential Impacts of Climate Change on Flood-Induced Travel Disruptions: A Case Study of Portland, Oregon, USA Author: Chang, Heejun, Lafrenz, Martin, Jung, Il-won, Figliozzi, Miguel, Platman, Deena, Pederson, Cindy Year: 2010 This study investigated potential impacts of climate change on travel disruption resulting from road closures in two urban watersheds in the Portland, Oregon, metropolitan area. We used ensemble climate change scenarios, a hydrologic model, a stream channel survey, a hydraulic model, and a travel forecast model to develop an integrated impact assessment method. High-resolution climate change scenarios are based on the combinations of two emission scenarios and eight general circulation models. The Precipitation-Runoff Modeling System was calibrated and validated for the historical period of 1988 and 2006 and simulated for determining the probability of floods for 2020 through 2049. We surveyed stream cross-sections at five road crossings for stream channel geometry and determined flood water surface elevations using the Hydrologic Engineering Centers River Analysis System (HEC-RAS) model. Four of the surveyed bridges and roadways were lower in elevation than the current 100-year flood water surface elevation, leading to relatively frequent nuisance flooding. These roadway flooding events will become more frequent under some climate change scenarios in the future, but climate change impacts will depend on local geomorphic conditions. Whereas vehicle miles traveled was not significantly affected by road closure, vehicle hours delay demonstrated a greater impact from road closures, increasing by 10 percent in the Fanno Creek area. Our research demonstrated the usefulness of the integration of top-down and bottom-up approaches in climate change impact assessment and the need for spatially explicit modeling and participatory planning in flood management and transportation planning under increasing climate uncertainty. Close

• 40. [Article] Assessing a Fluorescence Spectroscopy Method for In-Situ Microbial Drinking Water Quality

  Waterborne disease is a significant contributor to the global burden of disease, in particular among high-risk populations in developing nations. State-of-the-art methods for the enumeration of microbial ...

  Citation × Citation Citation Abstract Copy Title: Assessing a Fluorescence Spectroscopy Method for In-Situ Microbial Drinking Water Quality Author: Sharpe, Taylor Jeffery Year: 2017 Waterborne disease is a significant contributor to the global burden of disease, in particular among high-risk populations in developing nations. State-of-the-art methods for the enumeration of microbial pathogens in drinking water sources have important limitations, including high initial cost, 24-48 hour delays in results, high staffing and facility requirements, and training requirements which all become especially problematic in the developing nation context. A number of alternative approaches to microbial water quality testing have been proposed, with the goal of decreasing the required testing time, decreasing overall costs, leveraging appropriate technology approaches, or improving sensitivity or specificity of the water quality testing method. One approach that may offer solutions to some of these limitations involves the deployment of sensor networks using fluorescent spectroscopy to detect intrinsic protein fluorescence in water samples as a proxy for microbial activity. In recent years, a number of researchers have found significant and meaningful correlations between indicator bacteria species and the protein fluorescence of drinking water samples. Additionally, advances in the semiconductor industry could be used to drive down the cost of such sensors. This technology may also be extensible to other water quality parameters, including dissolved organic matter or the presence of fluorescent pollutants. In this thesis, a literature review describes the fundamentals of fluorescence spectroscopy, historical and recent work regarding the fluorescence of the amino acid tryptophan and associated bacterial fluorescence, possible mechanisms for this association, and potential applications of this technology for drinking water quality monitoring and waste water process control. Extensibility of the technology is also discussed. Next, experimental methodology in reproduction of similar results is described. Samples were taken from seven (7) surface water sources and tested using membrane filtration and an off-the-shelf fluorescence spectrometer to help examine the association between the presence of indicator bacteria and the tryptophan fluorescence of the water sample. The results, showing an association of R2 = 0.560, are compared to the results of recent similar experiments. Finally, two prototypes are described, including their design requirements and data from prototype testing. The results of the testing are briefly discussed, and next steps are outlined with the goal of developing a low-cost, in-situ microbial water quality sensor using fluorescence spectroscopy principles. Title: Assessing a Fluorescence Spectroscopy Method for In-Situ Microbial Drinking Water Quality Author: Sharpe, Taylor Jeffery Year: 2017 Waterborne disease is a significant contributor to the global burden of disease, in particular among high-risk populations in developing nations. State-of-the-art methods for the enumeration of microbial pathogens in drinking water sources have important limitations, including high initial cost, 24-48 hour delays in results, high staffing and facility requirements, and training requirements which all become especially problematic in the developing nation context. A number of alternative approaches to microbial water quality testing have been proposed, with the goal of decreasing the required testing time, decreasing overall costs, leveraging appropriate technology approaches, or improving sensitivity or specificity of the water quality testing method. One approach that may offer solutions to some of these limitations involves the deployment of sensor networks using fluorescent spectroscopy to detect intrinsic protein fluorescence in water samples as a proxy for microbial activity. In recent years, a number of researchers have found significant and meaningful correlations between indicator bacteria species and the protein fluorescence of drinking water samples. Additionally, advances in the semiconductor industry could be used to drive down the cost of such sensors. This technology may also be extensible to other water quality parameters, including dissolved organic matter or the presence of fluorescent pollutants. In this thesis, a literature review describes the fundamentals of fluorescence spectroscopy, historical and recent work regarding the fluorescence of the amino acid tryptophan and associated bacterial fluorescence, possible mechanisms for this association, and potential applications of this technology for drinking water quality monitoring and waste water process control. Extensibility of the technology is also discussed. Next, experimental methodology in reproduction of similar results is described. Samples were taken from seven (7) surface water sources and tested using membrane filtration and an off-the-shelf fluorescence spectrometer to help examine the association between the presence of indicator bacteria and the tryptophan fluorescence of the water sample. The results, showing an association of R2 = 0.560, are compared to the results of recent similar experiments. Finally, two prototypes are described, including their design requirements and data from prototype testing. The results of the testing are briefly discussed, and next steps are outlined with the goal of developing a low-cost, in-situ microbial water quality sensor using fluorescence spectroscopy principles. Close

• 41. [Article] Pharmaceutical Contaminants as Stressors on Rocky Intertidal and Estuarine Organisms: a Case Study of Fluoxetine

  Contaminants such as pharmaceuticals are of increasing concern due to their ubiquitous use and persistence in surface waters worldwide. Limited attention has been paid to the effects of pharmaceuticals ...

  Citation × Citation Citation Abstract Copy Title: Pharmaceutical Contaminants as Stressors on Rocky Intertidal and Estuarine Organisms: a Case Study of Fluoxetine Author: Peters, Joseph Richard Year: 2016 Contaminants such as pharmaceuticals are of increasing concern due to their ubiquitous use and persistence in surface waters worldwide. Limited attention has been paid to the effects of pharmaceuticals on marine life, despite widespread detection of these contaminants in the marine environment. Of the existing studies, the majority assess the negative effects of pharmaceuticals over an exposure period of 30 days or less and focus on cellular and subcellular biomarkers. Longer studies are required to determine if chronic contaminant exposure poses risks to marine life at environmentally relevant concentrations. Also scarce in the literature is examination of whole organism effects to identify potential community-level consequences. Two long-term studies with the antidepressant pharmaceutical, fluoxetine (the active constituent in Prozac®) were conducted to determine whether nominal concentrations detected in estuarine and coastal environments affect organism health and interactions. First, we measured whole organism metrics in the California mussel, Mytilus californianus over a period of 107 days. Specifically, we measured algal clearance rates, growth, and condition indices for both reproductive and overall health. We found that fluoxetine negatively affects all measured characteristics, however many effects are mediated by length of exposure. Perhaps the most notable result was that mussels spiked with fluoxetine cleared less algae after 30 days of exposure. Reduced growth and condition indices likely are a consequence of improper nutrition among fluoxetine-treated mussels. Any level of fluoxetine significantly affected the gonadosomatic index after 47 days. The results from this study on mussels fill an important data gap, highlighting organism-level effects of chronic exposure periods; such data more explicitly identify the impacts of pharmaceuticals and other contaminants on marine communities and ecosystems. Fluoxetine has also been documented to affect the behavior of fish and invertebrates, including freshwater and marine bivalves, crustaceans, and fish. Given that other crustaceans exhibited increased activity levels under fluoxetine exposure, we hypothesized that this would subject them to greater predation risk. In our second exposure study, we assessed whether a similar range of fluoxetine concentrations used in the mussel study altered the risk behavior of the Oregon mud crab, Hemigrapsus oregonensis, in response to a common predator, the red rock crab, Cancer productus. We conducted this study for 60 days, conducting day and night behavioral trials (with and without predators) four times a week. We found that crabs exposed to any amount of fluoxetine (3 or 30 ng/L) had increased activity levels relative to controls; however behaviors of 3 ng/L-spiked crabs were not always significantly different from controls. Among control crabs, day and night trials yielded similar results, where a clear response to the addition of the predator was observed. Crabs dosed with fluoxetine exhibited more foraging and active behaviors in the presence of the predator. Additionally, crabs spiked with fluoxetine at 30 ng/L had the greatest risk of mortality either by predation by red rock crabs or due to more aggressive behaviors among conspecifics. The results of this study shed light on a particularly unexplored area of contaminants research: how do psychoactive pharmaceuticals affect animal behavior when exposed to the low concentrations persisting in the aquatic environment for a prolonged period of time? Title: Pharmaceutical Contaminants as Stressors on Rocky Intertidal and Estuarine Organisms: a Case Study of Fluoxetine Author: Peters, Joseph Richard Year: 2016 Contaminants such as pharmaceuticals are of increasing concern due to their ubiquitous use and persistence in surface waters worldwide. Limited attention has been paid to the effects of pharmaceuticals on marine life, despite widespread detection of these contaminants in the marine environment. Of the existing studies, the majority assess the negative effects of pharmaceuticals over an exposure period of 30 days or less and focus on cellular and subcellular biomarkers. Longer studies are required to determine if chronic contaminant exposure poses risks to marine life at environmentally relevant concentrations. Also scarce in the literature is examination of whole organism effects to identify potential community-level consequences. Two long-term studies with the antidepressant pharmaceutical, fluoxetine (the active constituent in Prozac®) were conducted to determine whether nominal concentrations detected in estuarine and coastal environments affect organism health and interactions. First, we measured whole organism metrics in the California mussel, Mytilus californianus over a period of 107 days. Specifically, we measured algal clearance rates, growth, and condition indices for both reproductive and overall health. We found that fluoxetine negatively affects all measured characteristics, however many effects are mediated by length of exposure. Perhaps the most notable result was that mussels spiked with fluoxetine cleared less algae after 30 days of exposure. Reduced growth and condition indices likely are a consequence of improper nutrition among fluoxetine-treated mussels. Any level of fluoxetine significantly affected the gonadosomatic index after 47 days. The results from this study on mussels fill an important data gap, highlighting organism-level effects of chronic exposure periods; such data more explicitly identify the impacts of pharmaceuticals and other contaminants on marine communities and ecosystems. Fluoxetine has also been documented to affect the behavior of fish and invertebrates, including freshwater and marine bivalves, crustaceans, and fish. Given that other crustaceans exhibited increased activity levels under fluoxetine exposure, we hypothesized that this would subject them to greater predation risk. In our second exposure study, we assessed whether a similar range of fluoxetine concentrations used in the mussel study altered the risk behavior of the Oregon mud crab, Hemigrapsus oregonensis, in response to a common predator, the red rock crab, Cancer productus. We conducted this study for 60 days, conducting day and night behavioral trials (with and without predators) four times a week. We found that crabs exposed to any amount of fluoxetine (3 or 30 ng/L) had increased activity levels relative to controls; however behaviors of 3 ng/L-spiked crabs were not always significantly different from controls. Among control crabs, day and night trials yielded similar results, where a clear response to the addition of the predator was observed. Crabs dosed with fluoxetine exhibited more foraging and active behaviors in the presence of the predator. Additionally, crabs spiked with fluoxetine at 30 ng/L had the greatest risk of mortality either by predation by red rock crabs or due to more aggressive behaviors among conspecifics. The results of this study shed light on a particularly unexplored area of contaminants research: how do psychoactive pharmaceuticals affect animal behavior when exposed to the low concentrations persisting in the aquatic environment for a prolonged period of time? Close

• 42. [Article] Hydrogeology of the McKinney Butte Area: Sisters, Oregon

  McKinney Butte, a late Tertiary andesite vent and flow complex, is located near the town of Sisters, Oregon, in the upper Deschutes Basin, and is situated along the structural trend that forms the eastern ...

  Citation × Citation Citation Abstract Copy Title: Hydrogeology of the McKinney Butte Area: Sisters, Oregon Author: Hackett, Joshua Andrew Year: 2011 McKinney Butte, a late Tertiary andesite vent and flow complex, is located near the town of Sisters, Oregon, in the upper Deschutes Basin, and is situated along the structural trend that forms the eastern margin of the High Cascades graben (Sisters fault zone and Green Ridge). Rapid development and over appropriated surface water resources in this area have led to an increased dependence upon groundwater resources. A primary concern of resource managers is the potential impact of expanding groundwater use on stream flows and spring discharge. Two sets of springs (McKinney Butte Springs and Camp Polk Springs) discharge to Whychus Creek along the east flank of McKinney Butte, and during low-flow conditions supply a substantial component of the total flow in the creek. Despite their contribution to Whychus Creek, the springs along McKinney Butte are small-scale features and have received less attention than larger volume (> 2 m³/s) springs that occur in the basin (i.e., Metolius Spring and Lower Opal Springs). This study used discharge measurements in Whychus Creek upstream and downstream of the springs, and mixing models using measurements of electrical conductivity and temperature in the springs and Whychus Creek to determine the contribution of the springs to the creek. Isotopic, thermal, and geochemical signatures for the McKinney Butte and Camp Polk Springs, and local streams (Whychus Creek and Indian Ford Creek) and springs (Metolius Spring, Paulina Spring, Alder Springs, and Lower Opal Spring) were assessed to determine the source(s) of the McKinney Butte and Camp Polk Springs. The discharge and hydrochemical data along with hydraulic head data from local wells were used in the development of a conceptual model of groundwater flow for the McKinney Butte area. Discharge from the McKinney Butte Springs supplies the majority of water to Whychus Creek on the east flank of McKinney Butte (~0.20 m³/s), provides up to 46% of the flow in the creek, and is relatively stable throughout the year. Discharge from the Camp Polk Springs is less than 0.05 m³/s. Isotopic, thermal, and geochemical signatures indicate distinct sources for the McKinney Butte and Camp Polk Springs. Groundwater discharged at the McKinney Butte Springs is depleted in heavy stable isotopes (δD and δ¹⁸O) relative to the Camp Polk Springs. Recharge elevations inferred from stable isotope concentrations are 1800-1900 m for the McKinney Butte Springs and 950-1300 m for the Camp Polk Springs. Elevated water temperature in the McKinney Butte Springs relative to the average air temperature at the inferred recharge elevation indicates the presence of geothermal heat and implies deep circulation in the flow system. The temperature in the Camp Polk Springs is not elevated. The Camp Polk Springs, though not the McKinney Butte Springs, contain elevated concentrations of ions Cl, SO₄, and NO₃ that are indicative of contamination. The study results indicate the source of the Camp Polk Springs is shallow groundwater whereas the McKinney Butte Springs discharge water that has circulated deep in the groundwater flow system. Additionally, the hydrochemical traits of the McKinney Butte Springs are similar to Metolius Spring, suggesting discharge from the McKinney Butte Springs is controlled by the structural trend that forms the eastern margin of the High Cascades graben. The significant difference in discharge between the McKinney Butte Springs and Metolius spring may be related to the size of faults that occur locally. Title: Hydrogeology of the McKinney Butte Area: Sisters, Oregon Author: Hackett, Joshua Andrew Year: 2011 McKinney Butte, a late Tertiary andesite vent and flow complex, is located near the town of Sisters, Oregon, in the upper Deschutes Basin, and is situated along the structural trend that forms the eastern margin of the High Cascades graben (Sisters fault zone and Green Ridge). Rapid development and over appropriated surface water resources in this area have led to an increased dependence upon groundwater resources. A primary concern of resource managers is the potential impact of expanding groundwater use on stream flows and spring discharge. Two sets of springs (McKinney Butte Springs and Camp Polk Springs) discharge to Whychus Creek along the east flank of McKinney Butte, and during low-flow conditions supply a substantial component of the total flow in the creek. Despite their contribution to Whychus Creek, the springs along McKinney Butte are small-scale features and have received less attention than larger volume (> 2 m³/s) springs that occur in the basin (i.e., Metolius Spring and Lower Opal Springs). This study used discharge measurements in Whychus Creek upstream and downstream of the springs, and mixing models using measurements of electrical conductivity and temperature in the springs and Whychus Creek to determine the contribution of the springs to the creek. Isotopic, thermal, and geochemical signatures for the McKinney Butte and Camp Polk Springs, and local streams (Whychus Creek and Indian Ford Creek) and springs (Metolius Spring, Paulina Spring, Alder Springs, and Lower Opal Spring) were assessed to determine the source(s) of the McKinney Butte and Camp Polk Springs. The discharge and hydrochemical data along with hydraulic head data from local wells were used in the development of a conceptual model of groundwater flow for the McKinney Butte area. Discharge from the McKinney Butte Springs supplies the majority of water to Whychus Creek on the east flank of McKinney Butte (~0.20 m³/s), provides up to 46% of the flow in the creek, and is relatively stable throughout the year. Discharge from the Camp Polk Springs is less than 0.05 m³/s. Isotopic, thermal, and geochemical signatures indicate distinct sources for the McKinney Butte and Camp Polk Springs. Groundwater discharged at the McKinney Butte Springs is depleted in heavy stable isotopes (δD and δ¹⁸O) relative to the Camp Polk Springs. Recharge elevations inferred from stable isotope concentrations are 1800-1900 m for the McKinney Butte Springs and 950-1300 m for the Camp Polk Springs. Elevated water temperature in the McKinney Butte Springs relative to the average air temperature at the inferred recharge elevation indicates the presence of geothermal heat and implies deep circulation in the flow system. The temperature in the Camp Polk Springs is not elevated. The Camp Polk Springs, though not the McKinney Butte Springs, contain elevated concentrations of ions Cl, SO₄, and NO₃ that are indicative of contamination. The study results indicate the source of the Camp Polk Springs is shallow groundwater whereas the McKinney Butte Springs discharge water that has circulated deep in the groundwater flow system. Additionally, the hydrochemical traits of the McKinney Butte Springs are similar to Metolius Spring, suggesting discharge from the McKinney Butte Springs is controlled by the structural trend that forms the eastern margin of the High Cascades graben. The significant difference in discharge between the McKinney Butte Springs and Metolius spring may be related to the size of faults that occur locally. Close

• 43. [Article] Invertebrate Community Composition Across Inundation Regimes and Its Potential to Reduce Plant Stress

  Appreciation of the ecological and economic values associated with healthy salt marshes has led to a recent rise in the number of marshes that are being targeted for restoration by dike removal. The success ...

  Citation × Citation Citation Abstract Copy Title: Invertebrate Community Composition Across Inundation Regimes and Its Potential to Reduce Plant Stress Author: Lawson, Inez Ilicia Year: 2017 Appreciation of the ecological and economic values associated with healthy salt marshes has led to a recent rise in the number of marshes that are being targeted for restoration by dike removal. The success of restoration is often measured by the return of marsh plants, though this overlooks a key component of salt marshes, that of the invertebrate community within marsh sediments. To evaluate the short-term recovery of these invertebrates, sediment cores were collected across an elevational gradient in a recent dike removal marsh, one and two years post removal, and a nearby reference marsh. Abundance, richness and diversity as well as morphospecies community composition were compared across treatment groups (Reference, Removal) and elevation zone (High Marsh, Low Marsh). Morphospecies richness, abundance and diversity were significantly higher in Low Marsh samples than in High Marsh samples, though no statistically significant differences were found across treatments of the same elevation (e.g., Reference Low Marsh versus Removal Low Marsh). Pair-wise ANOSIM results found significant differences between community compositions across treatments, specifically Reference Low Marsh and Removal Low Marsh. The marsh edge, the lowest point of vascular plant growth before transitioning to tide flats, is considered a high stress environment for emergent vegetation. Plant establishment and survival in this low elevation zone is limited by the tolerance to inundation duration and frequency and anoxic sediments. Bioturbation and burrowing by macroinvertebrates increases the surface area exposed to surface water for gas exchange, increasing the depth of the redox potential discontinuity layer. Crabs that make stable, maintained burrows have been shown to increase oxygen penetration into sediment, improving plant productivity. Such crabs are not found in salt marshes of the Pacific Northwest of North America. However, other burrowing invertebrates may have a positive impact on plant health in these areas by reducing abiotic stress due to anoxic sediments, thereby allowing plants to establish and survive lower in the intertidal zone. To assess this potential relationship, study plots of Distichlis spicata were selected at equivalent elevations at the lowest point of plant establishment at the marsh edge. Focal plant rhizomes were severed from upland ramets and assigned an invertebrate abundance treatment based on a visual burrow count surrounding each plant (9 cm diameter). Focal plants were visited monthly from July to September 2016, plant health variables of chlorophyll content and chlorophyll fluorescence (photosynthetic efficiency), and sediment ORP readings were collected. Plant survivorship was significantly higher in plots with invertebrates, 96% of plants in "With Invertebrate" plots and 50% of plants in "No Invertebrates" plots survived the duration of the study. Plant health (chlorophyll content and chlorophyll fluorescence) generally increased with increased invertebrate presence though, not statistically significant. There may be potential for improved plant productivity and resilience to plants at the marsh edge due to invertebrate burrowing activity. This benefit could help mitigate projected losses in plant productivity due to sea level rise, though more research is needed to investigate the mechanism by which these invertebrates confer a health benefit to plants at the marsh edge. Title: Invertebrate Community Composition Across Inundation Regimes and Its Potential to Reduce Plant Stress Author: Lawson, Inez Ilicia Year: 2017 Appreciation of the ecological and economic values associated with healthy salt marshes has led to a recent rise in the number of marshes that are being targeted for restoration by dike removal. The success of restoration is often measured by the return of marsh plants, though this overlooks a key component of salt marshes, that of the invertebrate community within marsh sediments. To evaluate the short-term recovery of these invertebrates, sediment cores were collected across an elevational gradient in a recent dike removal marsh, one and two years post removal, and a nearby reference marsh. Abundance, richness and diversity as well as morphospecies community composition were compared across treatment groups (Reference, Removal) and elevation zone (High Marsh, Low Marsh). Morphospecies richness, abundance and diversity were significantly higher in Low Marsh samples than in High Marsh samples, though no statistically significant differences were found across treatments of the same elevation (e.g., Reference Low Marsh versus Removal Low Marsh). Pair-wise ANOSIM results found significant differences between community compositions across treatments, specifically Reference Low Marsh and Removal Low Marsh. The marsh edge, the lowest point of vascular plant growth before transitioning to tide flats, is considered a high stress environment for emergent vegetation. Plant establishment and survival in this low elevation zone is limited by the tolerance to inundation duration and frequency and anoxic sediments. Bioturbation and burrowing by macroinvertebrates increases the surface area exposed to surface water for gas exchange, increasing the depth of the redox potential discontinuity layer. Crabs that make stable, maintained burrows have been shown to increase oxygen penetration into sediment, improving plant productivity. Such crabs are not found in salt marshes of the Pacific Northwest of North America. However, other burrowing invertebrates may have a positive impact on plant health in these areas by reducing abiotic stress due to anoxic sediments, thereby allowing plants to establish and survive lower in the intertidal zone. To assess this potential relationship, study plots of Distichlis spicata were selected at equivalent elevations at the lowest point of plant establishment at the marsh edge. Focal plant rhizomes were severed from upland ramets and assigned an invertebrate abundance treatment based on a visual burrow count surrounding each plant (9 cm diameter). Focal plants were visited monthly from July to September 2016, plant health variables of chlorophyll content and chlorophyll fluorescence (photosynthetic efficiency), and sediment ORP readings were collected. Plant survivorship was significantly higher in plots with invertebrates, 96% of plants in "With Invertebrate" plots and 50% of plants in "No Invertebrates" plots survived the duration of the study. Plant health (chlorophyll content and chlorophyll fluorescence) generally increased with increased invertebrate presence though, not statistically significant. There may be potential for improved plant productivity and resilience to plants at the marsh edge due to invertebrate burrowing activity. This benefit could help mitigate projected losses in plant productivity due to sea level rise, though more research is needed to investigate the mechanism by which these invertebrates confer a health benefit to plants at the marsh edge. Close

• 44. [Article] Evidence Supporting Treatment Practice Based Delineation of Stormwater Runoff Zones

  Particles mobilized by stormwater negatively affect receiving surface waters. Stormwater best management practices (BMPs) can reduce solids along with associated pollutants in runoff but engineers and ...

  Citation × Citation Citation Abstract Copy Title: Evidence Supporting Treatment Practice Based Delineation of Stormwater Runoff Zones Author: Gorski, Jacob J. Year: 2013 Particles mobilized by stormwater negatively affect receiving surface waters. Stormwater best management practices (BMPs) can reduce solids along with associated pollutants in runoff but engineers and environmental managers have been long vexed by the problem of choosing the optimal BMP for a given situation. A common BMP process for solids removal is sedimentation. This thesis addresses the question of whether the effectiveness (and thus choice) of a sedimentation device can be estimated (and thus optimized) from the particle size properties of runoff, which, in turn, could be associated with specific runoff zones or land uses. Presented here is a series of experiments to determine the solids-removal capabilities of a manufactured oil-water separator that also removes solids via sedimentation. A statistical model developed from the experimental data shows that, under normal operating conditions, influent particle size can be used to accurately estimate effluent total suspended solids (TSS) for BMPs of this type. Relationships between particle size and particle-bound metal concentrations for Cu, Zn and Pb were then obtained from the literature and incorporated into the model to allow estimates of metal removal efficiencies based on TSS and PSD. The model can be used with an arbitrary particle size distribution (PSD); this allows effluent quality predictions to be made considering that particle sizes entering stormwater BMPs could vary due to anthropogenic, hydraulic or hydrologic factors. To place these experimental and modeling results in the context of an urban environment, samples of deposited stormwater solids were collected from residential areas, commercial areas and an industrial zone in Portland, Oregon, and the PSD of each sample was determined using light obstruction particle sizing. PSDs ranging over sizes from 3μm to 200μm vary among these locations. Areas with high anthropogenic impact were found to have PSDs skewed toward the smallest particle sizes. The statistical model developed here was then used to show that the effluent quality of the BMP tested would differ depending on the locations where solids were collected. The evidence presented in this thesis thus indicates that device performance will correlate with geographic locations or land use zone and validates further investigation into delineating the City of Portland's characteristic runoff zones and using the runoff characteristics of each zone to map it to the most desirable treatment practices. Title: Evidence Supporting Treatment Practice Based Delineation of Stormwater Runoff Zones Author: Gorski, Jacob J. Year: 2013 Particles mobilized by stormwater negatively affect receiving surface waters. Stormwater best management practices (BMPs) can reduce solids along with associated pollutants in runoff but engineers and environmental managers have been long vexed by the problem of choosing the optimal BMP for a given situation. A common BMP process for solids removal is sedimentation. This thesis addresses the question of whether the effectiveness (and thus choice) of a sedimentation device can be estimated (and thus optimized) from the particle size properties of runoff, which, in turn, could be associated with specific runoff zones or land uses. Presented here is a series of experiments to determine the solids-removal capabilities of a manufactured oil-water separator that also removes solids via sedimentation. A statistical model developed from the experimental data shows that, under normal operating conditions, influent particle size can be used to accurately estimate effluent total suspended solids (TSS) for BMPs of this type. Relationships between particle size and particle-bound metal concentrations for Cu, Zn and Pb were then obtained from the literature and incorporated into the model to allow estimates of metal removal efficiencies based on TSS and PSD. The model can be used with an arbitrary particle size distribution (PSD); this allows effluent quality predictions to be made considering that particle sizes entering stormwater BMPs could vary due to anthropogenic, hydraulic or hydrologic factors. To place these experimental and modeling results in the context of an urban environment, samples of deposited stormwater solids were collected from residential areas, commercial areas and an industrial zone in Portland, Oregon, and the PSD of each sample was determined using light obstruction particle sizing. PSDs ranging over sizes from 3μm to 200μm vary among these locations. Areas with high anthropogenic impact were found to have PSDs skewed toward the smallest particle sizes. The statistical model developed here was then used to show that the effluent quality of the BMP tested would differ depending on the locations where solids were collected. The evidence presented in this thesis thus indicates that device performance will correlate with geographic locations or land use zone and validates further investigation into delineating the City of Portland's characteristic runoff zones and using the runoff characteristics of each zone to map it to the most desirable treatment practices. Close

• 45. [Article] Examining the Effects of Climate Change and Urban Development on Water Demand: A Multi-Scale Analysis of Future Water Demand in Hillsboro, Oregon

  In the Portland, Oregon, metropolitan area, suburban cities such as Hillsboro are projected to grow as people seek affordable housing near a rapidly growing metropolis. This thesis examines the combined ...

  Citation × Citation Citation Abstract Copy Title: Examining the Effects of Climate Change and Urban Development on Water Demand: A Multi-Scale Analysis of Future Water Demand in Hillsboro, Oregon Author: House-Peters, Lily Year: 2010 In the Portland, Oregon, metropolitan area, suburban cities such as Hillsboro are projected to grow as people seek affordable housing near a rapidly growing metropolis. This thesis examines the combined impact of'c1imate change and urban development on both neighborhood and municipal scale residential water demand in Hillsboro, Oregon. I use two models, a surface energy balance model, Local-scale Urban Meteorological Parameterization Scheme (LUMPS), and a system dynamics model, CCDomestic, to investigate changes in residential water demand in the 2040s at two distinct spatial scales, the neighborhood and the municipality. I calibrate and validate each model to the reference period and then simulate the future (2030-2059) under three statistically downscaled global climate models and two urban development scenarios. The findings of this study indicate that climate change and urban development will not evenly affect water consumption in neighborhoods across a city. Instead, the current land cover and residential density of a neighborhood exert an important influence on the response. Heavily vegetated neighborhoods exhibit large increases in water demand under urban sprawl and warming scenarios, while neighborhoods dominated by impervious surfaces decrease water consumption under sprawl scenarios and show little change in water consumption under combined sprawl and warming scenarios. At the municipal scale findings suggest that water demand is highly sensitive to urban design and management and that the combination of urban densification and water conservation regulations could mitigate increases in water consumption from population growth and climate change. Title: Examining the Effects of Climate Change and Urban Development on Water Demand: A Multi-Scale Analysis of Future Water Demand in Hillsboro, Oregon Author: House-Peters, Lily Year: 2010 In the Portland, Oregon, metropolitan area, suburban cities such as Hillsboro are projected to grow as people seek affordable housing near a rapidly growing metropolis. This thesis examines the combined impact of'c1imate change and urban development on both neighborhood and municipal scale residential water demand in Hillsboro, Oregon. I use two models, a surface energy balance model, Local-scale Urban Meteorological Parameterization Scheme (LUMPS), and a system dynamics model, CCDomestic, to investigate changes in residential water demand in the 2040s at two distinct spatial scales, the neighborhood and the municipality. I calibrate and validate each model to the reference period and then simulate the future (2030-2059) under three statistically downscaled global climate models and two urban development scenarios. The findings of this study indicate that climate change and urban development will not evenly affect water consumption in neighborhoods across a city. Instead, the current land cover and residential density of a neighborhood exert an important influence on the response. Heavily vegetated neighborhoods exhibit large increases in water demand under urban sprawl and warming scenarios, while neighborhoods dominated by impervious surfaces decrease water consumption under sprawl scenarios and show little change in water consumption under combined sprawl and warming scenarios. At the municipal scale findings suggest that water demand is highly sensitive to urban design and management and that the combination of urban densification and water conservation regulations could mitigate increases in water consumption from population growth and climate change. Close

• 46. [Article] 3D Numerical Temperature Model Development and Calibration for Lakes and Reservoirs: A Case Study

  A 3D hydrodynamic and temperature numerical model was developed and calibrated for Lake Chaplain, Washington, USA. The governing equations are the continuity equation, free surface equation, momentum equation, ...

  Citation × Citation Citation Abstract Copy Title: 3D Numerical Temperature Model Development and Calibration for Lakes and Reservoirs: A Case Study Author: Al-Zubaidi, Hussein A. M., Wells, Scott A. Year: 2017 A 3D hydrodynamic and temperature numerical model was developed and calibrated for Lake Chaplain, Washington, USA. The governing equations are the continuity equation, free surface equation, momentum equation, and conservation equation of transport. The model employs the semi-implicit finite difference scheme to solve the governing equations and higher order schemes (QUICK and Quickest) for mass and heat transport in contrast to simpler but more diffusive first order UPWIND scheme. A unique feature of the 3D numerical solution of the model free surface equation is that the solution uses a tri-diagonal matrix form rather than a more common pentadiagonal matrix. The surface heat exchange and turbulence structure were based on the CE-QUAL-W2 model. Comparisons in water surface levels and temperature vertical profiles between model predictions and data were performed using different advective transport schemes. The model matched data with good error statistics. Title: 3D Numerical Temperature Model Development and Calibration for Lakes and Reservoirs: A Case Study Author: Al-Zubaidi, Hussein A. M., Wells, Scott A. Year: 2017 A 3D hydrodynamic and temperature numerical model was developed and calibrated for Lake Chaplain, Washington, USA. The governing equations are the continuity equation, free surface equation, momentum equation, and conservation equation of transport. The model employs the semi-implicit finite difference scheme to solve the governing equations and higher order schemes (QUICK and Quickest) for mass and heat transport in contrast to simpler but more diffusive first order UPWIND scheme. A unique feature of the 3D numerical solution of the model free surface equation is that the solution uses a tri-diagonal matrix form rather than a more common pentadiagonal matrix. The surface heat exchange and turbulence structure were based on the CE-QUAL-W2 model. Comparisons in water surface levels and temperature vertical profiles between model predictions and data were performed using different advective transport schemes. The model matched data with good error statistics. Close

• 47. [Article] Validation of the CE-QUAL-W2 Version 3 River Basin Hydrodynamic and Water Quality Model

  CE-QUAL-W2 Version 3, a 2-D (longitudinal-vertical) hydrodynamic and water quality model for river basins combining both river and stratified river-estuary and lakereservoir flow, is a development product ...

  Citation × Citation Citation Abstract Copy Title: Validation of the CE-QUAL-W2 Version 3 River Basin Hydrodynamic and Water Quality Model Author: Wells, Scott A. Year: 2002 CE-QUAL-W2 Version 3, a 2-D (longitudinal-vertical) hydrodynamic and water quality model for river basins combining both river and stratified river-estuary and lakereservoir flow, is a development product of the Waterways Experiment Station in Vicksburg, MS, USA. With the development and release of any revised or reformulated model codes, significant model validation is required. This includes comparison of model results to simple analytical solutions for hydrodynamics and water quality transport, as well as comparison to laboratory and field data. In this paper, the model is compared to numerous analytical solutions for mass transport (1-D advective mass transport) and hydrodynamics (impulsive wind stress on water surface, seiching). Suggestions are presented for proper validation protocols for hydrodynamic and water quality models. Title: Validation of the CE-QUAL-W2 Version 3 River Basin Hydrodynamic and Water Quality Model Author: Wells, Scott A. Year: 2002 CE-QUAL-W2 Version 3, a 2-D (longitudinal-vertical) hydrodynamic and water quality model for river basins combining both river and stratified river-estuary and lakereservoir flow, is a development product of the Waterways Experiment Station in Vicksburg, MS, USA. With the development and release of any revised or reformulated model codes, significant model validation is required. This includes comparison of model results to simple analytical solutions for hydrodynamics and water quality transport, as well as comparison to laboratory and field data. In this paper, the model is compared to numerous analytical solutions for mass transport (1-D advective mass transport) and hydrodynamics (impulsive wind stress on water surface, seiching). Suggestions are presented for proper validation protocols for hydrodynamic and water quality models. Close

• 48. [Article] Basis of the CE-QUAL-W2 Version 3 River Basin Hydrodynamic and Water Quality Model

  CE-QUAL-W2 Version 3, a 2-D (longitudinal-vertical) hydrodynamic and water quality model for river basins combining both river and stratified river-estuary and lake-reservoir flow, is a development product ...

  Citation × Citation Citation Abstract Copy Title: Basis of the CE-QUAL-W2 Version 3 River Basin Hydrodynamic and Water Quality Model Author: Wells, Scott A. Year: 2002 CE-QUAL-W2 Version 3, a 2-D (longitudinal-vertical) hydrodynamic and water quality model for river basins combining both river and stratified river-estuary and lake-reservoir flow, is a development product of the Waterways Experiment Station in Vicksburg, MS, USA. With the development and release of any revised or reformulated model codes, significant model validation is required. This includes comparison of model results to simple analytical solutions for hydrodynamics and water quality transport, as well as comparison to laboratory and field data. In this paper, the model is compared to numerous analytical solutions for mass transport (1- D advective mass transport) and hydrodynamics (impulsive wind stress on water surface, seiching). Suggestions are presented for proper validation protocols for hydrodynamic and water quality models. Title: Basis of the CE-QUAL-W2 Version 3 River Basin Hydrodynamic and Water Quality Model Author: Wells, Scott A. Year: 2002 CE-QUAL-W2 Version 3, a 2-D (longitudinal-vertical) hydrodynamic and water quality model for river basins combining both river and stratified river-estuary and lake-reservoir flow, is a development product of the Waterways Experiment Station in Vicksburg, MS, USA. With the development and release of any revised or reformulated model codes, significant model validation is required. This includes comparison of model results to simple analytical solutions for hydrodynamics and water quality transport, as well as comparison to laboratory and field data. In this paper, the model is compared to numerous analytical solutions for mass transport (1- D advective mass transport) and hydrodynamics (impulsive wind stress on water surface, seiching). Suggestions are presented for proper validation protocols for hydrodynamic and water quality models. Close

• 49. [Article] Water Purification Technologies: From a Residential Scale Perspective

  The Problem: Small communities in many parts of the world do not have fresh water, especially after natural disasters. Many Puerto Rico local governments did not investigate and maintain local water purification ...

  Citation × Citation Citation Abstract Copy Title: Water Purification Technologies: From a Residential Scale Perspective Author: Nguyen, Tin, Owaishiz, Abdalilah, Ryan, Mark Year: 2017 The Problem: Small communities in many parts of the world do not have fresh water, especially after natural disasters. Many Puerto Rico local governments did not investigate and maintain local water purification and pipe systems or possible superfund sites in preparation of natural disasters because they do not have enough staff due to Territory and EPA budget cuts. Local governments in Puerto Rico need to continue to react quickly because a majority of regional communities who have had community water service have not been able to restore their water systems. According to Vox, “there have also been reports of water contaminated raw sewage and at least 74 suspected cases and two deaths from leptospirosis, a deadly animal-borne disease that can also live in water” [31]. If people in Puerto Rico keep drinking water from dirty water pump systems due to the shortage of drinking water many more people in Puerto Rico can become seriously ill and may lead to death. Local governments in Puerto Rico need to reach out to the EPA and CDCP to provide effective strategies of water purification and help citizens by providing clean water technology to examine water that contains virus and contamination. The United States government needs to collaborate with Puerto Rico to resolve the environment issues occurring. According to Vox, “there are 18 superfund sites in Puerto Rico, including the Dorado Groundwater Contamination Site in the north-central part of the island where some people were getting their water. The site is part of a drinking water system that serves 67,000 people” [31]. According to Peter Lopez, the newly appointed head of EPA Region II, “From my experience, communities that are struggling financially are going to be hardest pressed to respond” [31]. This is a challenge when local governments do not receive help from FEMA to have funding for the healthcare fund, superfund site investigation, maintenance of pump systems, and delivery cost for thousands of bottles of water to reach Puerto Ricans hands. People have to use this unsafe water and they try to boil it but the taste is unacceptable. According to Oren and Atabey for USA today, Ortiz worries that the bad-tasting, blue-colored water that runs in her pipes is unsafe. She and her aunt use it only to clean clothes and dishes, and to shower. They had tried boiling it, but “it tasted weird,” Ortiz said. Bottled water can be hard to find and gets expensive, said her aunt, Maria Ortiz, 66. “If you are lucky to find some, a pack of 24 water bottles that used to be $3.99 now is about $7.50,” she said [32]. More and more Puerto Ricans are having a shortage of water delivered to them due to the lack of staffing. Our Focus: Evaluate water purification technologies in communities (at the residential level) of Puerto Rico and other Island Nations which have recently been devastated by hurricanes and are suffering greatly from lack of fresh water. Introduction: Less than 1% of the water on this planet is fresh water suitable for human use and most of that is inaccessible being frozen in polar ice caps. Climate change furthers this discrepancy when global temperatures rise. Climate becomes more radical increasing climatic extremes and causing more natural disasters. Contamination is a great risk to our water; especially surface water where pathogenic bacteria and microbes flourish and dissolved dirt can make it turbid. This is a problem on a massive global scale, but locally it is not challenging to solve. Providing clean water and educating people locally at the residential level is relatively easy. Title: Water Purification Technologies: From a Residential Scale Perspective Author: Nguyen, Tin, Owaishiz, Abdalilah, Ryan, Mark Year: 2017 The Problem: Small communities in many parts of the world do not have fresh water, especially after natural disasters. Many Puerto Rico local governments did not investigate and maintain local water purification and pipe systems or possible superfund sites in preparation of natural disasters because they do not have enough staff due to Territory and EPA budget cuts. Local governments in Puerto Rico need to continue to react quickly because a majority of regional communities who have had community water service have not been able to restore their water systems. According to Vox, “there have also been reports of water contaminated raw sewage and at least 74 suspected cases and two deaths from leptospirosis, a deadly animal-borne disease that can also live in water” [31]. If people in Puerto Rico keep drinking water from dirty water pump systems due to the shortage of drinking water many more people in Puerto Rico can become seriously ill and may lead to death. Local governments in Puerto Rico need to reach out to the EPA and CDCP to provide effective strategies of water purification and help citizens by providing clean water technology to examine water that contains virus and contamination. The United States government needs to collaborate with Puerto Rico to resolve the environment issues occurring. According to Vox, “there are 18 superfund sites in Puerto Rico, including the Dorado Groundwater Contamination Site in the north-central part of the island where some people were getting their water. The site is part of a drinking water system that serves 67,000 people” [31]. According to Peter Lopez, the newly appointed head of EPA Region II, “From my experience, communities that are struggling financially are going to be hardest pressed to respond” [31]. This is a challenge when local governments do not receive help from FEMA to have funding for the healthcare fund, superfund site investigation, maintenance of pump systems, and delivery cost for thousands of bottles of water to reach Puerto Ricans hands. People have to use this unsafe water and they try to boil it but the taste is unacceptable. According to Oren and Atabey for USA today, Ortiz worries that the bad-tasting, blue-colored water that runs in her pipes is unsafe. She and her aunt use it only to clean clothes and dishes, and to shower. They had tried boiling it, but “it tasted weird,” Ortiz said. Bottled water can be hard to find and gets expensive, said her aunt, Maria Ortiz, 66. “If you are lucky to find some, a pack of 24 water bottles that used to be $3.99 now is about $7.50,” she said [32]. More and more Puerto Ricans are having a shortage of water delivered to them due to the lack of staffing. Our Focus: Evaluate water purification technologies in communities (at the residential level) of Puerto Rico and other Island Nations which have recently been devastated by hurricanes and are suffering greatly from lack of fresh water. Introduction: Less than 1% of the water on this planet is fresh water suitable for human use and most of that is inaccessible being frozen in polar ice caps. Climate change furthers this discrepancy when global temperatures rise. Climate becomes more radical increasing climatic extremes and causing more natural disasters. Contamination is a great risk to our water; especially surface water where pathogenic bacteria and microbes flourish and dissolved dirt can make it turbid. This is a problem on a massive global scale, but locally it is not challenging to solve. Providing clean water and educating people locally at the residential level is relatively easy. Close

• 50. [Article] Bottom Topography Mapping via Nonlinear Data Assimilation

  A variational data assimilation method is described for bottom topography mapping in rivers and estuaries using remotely sensed observations of water surface currents. The velocity field and bottom topography ...

  Citation × Citation Citation Abstract Copy Title: Bottom Topography Mapping via Nonlinear Data Assimilation Author: Zaron, Edward D., Pradal, Marie-Aude, Miller, Patrick D., Blumberg, Alan F., Georgas, Nickitas, Li, Wei, Cornuelle, Julia Muccino Year: 2011 A variational data assimilation method is described for bottom topography mapping in rivers and estuaries using remotely sensed observations of water surface currents. The velocity field and bottom topography are related by the vertically integrated momentum and continuity equations, leading to a nonlinear inverse problem for bottom topography, which is solved using a Picard iteration strategy combined with a nonlinear line search. An illustration of the method is shown for Haverstraw Bay, in the Hudson River, where the known bottom topography is well reconstructed. Once the topography has been estimated, currents and water levels may be forecast. The method makes feasible 1) the estimation of bottom topography in regions where in situ data collection may be impossible, dangerous, or expensive, and 2) the calibration of barotropic shallow-water models via control of the bottom topography. Title: Bottom Topography Mapping via Nonlinear Data Assimilation Author: Zaron, Edward D., Pradal, Marie-Aude, Miller, Patrick D., Blumberg, Alan F., Georgas, Nickitas, Li, Wei, Cornuelle, Julia Muccino Year: 2011 A variational data assimilation method is described for bottom topography mapping in rivers and estuaries using remotely sensed observations of water surface currents. The velocity field and bottom topography are related by the vertically integrated momentum and continuity equations, leading to a nonlinear inverse problem for bottom topography, which is solved using a Picard iteration strategy combined with a nonlinear line search. An illustration of the method is shown for Haverstraw Bay, in the Hudson River, where the known bottom topography is well reconstructed. Once the topography has been estimated, currents and water levels may be forecast. The method makes feasible 1) the estimation of bottom topography in regions where in situ data collection may be impossible, dangerous, or expensive, and 2) the calibration of barotropic shallow-water models via control of the bottom topography. Close

• 51. [Article] An Analysis of Secular Change in Tides at Open-Ocean Sites in the Pacific

  Hourly sea level is examined at 25 open-ocean stations in the Pacific Ocean with records longer than 30 yr. A search for trends finds that the amplitude of the dominant semidiurnal tide M2 is increasing ...

  Citation × Citation Citation Abstract Copy Title: An Analysis of Secular Change in Tides at Open-Ocean Sites in the Pacific Author: Zaron, Edward D., Jay, David A. Year: 2014 Hourly sea level is examined at 25 open-ocean stations in the Pacific Ocean with records longer than 30 yr. A search for trends finds that the amplitude of the dominant semidiurnal tide M2 is increasing at 12 of the 13 sites where a statistically significant trend can be identified. It is also found that nontidal variance in the neighborhood of M2 is decreasing at all 12 of the sites where a significant increase in M2 tide is occurring. The trend in amplitude of the dominant diurnal tide K1 is significant at six stations, and it is both increasing (four stations) and decreasing (two stations). The trend in semidiurnal-band variance suggests the hypothesis that increases in M2 could be caused by improvements in time keeping or data processing that would reduce the apparent phase variability of the tide. This possibility is examined and found to be the likely explanation for tidal trends at four stations. Local changes are found to explain the trend at two stations, Johnston Island and Mokuoloe, as diagnosed from correlated changes in nonlinear overtides and site history. Changes in M2 at the equatorial station of Kanton are significant and unexplained by either timing errors or local morphodynamics; although, strong nonlinear overtides are present. Changing tides at five stations in the western Pacific, Malakal, Yap, Saipan, Kapingamarangi, and Pohnpei cannot be explained by the above and suggest a region where a connection between climate and tides may yet be identified. Title: An Analysis of Secular Change in Tides at Open-Ocean Sites in the Pacific Author: Zaron, Edward D., Jay, David A. Year: 2014 Hourly sea level is examined at 25 open-ocean stations in the Pacific Ocean with records longer than 30 yr. A search for trends finds that the amplitude of the dominant semidiurnal tide M2 is increasing at 12 of the 13 sites where a statistically significant trend can be identified. It is also found that nontidal variance in the neighborhood of M2 is decreasing at all 12 of the sites where a significant increase in M2 tide is occurring. The trend in amplitude of the dominant diurnal tide K1 is significant at six stations, and it is both increasing (four stations) and decreasing (two stations). The trend in semidiurnal-band variance suggests the hypothesis that increases in M2 could be caused by improvements in time keeping or data processing that would reduce the apparent phase variability of the tide. This possibility is examined and found to be the likely explanation for tidal trends at four stations. Local changes are found to explain the trend at two stations, Johnston Island and Mokuoloe, as diagnosed from correlated changes in nonlinear overtides and site history. Changes in M2 at the equatorial station of Kanton are significant and unexplained by either timing errors or local morphodynamics; although, strong nonlinear overtides are present. Changing tides at five stations in the western Pacific, Malakal, Yap, Saipan, Kapingamarangi, and Pohnpei cannot be explained by the above and suggest a region where a connection between climate and tides may yet be identified. Close

• 52. [Article] Hydrogeology of Pumice-Hosted Fens in the Winema-Fremont National Forest, Oregon, USA

  Subaerial fallout from the Holocene eruption of Mount Mazama in the Oregon Cascade Range was deposited upon relatively low permeability volcanic and volcaniclastic bedrock and regolith. In the Walker Rim ...

  Citation × Citation Citation Abstract Copy Title: Hydrogeology of Pumice-Hosted Fens in the Winema-Fremont National Forest, Oregon, USA Author: Cummings, Michael L., Weatherford, Jonathan Michael, Mowbray, Leslie A Year: 2014 Subaerial fallout from the Holocene eruption of Mount Mazama in the Oregon Cascade Range was deposited upon relatively low permeability volcanic and volcaniclastic bedrock and regolith. In the Walker Rim study area, erosion by ephemeral streams shortly after the eruption disrupted the lateral continuity of the 270 to 300 cm-thick pumice deposit. Co-evolution of the surface- and ground-water systems in a low-relief, low-slope landscape allowed diffuse groundwater discharge from the banks of the evolving stream system. Accumulation of organic material from groundwater dependent ecosystems at these sites of discharge allowed peat deposits to form on gently sloping erosion surfaces cut into the pumice deposit. Following early stream incision, fine-grained, silt-rich deposits accumulated in valleys and contributed permeability barriers to the lateral migration of water in the pumice aquifer. Fens discharge from the pumice aquifer through gently sloping surfaces patterned after the slope of the erosion surface cut into the pumice deposit and overlain by approximately 1 m of peat on the sloping surface and alluvium or iron-cemented pumice overlain by alluvium at the toe of the slope. The predominant source of groundwater is snowmelt which infiltrates the pumice deposit during the freshet. However, shallow groundwater flow also takes place along permeable pathways in bedrock units. Locally, low volume discharge takes place along faults. The snowmelt-dependent hydrologic system that supports the fens of the Walker Rim study area occurs at elevations primarily above 1585 m. Title: Hydrogeology of Pumice-Hosted Fens in the Winema-Fremont National Forest, Oregon, USA Author: Cummings, Michael L., Weatherford, Jonathan Michael, Mowbray, Leslie A Year: 2014 Subaerial fallout from the Holocene eruption of Mount Mazama in the Oregon Cascade Range was deposited upon relatively low permeability volcanic and volcaniclastic bedrock and regolith. In the Walker Rim study area, erosion by ephemeral streams shortly after the eruption disrupted the lateral continuity of the 270 to 300 cm-thick pumice deposit. Co-evolution of the surface- and ground-water systems in a low-relief, low-slope landscape allowed diffuse groundwater discharge from the banks of the evolving stream system. Accumulation of organic material from groundwater dependent ecosystems at these sites of discharge allowed peat deposits to form on gently sloping erosion surfaces cut into the pumice deposit. Following early stream incision, fine-grained, silt-rich deposits accumulated in valleys and contributed permeability barriers to the lateral migration of water in the pumice aquifer. Fens discharge from the pumice aquifer through gently sloping surfaces patterned after the slope of the erosion surface cut into the pumice deposit and overlain by approximately 1 m of peat on the sloping surface and alluvium or iron-cemented pumice overlain by alluvium at the toe of the slope. The predominant source of groundwater is snowmelt which infiltrates the pumice deposit during the freshet. However, shallow groundwater flow also takes place along permeable pathways in bedrock units. Locally, low volume discharge takes place along faults. The snowmelt-dependent hydrologic system that supports the fens of the Walker Rim study area occurs at elevations primarily above 1585 m. Close

• 53. [Article] CE-QUAL-W2 Version 3: Hydrodynamic and Water Quality River Basin Modeling

  CE-QUAL-W2 is a two-dimensional (longitudinal-vertical) water quality and hydrodynamic computer simulation model that was originally developed for deep, long, and narrow waterbodies. The current model, ...

  Citation × Citation Citation Abstract Copy Title: CE-QUAL-W2 Version 3: Hydrodynamic and Water Quality River Basin Modeling Author: Wells, Scott A. Year: 2000 CE-QUAL-W2 is a two-dimensional (longitudinal-vertical) water quality and hydrodynamic computer simulation model that was originally developed for deep, long, and narrow waterbodies. The current model, Version 2, has been used in over 200 river, reservoir/lake, and estuary applications throughout the U.S. and abroad. Version 2, though, cannot accommodate systems that have a significant sloping water surface since the vertical coordinate system is aligned with gravity and vertical accelerations are neglected. The governing equations for CE-QUAL-W2 were re-derived so that it could be applied to entire river basins including river-estuary, lake-river, and reservoir-river systems with channel slopes. This re-derivation is one of many improvements for the Version 3 code. Other improvements include improved numerical schemes, improved and additional water quality algorithms, and algorithms for addition of hydraulic structures (weirs, gates, culverts) between model segments. Test cases for this new code include a 244 km section of the Lower Snake River in Idaho and Oregon; the Bull Run River basin composed of 3 water supply reservoirs and 2 river sections with a 2.2% and a 1.4% average slope in the Oregon Cascade mountains; and the Columbia Slough system in Portland, OR, composed of 33 separate lake systems connected by hydraulic structures and a fresh-water tidal region. Title: CE-QUAL-W2 Version 3: Hydrodynamic and Water Quality River Basin Modeling Author: Wells, Scott A. Year: 2000 CE-QUAL-W2 is a two-dimensional (longitudinal-vertical) water quality and hydrodynamic computer simulation model that was originally developed for deep, long, and narrow waterbodies. The current model, Version 2, has been used in over 200 river, reservoir/lake, and estuary applications throughout the U.S. and abroad. Version 2, though, cannot accommodate systems that have a significant sloping water surface since the vertical coordinate system is aligned with gravity and vertical accelerations are neglected. The governing equations for CE-QUAL-W2 were re-derived so that it could be applied to entire river basins including river-estuary, lake-river, and reservoir-river systems with channel slopes. This re-derivation is one of many improvements for the Version 3 code. Other improvements include improved numerical schemes, improved and additional water quality algorithms, and algorithms for addition of hydraulic structures (weirs, gates, culverts) between model segments. Test cases for this new code include a 244 km section of the Lower Snake River in Idaho and Oregon; the Bull Run River basin composed of 3 water supply reservoirs and 2 river sections with a 2.2% and a 1.4% average slope in the Oregon Cascade mountains; and the Columbia Slough system in Portland, OR, composed of 33 separate lake systems connected by hydraulic structures and a fresh-water tidal region. Close

• 54. [Article] A Comparison of Five Models for Estimating Clear-Sky Solar Radiation

  Many agencies in the USA are developing management approaches to address water quality concerns and threatened and endangered species habitat requirements in water bodies. Many of these water bodies are ...

  Citation × Citation Citation Abstract Copy Title: A Comparison of Five Models for Estimating Clear-Sky Solar Radiation Author: Annear, Robert Leslie, Wells, Scott A. Year: 2007 Many agencies in the USA are developing management approaches to address water quality concerns and threatened and endangered species habitat requirements in water bodies. Many of these water bodies are water quality limited for temperature. Factors influencing stream temperature include: streamside vegetation, topographic shading, inflows and outflows, stream width, stream depth, light extinction and solar radiation. One of the key driving factors in estimating a water body heat budget is calculating the amount of solar radiation incident on the water surface. Even though it is preferable to measure clear-sky solar radiation, many temperature models rely on theoretical estimates of clear-sky solar radiation. The literature on estimating short-wave solar radiation by calculating the position of the sun and attenuating the radiation through the atmosphere was reviewed. As a first step in relating water temperature to solar radiation, several empirical solar radiation models were calibrated to data at seventeen sites around the United States for clear-sky days. Sensitivity analyses were conducted and differences between the models were examined. Results indicated that the more complex models for calculating solar radiation resulted in better estimates of clear-sky solar radiation once they were calibrated to data. When no data were available, models with one or no calibration parameters did reasonably well at estimating clear-sky solar radiation. Title: A Comparison of Five Models for Estimating Clear-Sky Solar Radiation Author: Annear, Robert Leslie, Wells, Scott A. Year: 2007 Many agencies in the USA are developing management approaches to address water quality concerns and threatened and endangered species habitat requirements in water bodies. Many of these water bodies are water quality limited for temperature. Factors influencing stream temperature include: streamside vegetation, topographic shading, inflows and outflows, stream width, stream depth, light extinction and solar radiation. One of the key driving factors in estimating a water body heat budget is calculating the amount of solar radiation incident on the water surface. Even though it is preferable to measure clear-sky solar radiation, many temperature models rely on theoretical estimates of clear-sky solar radiation. The literature on estimating short-wave solar radiation by calculating the position of the sun and attenuating the radiation through the atmosphere was reviewed. As a first step in relating water temperature to solar radiation, several empirical solar radiation models were calibrated to data at seventeen sites around the United States for clear-sky days. Sensitivity analyses were conducted and differences between the models were examined. Results indicated that the more complex models for calculating solar radiation resulted in better estimates of clear-sky solar radiation once they were calibrated to data. When no data were available, models with one or no calibration parameters did reasonably well at estimating clear-sky solar radiation. Close

• 55. [Article] Idaho Pend Oreille River Model: Model Development and Calibration

  The objectives of this project were to: • Develop a hydrodynamic and temperature model of Pend Oreille River using CE-QUAL-W2 Version 3.2 • Calibrate the CE-QUAL-W2 model to field data collected during ...

  Citation × Citation Citation Abstract Copy Title: Idaho Pend Oreille River Model: Model Development and Calibration Author: Annear, Robert Leslie, Berger, Chris, Wells, Scott A. Year: 2006 The objectives of this project were to: • Develop a hydrodynamic and temperature model of Pend Oreille River using CE-QUAL-W2 Version 3.2 • Calibrate the CE-QUAL-W2 model to field data collected during 2004 and 2005 using the following water quality variables: flow, water surface elevation, and velocity temperature o dissolved oxygen nutrients (NO3-N+NO2-N, NH4-N, PO4-P) algae – chlorophyll a BOD5 and dissolved organic matter and particulate organic matter compartments (both labile and refractory) for the organic matter cycling with algae periphyton The model chosen for development was CE-QUAL-W2 Version 3.2 (Cole and Wells, 2004). This is a two-dimensional unsteady hydrodynamic and water quality model that includes typical eutrophication constituents (algae, nutrients, temperature, organic matter, dissolved oxygen, pH). Portland State University’s Water Quality Research Group is a center for development of this modeling tool (see http://www.cee.pdx.edu/w2). The model simulation was run from January 1st, 2004 to September 25th, 2005. The calibration period focused on the summers during each year when water quality data were obtained. Title: Idaho Pend Oreille River Model: Model Development and Calibration Author: Annear, Robert Leslie, Berger, Chris, Wells, Scott A. Year: 2006 The objectives of this project were to: • Develop a hydrodynamic and temperature model of Pend Oreille River using CE-QUAL-W2 Version 3.2 • Calibrate the CE-QUAL-W2 model to field data collected during 2004 and 2005 using the following water quality variables: flow, water surface elevation, and velocity temperature o dissolved oxygen nutrients (NO3-N+NO2-N, NH4-N, PO4-P) algae – chlorophyll a BOD5 and dissolved organic matter and particulate organic matter compartments (both labile and refractory) for the organic matter cycling with algae periphyton The model chosen for development was CE-QUAL-W2 Version 3.2 (Cole and Wells, 2004). This is a two-dimensional unsteady hydrodynamic and water quality model that includes typical eutrophication constituents (algae, nutrients, temperature, organic matter, dissolved oxygen, pH). Portland State University’s Water Quality Research Group is a center for development of this modeling tool (see http://www.cee.pdx.edu/w2). The model simulation was run from January 1st, 2004 to September 25th, 2005. The calibration period focused on the summers during each year when water quality data were obtained. Close

• 56. [Article] Modeling the Impact of Water Quality and Food Web Structure on Bull Trout in Two Washington Reservoirs

  Mechanistic models of the hydrodynamics and water quality were developed for Lake Kachess and Lake Keechelus in the Yakima River basin of Eastern Washington. These models were coupled to a fish bioenergetics ...

  Citation × Citation Citation Abstract Copy Title: Modeling the Impact of Water Quality and Food Web Structure on Bull Trout in Two Washington Reservoirs Author: Berger, Chris J., Wells, Scott A. Year: 2017 Mechanistic models of the hydrodynamics and water quality were developed for Lake Kachess and Lake Keechelus in the Yakima River basin of Eastern Washington. These models were coupled to a fish bioenergetics model and used to explore management strategies to improve water quality in the reservoirs affecting kokanee production. The models were also applied to evaluate the impacts of the proposed implementation of the Kachess Drought Relief Pumping Plant (KDRPP) projects. The public domain model, CEQUAL-W2 Version 4 (Cole and Wells, 2016) was adapted to model the reservoirs. CEQUAL-W2 is a 2-dimensional (longitudinal-vertical) hydrodynamic and water quality model capable of predicting water surface, velocity, temperature, nutrients, multiple algae, zooplankton, periphyton, and macrophyte species, fish bioenergetics, sediment diagenesis, dissolved oxygen, pH, alkalinity, multiple CBOD groups, multiple suspended solids groups, multiple generic constituents (such as tracer, bacteria, toxics), and multiple organic matter groups, both dissolved and particulate. The model is set up to predict these state variables at longitudinal segments and vertical layers. Comparisons of field data to model predictions were made for water level, temperature, NH4-N, NO3-N, PO4-P, total N, Total P, total organic carbon, alkalinity, zooplankton, pH, chlorophyll a, and dissolved oxygen at multiple reservoir sites at various depths. Title: Modeling the Impact of Water Quality and Food Web Structure on Bull Trout in Two Washington Reservoirs Author: Berger, Chris J., Wells, Scott A. Year: 2017 Mechanistic models of the hydrodynamics and water quality were developed for Lake Kachess and Lake Keechelus in the Yakima River basin of Eastern Washington. These models were coupled to a fish bioenergetics model and used to explore management strategies to improve water quality in the reservoirs affecting kokanee production. The models were also applied to evaluate the impacts of the proposed implementation of the Kachess Drought Relief Pumping Plant (KDRPP) projects. The public domain model, CEQUAL-W2 Version 4 (Cole and Wells, 2016) was adapted to model the reservoirs. CEQUAL-W2 is a 2-dimensional (longitudinal-vertical) hydrodynamic and water quality model capable of predicting water surface, velocity, temperature, nutrients, multiple algae, zooplankton, periphyton, and macrophyte species, fish bioenergetics, sediment diagenesis, dissolved oxygen, pH, alkalinity, multiple CBOD groups, multiple suspended solids groups, multiple generic constituents (such as tracer, bacteria, toxics), and multiple organic matter groups, both dissolved and particulate. The model is set up to predict these state variables at longitudinal segments and vertical layers. Comparisons of field data to model predictions were made for water level, temperature, NH4-N, NO3-N, PO4-P, total N, Total P, total organic carbon, alkalinity, zooplankton, pH, chlorophyll a, and dissolved oxygen at multiple reservoir sites at various depths. Close

• 57. [Article] Development of a Steady-State River Hydrodynamic and Temperature Model Based on CE-QUAL-W2

  CE-QUAL-W2 is a 2-D hydrodynamic and water quality model that has been applied to reservoirs, lakes, river systems, and estuaries throughout the world. However, when this model is applied for shallow systems, ...

  Citation × Citation Citation Abstract Copy Title: Development of a Steady-State River Hydrodynamic and Temperature Model Based on CE-QUAL-W2 Author: Xu, Wenwei Year: 2014 CE-QUAL-W2 is a 2-D hydrodynamic and water quality model that has been applied to reservoirs, lakes, river systems, and estuaries throughout the world. However, when this model is applied for shallow systems, this model requires a long calculation time to maintain numerical stability, compared to applications of reservoirs or deeper river systems. To solve this problem, a new hydrodynamic and temperature model was built based on the framework of CE-QUAL-W2 but that allows for steady-state hydrodynamic computations. By calculating the hydrodynamics at steady-state, the time step for stability is relaxed and simulations can proceed at much higher time steps. The rest of the model framework is still used for water quality state variables, in this case, temperature. The algorithm used for computing the water surface elevation is Manning's equation. This thesis study is one part of the Willamette Water 2100 project (Santelmann et al., 2012), which examines hydrological, ecological, and human factors affecting water scarcity in the Willamette River Basin. This study included three stages: (1) Convert six existing CE-QUAL-W2 V3.1 models into a newer version: CE-QUAL-W2 V3.7. (2) Develop the steady-state model code in FORTRAN. (3) Test the steady-state model on three river systems in the Willamette River Basin at Year 2001 and 2002. The result proved that the steady-state model could reduce the computing time by 90% for river applications, while predicting dynamic river temperature with high accuracy at a two-minute time scale. This new model will be employed to simulate the future of the Willamette River System at a decadal or centennial timescales, addressing river temperature concerns and fish habitat issues. Title: Development of a Steady-State River Hydrodynamic and Temperature Model Based on CE-QUAL-W2 Author: Xu, Wenwei Year: 2014 CE-QUAL-W2 is a 2-D hydrodynamic and water quality model that has been applied to reservoirs, lakes, river systems, and estuaries throughout the world. However, when this model is applied for shallow systems, this model requires a long calculation time to maintain numerical stability, compared to applications of reservoirs or deeper river systems. To solve this problem, a new hydrodynamic and temperature model was built based on the framework of CE-QUAL-W2 but that allows for steady-state hydrodynamic computations. By calculating the hydrodynamics at steady-state, the time step for stability is relaxed and simulations can proceed at much higher time steps. The rest of the model framework is still used for water quality state variables, in this case, temperature. The algorithm used for computing the water surface elevation is Manning's equation. This thesis study is one part of the Willamette Water 2100 project (Santelmann et al., 2012), which examines hydrological, ecological, and human factors affecting water scarcity in the Willamette River Basin. This study included three stages: (1) Convert six existing CE-QUAL-W2 V3.1 models into a newer version: CE-QUAL-W2 V3.7. (2) Develop the steady-state model code in FORTRAN. (3) Test the steady-state model on three river systems in the Willamette River Basin at Year 2001 and 2002. The result proved that the steady-state model could reduce the computing time by 90% for river applications, while predicting dynamic river temperature with high accuracy at a two-minute time scale. This new model will be employed to simulate the future of the Willamette River System at a decadal or centennial timescales, addressing river temperature concerns and fish habitat issues. Close

• 58. [Article] Analysis of Landsat Satellite Data to Monitor Water Quality Parameters in Tenmile Lake, Oregon

  The health of North and South Tenmile Lakes in coastal Oregon has declined since the introduction of invasive species of fish and plant life in the 1920s. The lakes are now on the Federal Clean Water Act ...

  Citation × Citation Citation Abstract Copy Title: Analysis of Landsat Satellite Data to Monitor Water Quality Parameters in Tenmile Lake, Oregon Author: Waxter, Michael T. Year: 2014 The health of North and South Tenmile Lakes in coastal Oregon has declined since the introduction of invasive species of fish and plant life in the 1920s. The lakes are now on the Federal Clean Water Act list of impaired water bodies due, in part, to a lack of dissolved oxygen and Hazardous Algae Blooms (HAB) blooms that occur during June through September. In this report we discuss the possibility of detecting and monitoring these blooms using satellite measurements of water surface color. In-situ measurements obtained from the Tenmile Lakes Basin Partnership were used to calibrate reflectance from the Thematic Mapper on the Landsat 5 satellite. Results show a good linear correlation between turbidity and radiance, which are inversely related in algal dominated lakes. Additionally, a correlation between biovolume and reflectance was obtained. Spatial patterns of turbidity and biovolume are observed, with large concentrations observed in lake areas with large residence times. The comparatively lowest concentrations are observed along the probable pathway of cleaner water input by creeks into the lake. However, the ability to predict turbidity and biovolume from satellite reflectance data is currently complicated by the lack of coincident in-situ and satellite data, and the limited number of spectral bands available to separate turbidity from different species of bacteria and algae. Title: Analysis of Landsat Satellite Data to Monitor Water Quality Parameters in Tenmile Lake, Oregon Author: Waxter, Michael T. Year: 2014 The health of North and South Tenmile Lakes in coastal Oregon has declined since the introduction of invasive species of fish and plant life in the 1920s. The lakes are now on the Federal Clean Water Act list of impaired water bodies due, in part, to a lack of dissolved oxygen and Hazardous Algae Blooms (HAB) blooms that occur during June through September. In this report we discuss the possibility of detecting and monitoring these blooms using satellite measurements of water surface color. In-situ measurements obtained from the Tenmile Lakes Basin Partnership were used to calibrate reflectance from the Thematic Mapper on the Landsat 5 satellite. Results show a good linear correlation between turbidity and radiance, which are inversely related in algal dominated lakes. Additionally, a correlation between biovolume and reflectance was obtained. Spatial patterns of turbidity and biovolume are observed, with large concentrations observed in lake areas with large residence times. The comparatively lowest concentrations are observed along the probable pathway of cleaner water input by creeks into the lake. However, the ability to predict turbidity and biovolume from satellite reflectance data is currently complicated by the lack of coincident in-situ and satellite data, and the limited number of spectral bands available to separate turbidity from different species of bacteria and algae. Close

• 59. [Article] Asymmetry of Tidal Plume Fronts in an Eastern Boundary Current Regime

  The Columbia River tidal plume or near-field is formed twice daily by the ebb outflow of the Columbia River. It is a part of a larger, anticyclonic plume bulge, which in turn is embedded in far-field plume ...

  Citation × Citation Citation Abstract Copy Title: Asymmetry of Tidal Plume Fronts in an Eastern Boundary Current Regime Author: Jay, David A., Pan, Jiayi, Orton, Philip M., Horner-Devine, Alexander R. Year: 2006 The Columbia River tidal plume or near-field is formed twice daily by the ebb outflow of the Columbia River. It is a part of a larger, anticyclonic plume bulge, which in turn is embedded in far-field plume and coastal waters. Because of the mixing caused directly and indirectly by plume fronts, the interaction of the tidal plume and bulge with the California Current upwelling regime plays a vital role in coastal productivity on the Oregon and Washington shelves. The tidal plume is initially supercritical with respect to the internal Froude number on all stronger ebbs. It is separated from the plume bulge by a front, whose properties are very different under upwelling vs. downwelling conditions. Under summer upwelling conditions, this front is sharp and narrow (only 50-100 m wide on its upwind or northern side) and marks a transition from supercritical to subcritical flow for 6-12 hours after high water. This sharp front is a source of turbulent mixing, despite the strong stratification. Because the tidal plume may overlie newly upwelled waters, these fronts can mix nutrients into the plume, enhancing primary productivity. Symmetry would suggest that there should be a sharp front south of the estuary mouth under summer downwelling conditions. Instead, the downwelling tidal plume front is usually broad (up to several km) and diffuse on the upstream side. Less mixing occurs, and the water immediately below the plume consists of old plume and surface ocean waters, both low in nutrients. There is also a second up-welling-downwelling asymmetry. Supercritical upwelling plume fronts often generate solitons trains as they slow and transition to a subcritical state. These soliton trains contribute to vertical mixing in the plume bulge and have a non-zero Stokes drift so that they transport low-salinity water across the tidal plume into the plume bulge. Under downwelling conditions, soliton forma-tion is uncommon. Moreover, solition formation almost always begins on the south side of the plume so that the front "unzips" from south to north. This implies that a frontal transition from supercritical to subcritical conditions first occurs on the south side tidal plume, regardless of whether this is the upwind or downwind side of the plume. This contribution describes and analyzes these two asymmetries using vessel data, SAR images and a vorticity analysis. Internal Froude number and plume depth are key parameters in distinguishing the upwelling and downwelling situations, and the observed asymmetries can be explained in terms of potential vorticity conservation. The tidal outflow embeds relative vorticity in the emerging tidal plume water mass. This vorticity controls the transition of the tidal plume front to a subcritical state and the timing and location of internal wave generation by plume fronts. Title: Asymmetry of Tidal Plume Fronts in an Eastern Boundary Current Regime Author: Jay, David A., Pan, Jiayi, Orton, Philip M., Horner-Devine, Alexander R. Year: 2006 The Columbia River tidal plume or near-field is formed twice daily by the ebb outflow of the Columbia River. It is a part of a larger, anticyclonic plume bulge, which in turn is embedded in far-field plume and coastal waters. Because of the mixing caused directly and indirectly by plume fronts, the interaction of the tidal plume and bulge with the California Current upwelling regime plays a vital role in coastal productivity on the Oregon and Washington shelves. The tidal plume is initially supercritical with respect to the internal Froude number on all stronger ebbs. It is separated from the plume bulge by a front, whose properties are very different under upwelling vs. downwelling conditions. Under summer upwelling conditions, this front is sharp and narrow (only 50-100 m wide on its upwind or northern side) and marks a transition from supercritical to subcritical flow for 6-12 hours after high water. This sharp front is a source of turbulent mixing, despite the strong stratification. Because the tidal plume may overlie newly upwelled waters, these fronts can mix nutrients into the plume, enhancing primary productivity. Symmetry would suggest that there should be a sharp front south of the estuary mouth under summer downwelling conditions. Instead, the downwelling tidal plume front is usually broad (up to several km) and diffuse on the upstream side. Less mixing occurs, and the water immediately below the plume consists of old plume and surface ocean waters, both low in nutrients. There is also a second up-welling-downwelling asymmetry. Supercritical upwelling plume fronts often generate solitons trains as they slow and transition to a subcritical state. These soliton trains contribute to vertical mixing in the plume bulge and have a non-zero Stokes drift so that they transport low-salinity water across the tidal plume into the plume bulge. Under downwelling conditions, soliton forma-tion is uncommon. Moreover, solition formation almost always begins on the south side of the plume so that the front "unzips" from south to north. This implies that a frontal transition from supercritical to subcritical conditions first occurs on the south side tidal plume, regardless of whether this is the upwind or downwind side of the plume. This contribution describes and analyzes these two asymmetries using vessel data, SAR images and a vorticity analysis. Internal Froude number and plume depth are key parameters in distinguishing the upwelling and downwelling situations, and the observed asymmetries can be explained in terms of potential vorticity conservation. The tidal outflow embeds relative vorticity in the emerging tidal plume water mass. This vorticity controls the transition of the tidal plume front to a subcritical state and the timing and location of internal wave generation by plume fronts. Close

• 60. [Article] On the Observability of Bottom Topography from Measurements of Tidal Sea Surface Height

  of whether features of the ocean bottom topography can be identified from measurements of water level is investigated using a simplified one-dimensional barotropic model. Because of the nonlinear dependence ...

  Citation × Citation Citation Abstract Copy Title: On the Observability of Bottom Topography from Measurements of Tidal Sea Surface Height Author: Zaron, Edward D. Year: 2016 of whether features of the ocean bottom topography can be identified from measurements of water level is investigated using a simplified one-dimensional barotropic model. Because of the nonlinear dependence of the sea surface height on the water depth, a linearized analysis is performed concerning the identification of a Gaussian bump within two specific depth profiles, (1) a constant depth domain, and, (2) a constant depth domain adjoining a near-resonant continental shelf. Observability is quantified by examining the estimation error in a series of identical-twin experiments varying data density, tide wavelength, assumed (versus actual) topographic correlation scale, and friction. For measurements of sea surface height that resolve the scale of the topographic perturbation, the fractional error in the bottom topography is approximately a factor of 10 larger than the fractional error of the sea surface height. Domain-scale and shelf-scale resonances may lead to inaccurate topography estimates due to a reduction in the effective number of degrees of freedom in the dynamics, and the amplification of nonlinearity. A realizability condition for the variance of the topography error in the limit of zero bottom depth is proposed which is interpreted as a bound on the fractional error of the topography. Appropriately designed spatial covariance models partly ameliorate the negative impact of shelf-scale near-resonance, and highlight the importance of spatial covariance modeling for bottom topography estimation. Title: On the Observability of Bottom Topography from Measurements of Tidal Sea Surface Height Author: Zaron, Edward D. Year: 2016 of whether features of the ocean bottom topography can be identified from measurements of water level is investigated using a simplified one-dimensional barotropic model. Because of the nonlinear dependence of the sea surface height on the water depth, a linearized analysis is performed concerning the identification of a Gaussian bump within two specific depth profiles, (1) a constant depth domain, and, (2) a constant depth domain adjoining a near-resonant continental shelf. Observability is quantified by examining the estimation error in a series of identical-twin experiments varying data density, tide wavelength, assumed (versus actual) topographic correlation scale, and friction. For measurements of sea surface height that resolve the scale of the topographic perturbation, the fractional error in the bottom topography is approximately a factor of 10 larger than the fractional error of the sea surface height. Domain-scale and shelf-scale resonances may lead to inaccurate topography estimates due to a reduction in the effective number of degrees of freedom in the dynamics, and the amplification of nonlinearity. A realizability condition for the variance of the topography error in the limit of zero bottom depth is proposed which is interpreted as a bound on the fractional error of the topography. Appropriately designed spatial covariance models partly ameliorate the negative impact of shelf-scale near-resonance, and highlight the importance of spatial covariance modeling for bottom topography estimation. Close

• 61. [Article] Lake Roosevelt Water Quality and Hydrodynamic Model Calibration with Fish Bioenergetics

  An understanding of the effects of hydrodynamics and reservoir operations on the Franklin D. Roosevelt Lake (Lake Roosevelt) aquatic food web allows for better management of the reservoir. A CE-QUAL-W2, ...

  Citation × Citation Citation Abstract Copy Title: Lake Roosevelt Water Quality and Hydrodynamic Model Calibration with Fish Bioenergetics Author: McKillip, Michael Lee Year: 2007 An understanding of the effects of hydrodynamics and reservoir operations on the Franklin D. Roosevelt Lake (Lake Roosevelt) aquatic food web allows for better management of the reservoir. A CE-QUAL-W2, v.3.5, hydrodynamic and water quality model (Cole and Wells, 20061) is being applied to the reservoir. The models zooplankton algorithms are expanded and a fish bioenergetics model is incorporated. The Lake Roosevelt model extent is shown in Figure 1. The model includes the lacustrine arms up to full pool on the Sanpoil, Kettle, and Colville Rivers; the Spokane River arm up to Little Falls Dam; and the Columbia River from Grand Coulee Dam to the U.S.-Canadian border. The previous companion report, “Boundary Conditions and Set-up” (McKillip, Annear, and Wells, 2006), covered • A limnological overview • Hydrodynamic boundary condition data and model inputs • Grand Coulee Dam structures (powerhouse and spillway characteristics) • Water temperature boundary condition data and model inputs • Meteorological data and model inputs • Water quality boundary condition data • Model bathymetry data and model grid development • Topographic shading • Primary and secondary production data • Kokanee hatchery release data This report discusses the model calibration and issues related to the calibration. This report discusses the topics of: 1) Hydrodynamic calibration: Hydrodynamic calibration focuses on matching the water surface elevation at Grand Coulee Dam. 2) Temperature calibration: Temperature calibration focuses on matching temperature profiles throughout the reservoir and continuous data below Grand Coulee Dam. Many of the calibration issues centered on properly characterizing the localized wind and powerhouse withdrawals. 3) Abiotic water quality calibration: Abiotic water quality calibration focused on matching water quality profile data in the reservoir. The selection of proper rate kinetics and understanding the impact of hydrodynamics on water quality state variables was critical to proper calibration. 4) Bioenergetic (algae, zooplankton, kokanee) modeling approach and calibration 5) Sensitivity analyses Title: Lake Roosevelt Water Quality and Hydrodynamic Model Calibration with Fish Bioenergetics Author: McKillip, Michael Lee Year: 2007 An understanding of the effects of hydrodynamics and reservoir operations on the Franklin D. Roosevelt Lake (Lake Roosevelt) aquatic food web allows for better management of the reservoir. A CE-QUAL-W2, v.3.5, hydrodynamic and water quality model (Cole and Wells, 20061) is being applied to the reservoir. The models zooplankton algorithms are expanded and a fish bioenergetics model is incorporated. The Lake Roosevelt model extent is shown in Figure 1. The model includes the lacustrine arms up to full pool on the Sanpoil, Kettle, and Colville Rivers; the Spokane River arm up to Little Falls Dam; and the Columbia River from Grand Coulee Dam to the U.S.-Canadian border. The previous companion report, “Boundary Conditions and Set-up” (McKillip, Annear, and Wells, 2006), covered • A limnological overview • Hydrodynamic boundary condition data and model inputs • Grand Coulee Dam structures (powerhouse and spillway characteristics) • Water temperature boundary condition data and model inputs • Meteorological data and model inputs • Water quality boundary condition data • Model bathymetry data and model grid development • Topographic shading • Primary and secondary production data • Kokanee hatchery release data This report discusses the model calibration and issues related to the calibration. This report discusses the topics of: 1) Hydrodynamic calibration: Hydrodynamic calibration focuses on matching the water surface elevation at Grand Coulee Dam. 2) Temperature calibration: Temperature calibration focuses on matching temperature profiles throughout the reservoir and continuous data below Grand Coulee Dam. Many of the calibration issues centered on properly characterizing the localized wind and powerhouse withdrawals. 3) Abiotic water quality calibration: Abiotic water quality calibration focused on matching water quality profile data in the reservoir. The selection of proper rate kinetics and understanding the impact of hydrodynamics on water quality state variables was critical to proper calibration. 4) Bioenergetic (algae, zooplankton, kokanee) modeling approach and calibration 5) Sensitivity analyses Close

• 62. [Article] Water Flow through Temperate Glaciers

  Understanding water movement through a glacier is fundamental to several critical issues in glaciology, including glacier dynamics, glacier-induced floods, and the prediction of runoff from glacierized ...

  Citation × Citation Citation Abstract Copy Title: Water Flow through Temperate Glaciers Author: Fountain, Andrew G., Walder, Joseph S. Year: 1998 Understanding water movement through a glacier is fundamental to several critical issues in glaciology, including glacier dynamics, glacier-induced floods, and the prediction of runoff from glacierized drainage basins. To this end we have synthesized a conceptual model of water movement through a temperate glacier from the surface to the outlet stream. Processes that regulate the rate and distribution of water input at the glacier surface and that regulate water movement from the surface to the bed play important but commonly neglected roles in glacier hydrology. Where a glacier is covered by a layer of porous, permeable firn (the accumulation zone), the flux of water to the glacier interior varies slowly because the firn temporarily stores water and thereby smooths out variations in the supply rate. In the firn-free ablation zone, in contrast, the flux of water into the glacier depends directly on the rate of surface melt or rainfall and therefore varies greatly in time. Water moves from the surface to the bed through an upward branching arborescent network consisting of both steeply inclined conduits, formed by the enlargement of intergranular veins, and gently inclined conduits, spawned by water flow along the bottoms of near-surface fractures (crevasses). Englacial drainage conduits deliver water to the glacier bed at a limited number of points, probably a long distance downglacier of where water enters the glacier. Englacial conduits supplied from the accumulation zone are quasi steady state features that convey the slowly varying water flux delivered via the firn. Their size adjusts so that they are usually full of water and flow is pressurized. In contrast, water flow in englacial conduits supplied from the ablation area is pressurized only near times of peak daily flow or during rainstorms; flow is otherwise in an open-channel configuration. The subglacial drainage system typically consists of several elements that are distinct both morphologically and hydrologically. An upglacier branching, arborescent network of channels incised into the basal ice conveys water rapidly. Much of the water flux to the bed probably enters directly into the arborescent channel network, which covers only a small fraction of the glacier bed. More extensive spatially is a nonarborescent network, which commonly includes cavities (gaps between the glacier sole and bed), channels incised into the bed, and a layer of permeable sediment. The nonarborescent network conveys water slowly and is usually poorly connected to the arborescent system. The arborescent channel network largely collapses during winter but reforms in the spring as the first flush of meltwater to the bed destabilizes the cavities within the nonarborescent network. The volume of water stored by a glacier varies diurnally and seasonally. Small, temperate alpine glaciers seem to attain a maximum seasonal water storage of approximately 200 mm of water averaged over the area of the glacier bed, with daily fluctuations of as much as 20-30 mm. The likely storage capacity of subglacial cavities is insufficient to account for estimated stored water volumes, so most water storage may actually occur englacially. Stored water may also be released abruptly and catastrophically in the form of outburst floods. Title: Water Flow through Temperate Glaciers Author: Fountain, Andrew G., Walder, Joseph S. Year: 1998 Understanding water movement through a glacier is fundamental to several critical issues in glaciology, including glacier dynamics, glacier-induced floods, and the prediction of runoff from glacierized drainage basins. To this end we have synthesized a conceptual model of water movement through a temperate glacier from the surface to the outlet stream. Processes that regulate the rate and distribution of water input at the glacier surface and that regulate water movement from the surface to the bed play important but commonly neglected roles in glacier hydrology. Where a glacier is covered by a layer of porous, permeable firn (the accumulation zone), the flux of water to the glacier interior varies slowly because the firn temporarily stores water and thereby smooths out variations in the supply rate. In the firn-free ablation zone, in contrast, the flux of water into the glacier depends directly on the rate of surface melt or rainfall and therefore varies greatly in time. Water moves from the surface to the bed through an upward branching arborescent network consisting of both steeply inclined conduits, formed by the enlargement of intergranular veins, and gently inclined conduits, spawned by water flow along the bottoms of near-surface fractures (crevasses). Englacial drainage conduits deliver water to the glacier bed at a limited number of points, probably a long distance downglacier of where water enters the glacier. Englacial conduits supplied from the accumulation zone are quasi steady state features that convey the slowly varying water flux delivered via the firn. Their size adjusts so that they are usually full of water and flow is pressurized. In contrast, water flow in englacial conduits supplied from the ablation area is pressurized only near times of peak daily flow or during rainstorms; flow is otherwise in an open-channel configuration. The subglacial drainage system typically consists of several elements that are distinct both morphologically and hydrologically. An upglacier branching, arborescent network of channels incised into the basal ice conveys water rapidly. Much of the water flux to the bed probably enters directly into the arborescent channel network, which covers only a small fraction of the glacier bed. More extensive spatially is a nonarborescent network, which commonly includes cavities (gaps between the glacier sole and bed), channels incised into the bed, and a layer of permeable sediment. The nonarborescent network conveys water slowly and is usually poorly connected to the arborescent system. The arborescent channel network largely collapses during winter but reforms in the spring as the first flush of meltwater to the bed destabilizes the cavities within the nonarborescent network. The volume of water stored by a glacier varies diurnally and seasonally. Small, temperate alpine glaciers seem to attain a maximum seasonal water storage of approximately 200 mm of water averaged over the area of the glacier bed, with daily fluctuations of as much as 20-30 mm. The likely storage capacity of subglacial cavities is insufficient to account for estimated stored water volumes, so most water storage may actually occur englacially. Stored water may also be released abruptly and catastrophically in the form of outburst floods. Close

• 63. [Article] Hydrogeochemical Characterization of the Alvord Valley Known Geothermal Resources Area, Harney County, Oregon

  The Alvord Valley Known Geothermal Resources Area (KGRA) , located east of the Steens Mountain-Pueblo Mountains fault block in southeastern Oregon, is within the northern Basin and Range province. This ...

  Citation × Citation Citation Abstract Copy Title: Hydrogeochemical Characterization of the Alvord Valley Known Geothermal Resources Area, Harney County, Oregon Author: St. John, Anna Maria Year: 1993 The Alvord Valley Known Geothermal Resources Area (KGRA) , located east of the Steens Mountain-Pueblo Mountains fault block in southeastern Oregon, is within the northern Basin and Range province. This investigation focuses on three thermal areas in the Alvord Basin: Borax Lake and the hot springs north of Borax Lake, Alvord Hot Springs and Mickey Springs. Mickey Springs and the springs north of Borax Lake are boiling at the surface (94 and 95° C, respectively). Inflow temperatures to Borax Lake, measured at a depth of 30 m, are greater than 100° C. Surface temperatures for Alvord Hot Springs and a flowing well northeast of Borax Lake are 78 and 59° C, respectively. Thermal fluids issue from Quaternary lacustrine and alluvial deposits. While silica sinter deposits are present at all three thermal areas, sinter is not presently being deposited. Minor calcite is being deposited at the springs north of Borax Lake. The springs discharge from N to NEstriking, high-angle, basin-bounding faults along the base of Steens Mountain and Mickey Mountain and NE-striking intrabasinal faults south of Alvord Lake. The thermal waters are dilute sodium-bicarbonate waters with significant amounts of sulfate and chloride. Conservative element plots (B, F, and Li vs. Cl) indicate good correlation between Cl and the other conservative elements. These correlations could result from mixing of thermal water with a dilute cold water or fluid evolution due to increased fluid-rock interaction, evaporation, and steam loss due to boiling. The small variations in chloride concentrations of thermal fluids during the sampling period argues against mixing of thermal fluids with cold water. The geothermal system is a hot-water rather than a vapordominated system. The ỎD content of thermal fluids is similar to the ỎD content of local cold water wells, springs, basinal pore fluids at a depth of 4 to 5 m, and perennial streams. Similarities in ỎD values indicate recharge for geothermal fluids is precipitation from the Steens Mountain fault block. The Ỏ18 content of thermal fluids is shifted 2 to 3°/oo to the right of the world meteoric water line indicating fluid-rock interaction at elevated temperatures in the reservoir. Tritium contents indicate relatively long residence times and/or low-velocity circulation of meteoric water through basement rocks. Values range from 0 to 0.25 T.U. The application of two end-member models, which calculate fluid residence times, generate a minimum of 57 years and a maximum of greater than 10,000 years. Estimated reservoir temperatures based on cation and silica geothermometry are between 170 and 200°C. Oxygensulfate isotope geothermometer estimates indicate reservoir temperatures between 198 and 207' C for Borax Lake and Alvord Hot Springs. Mickey Springs and a flowing well northeast of Borax Lake yield temperature estimates of 168 and 150° C, respectively. These values indicate partial reequilibration of the isotopic system. The Ỏ13C contents of carbon dioxide and methane of gas discharges from the thermal areas are similar to geothermal fluids from other sites. The Ỏ13C of methane indicate "normal" geothermal methane for Alvord Hot Springs and Mickey Springs (-27.8 and -27.6, respectively). The Ỏ13C of CH4 for springs north of Borax Lake (-33.6) indicates a small amount of thermogenic methane may be contributed by thermal alteration of organics in basinal sediments. The Ỏ13C contents for C02 at Alvord Hot Springs and Borax Lake are within the range expected for atmospheric, fumarolic, or mantle derived C02 (-6.5 and -6.6, respectively). The Ỏ13C content of C02 from Mickey Springs is isotopically lighter than gas released from fumaroles or the mantle (-9.4). N2/Ar ratios for Mickey Springs and Borax Lake gases (39.2 and 40.8, respectively) indicate interaction with airsaturated ground water during flow through the the zone of aeration. Helium is enriched relative to Ar and N2 in gas discharges from Alvord Hot Springs, indicating longer fluid residence times and/or increased crustal interaction at high temperatures. Ratios of B/Cl indicate the fluid reservoir is hosted in volcanic rocks. The Li/Cs ratios for the Borax Lake thermal area are consistent with a reservoir located in rhyoli tic rocks. The 228Ra/226Ra content of Borax Lake thermal fluids (1.14 ± 0.13 dpm/kg) indicates interaction with volcanic rocks for Borax Lake. The 228Ra/226Ra content of thermal fluids from Alvord Hot Springs and Mickey Springs (0.38~0.02 and 0.17 ~ 0.09) are lower than those expected for volcanic rocks and may indicate local uranium accumulation in the reservoir or zones of upflow. The 87Sr / 86Sr values for thermal waters and stratigraphic uni ts indicate the fluid reservoir is located in volcanic rocks beneath Steens Basalt. Equilibration of fluids in these units argues for thermal water circulation depths of 2 to 2.5 km in the Borax Lake thermal area, greater than 3 km in the Alvord Hot Springs area and 1 to 2 km in the Mickey Springs area. Data presented in this study do not preclude a single large deep reservoir system discharging at these three thermal areas in the Alvord basin. Differences in the chemical and isotopic composition of discharge from the three thermal areas are produced during upf low from the reservoir. During upflow, thermal waters follow a complex pathway of vertical and lateral fractures which includes short residence times in shallow reservoirs before reaching the surface. Boiling, mixing with condensate, oxidation, mixing with 1-3% tritium-bearing, near-surface cold water, relative differences in flow rate and volume, and slow cooling without vigorous boiling are processes that modify fluid composition during upflow from the deep geothermal reservoir. Title: Hydrogeochemical Characterization of the Alvord Valley Known Geothermal Resources Area, Harney County, Oregon Author: St. John, Anna Maria Year: 1993 The Alvord Valley Known Geothermal Resources Area (KGRA) , located east of the Steens Mountain-Pueblo Mountains fault block in southeastern Oregon, is within the northern Basin and Range province. This investigation focuses on three thermal areas in the Alvord Basin: Borax Lake and the hot springs north of Borax Lake, Alvord Hot Springs and Mickey Springs. Mickey Springs and the springs north of Borax Lake are boiling at the surface (94 and 95° C, respectively). Inflow temperatures to Borax Lake, measured at a depth of 30 m, are greater than 100° C. Surface temperatures for Alvord Hot Springs and a flowing well northeast of Borax Lake are 78 and 59° C, respectively. Thermal fluids issue from Quaternary lacustrine and alluvial deposits. While silica sinter deposits are present at all three thermal areas, sinter is not presently being deposited. Minor calcite is being deposited at the springs north of Borax Lake. The springs discharge from N to NEstriking, high-angle, basin-bounding faults along the base of Steens Mountain and Mickey Mountain and NE-striking intrabasinal faults south of Alvord Lake. The thermal waters are dilute sodium-bicarbonate waters with significant amounts of sulfate and chloride. Conservative element plots (B, F, and Li vs. Cl) indicate good correlation between Cl and the other conservative elements. These correlations could result from mixing of thermal water with a dilute cold water or fluid evolution due to increased fluid-rock interaction, evaporation, and steam loss due to boiling. The small variations in chloride concentrations of thermal fluids during the sampling period argues against mixing of thermal fluids with cold water. The geothermal system is a hot-water rather than a vapordominated system. The ỎD content of thermal fluids is similar to the ỎD content of local cold water wells, springs, basinal pore fluids at a depth of 4 to 5 m, and perennial streams. Similarities in ỎD values indicate recharge for geothermal fluids is precipitation from the Steens Mountain fault block. The Ỏ18 content of thermal fluids is shifted 2 to 3°/oo to the right of the world meteoric water line indicating fluid-rock interaction at elevated temperatures in the reservoir. Tritium contents indicate relatively long residence times and/or low-velocity circulation of meteoric water through basement rocks. Values range from 0 to 0.25 T.U. The application of two end-member models, which calculate fluid residence times, generate a minimum of 57 years and a maximum of greater than 10,000 years. Estimated reservoir temperatures based on cation and silica geothermometry are between 170 and 200°C. Oxygensulfate isotope geothermometer estimates indicate reservoir temperatures between 198 and 207' C for Borax Lake and Alvord Hot Springs. Mickey Springs and a flowing well northeast of Borax Lake yield temperature estimates of 168 and 150° C, respectively. These values indicate partial reequilibration of the isotopic system. The Ỏ13C contents of carbon dioxide and methane of gas discharges from the thermal areas are similar to geothermal fluids from other sites. The Ỏ13C of methane indicate "normal" geothermal methane for Alvord Hot Springs and Mickey Springs (-27.8 and -27.6, respectively). The Ỏ13C of CH4 for springs north of Borax Lake (-33.6) indicates a small amount of thermogenic methane may be contributed by thermal alteration of organics in basinal sediments. The Ỏ13C contents for C02 at Alvord Hot Springs and Borax Lake are within the range expected for atmospheric, fumarolic, or mantle derived C02 (-6.5 and -6.6, respectively). The Ỏ13C content of C02 from Mickey Springs is isotopically lighter than gas released from fumaroles or the mantle (-9.4). N2/Ar ratios for Mickey Springs and Borax Lake gases (39.2 and 40.8, respectively) indicate interaction with airsaturated ground water during flow through the the zone of aeration. Helium is enriched relative to Ar and N2 in gas discharges from Alvord Hot Springs, indicating longer fluid residence times and/or increased crustal interaction at high temperatures. Ratios of B/Cl indicate the fluid reservoir is hosted in volcanic rocks. The Li/Cs ratios for the Borax Lake thermal area are consistent with a reservoir located in rhyoli tic rocks. The 228Ra/226Ra content of Borax Lake thermal fluids (1.14 ± 0.13 dpm/kg) indicates interaction with volcanic rocks for Borax Lake. The 228Ra/226Ra content of thermal fluids from Alvord Hot Springs and Mickey Springs (0.38~0.02 and 0.17 ~ 0.09) are lower than those expected for volcanic rocks and may indicate local uranium accumulation in the reservoir or zones of upflow. The 87Sr / 86Sr values for thermal waters and stratigraphic uni ts indicate the fluid reservoir is located in volcanic rocks beneath Steens Basalt. Equilibration of fluids in these units argues for thermal water circulation depths of 2 to 2.5 km in the Borax Lake thermal area, greater than 3 km in the Alvord Hot Springs area and 1 to 2 km in the Mickey Springs area. Data presented in this study do not preclude a single large deep reservoir system discharging at these three thermal areas in the Alvord basin. Differences in the chemical and isotopic composition of discharge from the three thermal areas are produced during upf low from the reservoir. During upflow, thermal waters follow a complex pathway of vertical and lateral fractures which includes short residence times in shallow reservoirs before reaching the surface. Boiling, mixing with condensate, oxidation, mixing with 1-3% tritium-bearing, near-surface cold water, relative differences in flow rate and volume, and slow cooling without vigorous boiling are processes that modify fluid composition during upflow from the deep geothermal reservoir. Close

• 64. [Article] Investigations of the Air-Water Interface: A Structural Analysis of Metallic Surface Films and Aquatic Surface Films by Comparative Microscopy

  The air-water interface is an important natural boundary layer that has been neglected as an area of environmental field research. This study establishes that comparative microscopy can be an effective ...

  Citation × Citation Citation Abstract Copy Title: Investigations of the Air-Water Interface: A Structural Analysis of Metallic Surface Films and Aquatic Surface Films by Comparative Microscopy Author: Smith, Randall William Year: 2015 The air-water interface is an important natural boundary layer that has been neglected as an area of environmental field research. This study establishes that comparative microscopy can be an effective environmental method, and establishes that the term metallic surface films, is a more accurate descriptor than iron oxide surface films. This research shows that surface films are complex, often with layered structure, serve as habitat for significant biota, and act as a point of mineralization to several transition metal elements including manganese, iron, copper, nickel and zinc. This study demonstrates that surface films form under several conditions and can have diverse morphology. Activity of biota, microbes, particularly diatoms, suggests that bacteria and cyanobacteria integrate into the film often in patches, represented by forms and casts. Analytical imaging is used to document and compare film morphology and structures, using scanning electron microscopy, photoemission electron microscopy and transmission electron microscopy with elemental analysis by energy dispersive spectroscopy to confirm the hypothesis. Instrument parameters and strengths are reviewed. Component layers of a copper/zinc film were used to confirm metallic layers and elemental distribution. Bacterial casts were used to confirm film interaction, and to show entrainment and enrichment of the film to incorporate autochthonous and allochthonous materials into the films themselves. Most samples were from Oregon selected sites, with some samples from Maryland and Barbados. Title: Investigations of the Air-Water Interface: A Structural Analysis of Metallic Surface Films and Aquatic Surface Films by Comparative Microscopy Author: Smith, Randall William Year: 2015 The air-water interface is an important natural boundary layer that has been neglected as an area of environmental field research. This study establishes that comparative microscopy can be an effective environmental method, and establishes that the term metallic surface films, is a more accurate descriptor than iron oxide surface films. This research shows that surface films are complex, often with layered structure, serve as habitat for significant biota, and act as a point of mineralization to several transition metal elements including manganese, iron, copper, nickel and zinc. This study demonstrates that surface films form under several conditions and can have diverse morphology. Activity of biota, microbes, particularly diatoms, suggests that bacteria and cyanobacteria integrate into the film often in patches, represented by forms and casts. Analytical imaging is used to document and compare film morphology and structures, using scanning electron microscopy, photoemission electron microscopy and transmission electron microscopy with elemental analysis by energy dispersive spectroscopy to confirm the hypothesis. Instrument parameters and strengths are reviewed. Component layers of a copper/zinc film were used to confirm metallic layers and elemental distribution. Bacterial casts were used to confirm film interaction, and to show entrainment and enrichment of the film to incorporate autochthonous and allochthonous materials into the films themselves. Most samples were from Oregon selected sites, with some samples from Maryland and Barbados. Close

• 65. [Article] Isolating the Photocatalytic Degradations of Methylene Blue Dye on TiO2 Surface

  Photocatalytic degradation of organic molecules has a broad applicability and has been studied with particular intensity for the purpose of water and air purification [1]. In this process, light is absorbed ...

  Citation × Citation Citation Abstract Copy Title: Isolating the Photocatalytic Degradations of Methylene Blue Dye on TiO2 Surface Author: Fowler, Simon, Molina, Emilio, Rodriguez-Ariza, Esteban, Quinton-Cox, Sydney, Jiao, Jun Year: 2015 Photocatalytic degradation of organic molecules has a broad applicability and has been studied with particular intensity for the purpose of water and air purification [1]. In this process, light is absorbed by a semiconducting material and converted to electron-hole pairs, which in turn react with water molecules to form hydroxyl radicals (•OH). These highly oxidative molecules go on to degrade organic molecules through what is known as an Advanced Oxidation Process (AOP) [2]. However, the result is usually achieved through diverse pathways, and isolation of the individual mechanisms is difficult. In particular, this experiment is designed to isolate the degradation of an organic marker at the surface of the catalyst material, as opposed to degradation away from the catalyst surface (i.e. within the aqueous medium). This has been achieved by designing an experiment to observe the relative mass of methylene blue (MB) on the catalyst surface during a photodegradation reaction. The TiO2 film was deposited onto glass beads in order to immobilize the catalyst material on a visibly transparent substrate, allowing measurement of dye concentration via visible light spectroscopy. Title: Isolating the Photocatalytic Degradations of Methylene Blue Dye on TiO2 Surface Author: Fowler, Simon, Molina, Emilio, Rodriguez-Ariza, Esteban, Quinton-Cox, Sydney, Jiao, Jun Year: 2015 Photocatalytic degradation of organic molecules has a broad applicability and has been studied with particular intensity for the purpose of water and air purification [1]. In this process, light is absorbed by a semiconducting material and converted to electron-hole pairs, which in turn react with water molecules to form hydroxyl radicals (•OH). These highly oxidative molecules go on to degrade organic molecules through what is known as an Advanced Oxidation Process (AOP) [2]. However, the result is usually achieved through diverse pathways, and isolation of the individual mechanisms is difficult. In particular, this experiment is designed to isolate the degradation of an organic marker at the surface of the catalyst material, as opposed to degradation away from the catalyst surface (i.e. within the aqueous medium). This has been achieved by designing an experiment to observe the relative mass of methylene blue (MB) on the catalyst surface during a photodegradation reaction. The TiO2 film was deposited onto glass beads in order to immobilize the catalyst material on a visibly transparent substrate, allowing measurement of dye concentration via visible light spectroscopy. Close

• 66. [Article] Turbulent Kinetic Energy and Coherent Structures in a Tidal River

  We investigate the relationship between turbulence statistics and coherent structures (CS) in an unstratified reach of the Snohomish River estuary using in situ velocity measurements and surface infrared ...

  Citation × Citation Citation Abstract Copy Title: Turbulent Kinetic Energy and Coherent Structures in a Tidal River Author: Talke, Stefan A., Horner-Devine, Alexander R., Chickadel, C. Chris, Jessup, Andrew T. Year: 2013 We investigate the relationship between turbulence statistics and coherent structures (CS) in an unstratified reach of the Snohomish River estuary using in situ velocity measurements and surface infrared (IR) imaging. Sequential IR images are used to estimate surface flow characteristics via a particle-image-velocimetry (PIV) technique, and are conditionally sampled to delineate the surface statistics of bottom-generated CS, or boils. In the water column, we find that turbulent kinetic energy (TKE) production exceeds dissipation near the bed but is less than dissipation in the midwater column and that TKE flux divergence closes a significant portion of the measured imbalance. The surface boundary leads to divergence in upwelling CS, and leads to the redistribution of vertical TKE to the horizontal. Very near the surface, statistical anisotropy is observed at length scales larger than the depth H (3–5 m), while boil-scale motions of O(1)m are nearly isotropic and exhibit a 25/3 turbulent cascade to smaller scales. Conditional sampling suggests that TKE dissipation in boils is approximately 2 times greater on average than dissipation in ambient flow. Similarly, surface boils are marked by significantly greater velocity variance, upwelling, divergence, and TKE flux divergence than ambient flow regions. Coherent structures and their surface manifestation, therefore, play an important role in the vertical transport of TKE and the water column distribution of dissipation, and are an important component of the TKE budget. Title: Turbulent Kinetic Energy and Coherent Structures in a Tidal River Author: Talke, Stefan A., Horner-Devine, Alexander R., Chickadel, C. Chris, Jessup, Andrew T. Year: 2013 We investigate the relationship between turbulence statistics and coherent structures (CS) in an unstratified reach of the Snohomish River estuary using in situ velocity measurements and surface infrared (IR) imaging. Sequential IR images are used to estimate surface flow characteristics via a particle-image-velocimetry (PIV) technique, and are conditionally sampled to delineate the surface statistics of bottom-generated CS, or boils. In the water column, we find that turbulent kinetic energy (TKE) production exceeds dissipation near the bed but is less than dissipation in the midwater column and that TKE flux divergence closes a significant portion of the measured imbalance. The surface boundary leads to divergence in upwelling CS, and leads to the redistribution of vertical TKE to the horizontal. Very near the surface, statistical anisotropy is observed at length scales larger than the depth H (3–5 m), while boil-scale motions of O(1)m are nearly isotropic and exhibit a 25/3 turbulent cascade to smaller scales. Conditional sampling suggests that TKE dissipation in boils is approximately 2 times greater on average than dissipation in ambient flow. Similarly, surface boils are marked by significantly greater velocity variance, upwelling, divergence, and TKE flux divergence than ambient flow regions. Coherent structures and their surface manifestation, therefore, play an important role in the vertical transport of TKE and the water column distribution of dissipation, and are an important component of the TKE budget. Close

• 67. [Article] Mass Exchange Dynamics of Surface and Subsurface Oil in Shallow-Water Transport

  We formulate a model for the mass exchange between oil at and below the sea surface. This is a particularly important aspect of modeling oil spills. Surface and subsurface oil have different chemical and ...

  Citation × Citation Citation Abstract Copy Title: Mass Exchange Dynamics of Surface and Subsurface Oil in Shallow-Water Transport Author: Moghimi, Saeed, Ramirez, Jorge, Restrepo, Juan M., Venkataramani, Shankar Year: 2017 We formulate a model for the mass exchange between oil at and below the sea surface. This is a particularly important aspect of modeling oil spills. Surface and subsurface oil have different chemical and transport characteristics and lumping them together would compromise the accuracy of the resulting model. Without observational or computational constraints, it is thus not possible to quantitatively predict oil spills based upon partial field observations of surface and/or sub-surface oil. The primary challenge in capturing the mass exchange is that the principal mechanisms are on the microscale. This is a serious barrier to developing practical models for oil spills that are capable of addressing questions regarding the fate of oil at the large spatio-temporal scales, as demanded by environmental questions. We use upscaling to propose an environmental-scale model which incorporates the mass exchange between surface and subsurface oil due to oil droplet dynamics, buoyancy effects, and sea surface and subsurface mechanics. While the mass exchange mechanism detailed here is generally applicable to oil transport models, it addresses the modeling needs of a particular to an oil spill model [1]. This transport model is designed to capture oil spills at very large spatio-temporal scales. It accomplishes this goal by specializing to shallow-water environments, in which depth averaging is a perfectly good approximation for the flow, while at the same time retaining mass conservation of oil over the whole oceanic domain. Title: Mass Exchange Dynamics of Surface and Subsurface Oil in Shallow-Water Transport Author: Moghimi, Saeed, Ramirez, Jorge, Restrepo, Juan M., Venkataramani, Shankar Year: 2017 We formulate a model for the mass exchange between oil at and below the sea surface. This is a particularly important aspect of modeling oil spills. Surface and subsurface oil have different chemical and transport characteristics and lumping them together would compromise the accuracy of the resulting model. Without observational or computational constraints, it is thus not possible to quantitatively predict oil spills based upon partial field observations of surface and/or sub-surface oil. The primary challenge in capturing the mass exchange is that the principal mechanisms are on the microscale. This is a serious barrier to developing practical models for oil spills that are capable of addressing questions regarding the fate of oil at the large spatio-temporal scales, as demanded by environmental questions. We use upscaling to propose an environmental-scale model which incorporates the mass exchange between surface and subsurface oil due to oil droplet dynamics, buoyancy effects, and sea surface and subsurface mechanics. While the mass exchange mechanism detailed here is generally applicable to oil transport models, it addresses the modeling needs of a particular to an oil spill model [1]. This transport model is designed to capture oil spills at very large spatio-temporal scales. It accomplishes this goal by specializing to shallow-water environments, in which depth averaging is a perfectly good approximation for the flow, while at the same time retaining mass conservation of oil over the whole oceanic domain. Close

• 68. [Article] Assessing Hydrologic and Water Quality Sensitivities to Precipitation Changes, Urban Growth and Land Management Using SWAT

  Precipitation changes and urban growth are two factors altering the state of water quality. Changes in precipitation will alter the amount and timing of flows, and the corresponding sediment and nutrient ...

  Citation × Citation Citation Abstract Copy Title: Assessing Hydrologic and Water Quality Sensitivities to Precipitation Changes, Urban Growth and Land Management Using SWAT Author: Psaris, Alexander Michael Year: 2014 Precipitation changes and urban growth are two factors altering the state of water quality. Changes in precipitation will alter the amount and timing of flows, and the corresponding sediment and nutrient dynamics. Meanwhile, densification associated with urban growth will create more impervious surfaces which will alter sediment and nutrient loadings. Land and water managers often rely on models to develop possible future scenarios and devise management responses to these projected changes. We use the Soil and Water Assessment Tool (SWAT) to assess the sensitivities of stream flow, sediment, and nutrient loads in two urbanizing watersheds in Northwest Oregon, USA to various climate and urbanization scenarios. We evaluate the spatial patterns climate change and urban growth will have on water, sediment and nutrient yields. We also identify critical source areas (CSAs) and investigate how implementation of vegetative filter strips (VFS) could ameliorate the effects of these changes. Our findings suggest that: 1) Water yield is tightly coupled to precipitation. 2) Large increases in winter and spring precipitation provide enough sub-surface storage to increase summertime water yields despite a moderate decrease in summer precipitation. 3) Expansion of urban areas increases surface runoff and has mixed effects on sediment and nutrients. 4) Implementation of VFS reduces pollutant loads helping overall watershed health. This research demonstrates the usefulness of SWAT in facilitating informed land and water management decisions. Title: Assessing Hydrologic and Water Quality Sensitivities to Precipitation Changes, Urban Growth and Land Management Using SWAT Author: Psaris, Alexander Michael Year: 2014 Precipitation changes and urban growth are two factors altering the state of water quality. Changes in precipitation will alter the amount and timing of flows, and the corresponding sediment and nutrient dynamics. Meanwhile, densification associated with urban growth will create more impervious surfaces which will alter sediment and nutrient loadings. Land and water managers often rely on models to develop possible future scenarios and devise management responses to these projected changes. We use the Soil and Water Assessment Tool (SWAT) to assess the sensitivities of stream flow, sediment, and nutrient loads in two urbanizing watersheds in Northwest Oregon, USA to various climate and urbanization scenarios. We evaluate the spatial patterns climate change and urban growth will have on water, sediment and nutrient yields. We also identify critical source areas (CSAs) and investigate how implementation of vegetative filter strips (VFS) could ameliorate the effects of these changes. Our findings suggest that: 1) Water yield is tightly coupled to precipitation. 2) Large increases in winter and spring precipitation provide enough sub-surface storage to increase summertime water yields despite a moderate decrease in summer precipitation. 3) Expansion of urban areas increases surface runoff and has mixed effects on sediment and nutrients. 4) Implementation of VFS reduces pollutant loads helping overall watershed health. This research demonstrates the usefulness of SWAT in facilitating informed land and water management decisions. Close

• 69. [Article] Solidification and Morphology of Submarine Lavas: A Dependence on Extrusion Rate

  The results of recent laboratory experiments with wax extruded beneath relatively cold water may be extrapolated to predict the surface morphology of submarine lavas as a function of the extrusion rate ...

  Citation × Citation Citation Abstract Copy Title: Solidification and Morphology of Submarine Lavas: A Dependence on Extrusion Rate Author: Griffiths, Ross W., Fink, Jonathan H. Year: 1992 The results of recent laboratory experiments with wax extruded beneath relatively cold water may be extrapolated to predict the surface morphology of submarine lavas as a function of the extrusion rate and melt vIscosity. The experiments with solidifying wax indicated that the surface morphology was controlled by a single parameter, the ratio of the time taken for the surface to solidify, and a time scale for lateral flow. For submarine basalts a solution of the cooling problem (which is dominated by conduction in the lava but convective heat transfer in the water) and estimates of lava viscosities place this parameter within the empirically determined "pillowing" regime over a Wide range of extrusion rates. This result is consistent with the observation that pillow basalts are the most common products of submarine eruptions. Smoother surfaces corresponding to the various types .of submarine sheet flows are predicted for sufficiently rapid extrusions of basaltic magma. Still higher eruption rates ID regions of low topographic relief may produce submarine lava lakes. Minimum emplacement times can be calculated for submarine volocanic constructs of a single lava flow type. Title: Solidification and Morphology of Submarine Lavas: A Dependence on Extrusion Rate Author: Griffiths, Ross W., Fink, Jonathan H. Year: 1992 The results of recent laboratory experiments with wax extruded beneath relatively cold water may be extrapolated to predict the surface morphology of submarine lavas as a function of the extrusion rate and melt vIscosity. The experiments with solidifying wax indicated that the surface morphology was controlled by a single parameter, the ratio of the time taken for the surface to solidify, and a time scale for lateral flow. For submarine basalts a solution of the cooling problem (which is dominated by conduction in the lava but convective heat transfer in the water) and estimates of lava viscosities place this parameter within the empirically determined "pillowing" regime over a Wide range of extrusion rates. This result is consistent with the observation that pillow basalts are the most common products of submarine eruptions. Smoother surfaces corresponding to the various types .of submarine sheet flows are predicted for sufficiently rapid extrusions of basaltic magma. Still higher eruption rates ID regions of low topographic relief may produce submarine lava lakes. Minimum emplacement times can be calculated for submarine volocanic constructs of a single lava flow type. Close

• 70. [Article] The Morphology of Lava Flows in Planetary Environments: Predictions From Analog Experiments

  The rates of surface cooling and lateral spreading are evaluated for lava flows on the surface of Earth, Venus, Mars, the Moon, and 10. Differences between the flow morphologies expected in these environments ...

  Citation × Citation Citation Abstract Copy Title: The Morphology of Lava Flows in Planetary Environments: Predictions From Analog Experiments Author: Griffiths, Ross W., Fink, Jonathan H. Year: 1992 The rates of surface cooling and lateral spreading are evaluated for lava flows on the surface of Earth, Venus, Mars, the Moon, and 10. Differences between the flow morphologies expected in these environments are then predicted under the assumption that the results of recent laboratory simulations oflavas using wax extruded beneath cold water (Fink and Griffiths, 1990) can be carried over. These experiments involved the spreading of viscous liquid under gravity in the presence of a solidifying surface crust and revealed a set of four distinct surface morphologies. Transitions from one morphology to the next occurred in a well-defined sequence when the relative rates of surface solidification and lateral spreading were varied. In comparison with subaerial flows on Earth, the surface of lavas solidifies faster on Venus, where the dense atmosphere provides additional convective heat transfer. Lateral flow oflava is much slower under the smaller gravity of the Moon. Hence, for a given extrusion rate and viscosity, solid crust is predicted to form closer to the vent on both the Moon and Venus than on Earth. Equivalently, faster extrusion rates than those on Earth are required on the Moon, 10, and Venus in order to produce a given surface morphology. A comparison of observed structure, flow rates, and estimated viscosities for some well-documented terrestrial lava flows shows reasonable agreement with the predictions of the model. Extrapolation to extraterrestrial lavas is then illustrated by constraining the effusion rate for a Martian lava flow whose composition is assumed. Spectral information on the chemical composition of Martian flows to be sought by the thermal emission spectrometer on the Mars Observer mission, in conjunction with detailed morphologic observations from the Mars Observer camera, could allow much more accurate estimates of effusion rates for Martian lavas. Title: The Morphology of Lava Flows in Planetary Environments: Predictions From Analog Experiments Author: Griffiths, Ross W., Fink, Jonathan H. Year: 1992 The rates of surface cooling and lateral spreading are evaluated for lava flows on the surface of Earth, Venus, Mars, the Moon, and 10. Differences between the flow morphologies expected in these environments are then predicted under the assumption that the results of recent laboratory simulations oflavas using wax extruded beneath cold water (Fink and Griffiths, 1990) can be carried over. These experiments involved the spreading of viscous liquid under gravity in the presence of a solidifying surface crust and revealed a set of four distinct surface morphologies. Transitions from one morphology to the next occurred in a well-defined sequence when the relative rates of surface solidification and lateral spreading were varied. In comparison with subaerial flows on Earth, the surface of lavas solidifies faster on Venus, where the dense atmosphere provides additional convective heat transfer. Lateral flow oflava is much slower under the smaller gravity of the Moon. Hence, for a given extrusion rate and viscosity, solid crust is predicted to form closer to the vent on both the Moon and Venus than on Earth. Equivalently, faster extrusion rates than those on Earth are required on the Moon, 10, and Venus in order to produce a given surface morphology. A comparison of observed structure, flow rates, and estimated viscosities for some well-documented terrestrial lava flows shows reasonable agreement with the predictions of the model. Extrapolation to extraterrestrial lavas is then illustrated by constraining the effusion rate for a Martian lava flow whose composition is assumed. Spectral information on the chemical composition of Martian flows to be sought by the thermal emission spectrometer on the Mars Observer mission, in conjunction with detailed morphologic observations from the Mars Observer camera, could allow much more accurate estimates of effusion rates for Martian lavas. Close

• 71. [Article] Cohstrex: Coherent Structures in Rivers and Estuaries Experiment

  COHSTREX, the Coherent Structures in Rivers and Estuaries Experiment, was a five-year project to exploit the remotely sensed signatures of coherent flow structures in rivers and estuaries. The purpose ...

  Citation × Citation Citation Abstract Copy Title: Cohstrex: Coherent Structures in Rivers and Estuaries Experiment Author: Jessup, Andrew, Chickadel, C., Talke, Stefan, Horner-Devine, Alexander Year: 2013 COHSTREX, the Coherent Structures in Rivers and Estuaries Experiment, was a five-year project to exploit the remotely sensed signatures of coherent flow structures in rivers and estuaries. The purpose of the study was to use remote-sensing measurements of coherent structures at a river surface to characterize and quantify the flow. Two major field experiments were undertaken on the Snohomish River near Everett, WA, United States. The first experiment took place near the mouth of the river where stratification was strong due to a tidally driven salt wedge. Flow over a rocky sill generated a field of boils (bottom-generated fluid upwellings) on the flow surface that propagated downstream and provided insight into mixing layer dynamics. The second experiment took place approximately 15[t#]km upstream from the mouth of the river where the tide still affected the river level and velocity, but stratification was minimal. The focus of the unstratified flow experiment was the study of boils generated by flow over flat beds and beds with a bottom roughness. Herein, we provide an overview of infrared measurements of thermal variability on the surface and in-situ measurements of turbulent velocities beneath the surface. A major finding of COHSTREX is that infrared imagery of the thermal signature of coherent flow structures in estuarine rivers is a powerful tool for visualizing and quantifying the flow. Thermal signatures include mixing of water masses with different temperatures, and disruptions of the flow surface by coherent flow structures generated by bottom roughness. Through use of particle image velocimetry (PIV) techniques applied to infrared imagery of the river surface, we are able to estimate mean and turbulent properties of the flow. Title: Cohstrex: Coherent Structures in Rivers and Estuaries Experiment Author: Jessup, Andrew, Chickadel, C., Talke, Stefan, Horner-Devine, Alexander Year: 2013 COHSTREX, the Coherent Structures in Rivers and Estuaries Experiment, was a five-year project to exploit the remotely sensed signatures of coherent flow structures in rivers and estuaries. The purpose of the study was to use remote-sensing measurements of coherent structures at a river surface to characterize and quantify the flow. Two major field experiments were undertaken on the Snohomish River near Everett, WA, United States. The first experiment took place near the mouth of the river where stratification was strong due to a tidally driven salt wedge. Flow over a rocky sill generated a field of boils (bottom-generated fluid upwellings) on the flow surface that propagated downstream and provided insight into mixing layer dynamics. The second experiment took place approximately 15[t#]km upstream from the mouth of the river where the tide still affected the river level and velocity, but stratification was minimal. The focus of the unstratified flow experiment was the study of boils generated by flow over flat beds and beds with a bottom roughness. Herein, we provide an overview of infrared measurements of thermal variability on the surface and in-situ measurements of turbulent velocities beneath the surface. A major finding of COHSTREX is that infrared imagery of the thermal signature of coherent flow structures in estuarine rivers is a powerful tool for visualizing and quantifying the flow. Thermal signatures include mixing of water masses with different temperatures, and disruptions of the flow surface by coherent flow structures generated by bottom roughness. Through use of particle image velocimetry (PIV) techniques applied to infrared imagery of the river surface, we are able to estimate mean and turbulent properties of the flow. Close

• 72. [Article] Near-Surface Internal Melting: a Substantial Mass Loss on Antarctic Dry Valley Glaciers

  The McMurdo Dry Valleys, southern Victoria Land, East Antarctica, are a polar desert, and melt from glacial ice is the primary source of water to streams, lakes and associated ecosystems. Previous work ...

  Citation × Citation Citation Abstract Copy Title: Near-Surface Internal Melting: a Substantial Mass Loss on Antarctic Dry Valley Glaciers Author: Hoffman, Matthew J., Fountain, Andrew G., Liston, Glen E. Year: 2014 The McMurdo Dry Valleys, southern Victoria Land, East Antarctica, are a polar desert, and melt from glacial ice is the primary source of water to streams, lakes and associated ecosystems. Previous work found that to adequately model glacier ablation and subsurface ice temperatures with a surface energy-balance model required including the transmission of solar radiation into the ice. Here we investigate the contribution of subsurface melt to the mass balance of (and runoff from) Dry Valley glaciers by including a drainage process in the model and applying the model to three glacier sites using 13years of hourly meteorological data. Model results for the smooth glacier surfaces common to many glaciers in the Dry Valleys showed that sublimation was typically the largest component of surface lowering, with rare episodes of surface melting, consistent with anecdotal field observations. Results also showed extensive internal melting 5-15 cm below the ice surface, the drainage of which accounted for 50% of summer ablation. This is consistent with field observations of subsurface streams and formation of a weathering crust. We identify an annual cycle of weathering crust formation in summer and its removal during the 10 months of winter sublimation. Title: Near-Surface Internal Melting: a Substantial Mass Loss on Antarctic Dry Valley Glaciers Author: Hoffman, Matthew J., Fountain, Andrew G., Liston, Glen E. Year: 2014 The McMurdo Dry Valleys, southern Victoria Land, East Antarctica, are a polar desert, and melt from glacial ice is the primary source of water to streams, lakes and associated ecosystems. Previous work found that to adequately model glacier ablation and subsurface ice temperatures with a surface energy-balance model required including the transmission of solar radiation into the ice. Here we investigate the contribution of subsurface melt to the mass balance of (and runoff from) Dry Valley glaciers by including a drainage process in the model and applying the model to three glacier sites using 13years of hourly meteorological data. Model results for the smooth glacier surfaces common to many glaciers in the Dry Valleys showed that sublimation was typically the largest component of surface lowering, with rare episodes of surface melting, consistent with anecdotal field observations. Results also showed extensive internal melting 5-15 cm below the ice surface, the drainage of which accounted for 50% of summer ablation. This is consistent with field observations of subsurface streams and formation of a weathering crust. We identify an annual cycle of weathering crust formation in summer and its removal during the 10 months of winter sublimation. Close

• 73. [Article] Investigations into the Regional and Local Timescale Variations of Subglacial Drainage Networks

  Subglacial water plays an important role in the regulation of an ice sheet's mass balance. It may be the dominant control on the velocities of ice streams and outlet glaciers on scales of months to millennia. ...

  Citation × Citation Citation Abstract Copy Title: Investigations into the Regional and Local Timescale Variations of Subglacial Drainage Networks Author: Hiester, Justin Year: 2013 Subglacial water plays an important role in the regulation of an ice sheet's mass balance. It may be the dominant control on the velocities of ice streams and outlet glaciers on scales of months to millennia. Recent satellite observations of ice surface elevation changes have given researchers new insights into how subglacial water is stored and transported. Localized uplift and settling of the ice surface implies that lakes exist beneath the ice sheet that are being filled and drained on relatively short time scales. %At the base of an ice sheet water can be transported through a variety of drainage networks or stored in subglacial lakes. Here, a numerical investigation of the mechanisms of transport and storage of subglacial water and the associated time scales is presented. Experiments are carried out using a finite element model of coupled ice and water flow. The first experiment seeks to understand the relationship between the depth of a basal depression and the area over which the feature affects basal water flow. It is found that as the perturbation to a topographic depression's depth is increased, water is rerouted in response to the perturbation. Additionally it is found that the relationship between perturbation depth and the extent upstream to which its effects reach is nonlinear. The second experiment examines how the aspect ratio of bed features (prolate, oblate, or equidimensional) influences basal water flow. It is found that the systems that develop and their interactions are mediated by both the topography and the feedbacks taken into account by the coupling of the systems in the model. Features oriented parallel to ice and water flow are associated with distributed fan systems that develop branches which migrate laterally across the domain and interact with one another on monthly and yearly timescales. Laterally oriented features develop laterally extensive ponds. As the ratio of longitudinal to lateral dimension of the topography is increased, a combination of these two water distributions is seen. Title: Investigations into the Regional and Local Timescale Variations of Subglacial Drainage Networks Author: Hiester, Justin Year: 2013 Subglacial water plays an important role in the regulation of an ice sheet's mass balance. It may be the dominant control on the velocities of ice streams and outlet glaciers on scales of months to millennia. Recent satellite observations of ice surface elevation changes have given researchers new insights into how subglacial water is stored and transported. Localized uplift and settling of the ice surface implies that lakes exist beneath the ice sheet that are being filled and drained on relatively short time scales. %At the base of an ice sheet water can be transported through a variety of drainage networks or stored in subglacial lakes. Here, a numerical investigation of the mechanisms of transport and storage of subglacial water and the associated time scales is presented. Experiments are carried out using a finite element model of coupled ice and water flow. The first experiment seeks to understand the relationship between the depth of a basal depression and the area over which the feature affects basal water flow. It is found that as the perturbation to a topographic depression's depth is increased, water is rerouted in response to the perturbation. Additionally it is found that the relationship between perturbation depth and the extent upstream to which its effects reach is nonlinear. The second experiment examines how the aspect ratio of bed features (prolate, oblate, or equidimensional) influences basal water flow. It is found that the systems that develop and their interactions are mediated by both the topography and the feedbacks taken into account by the coupling of the systems in the model. Features oriented parallel to ice and water flow are associated with distributed fan systems that develop branches which migrate laterally across the domain and interact with one another on monthly and yearly timescales. Laterally oriented features develop laterally extensive ponds. As the ratio of longitudinal to lateral dimension of the topography is increased, a combination of these two water distributions is seen. Close

• 74. [Article] Hydrologic Remote Sensing and Land Surface Data Assimilation

  Accurate, reliable and skillful forecasting of key environmental variables such as soil moisture and snow are of paramount importance due to their strong influence on many water resources applications ...

  Citation × Citation Citation Abstract Copy Title: Hydrologic Remote Sensing and Land Surface Data Assimilation Author: Moradkhani, Hamid Year: 2008 Accurate, reliable and skillful forecasting of key environmental variables such as soil moisture and snow are of paramount importance due to their strong influence on many water resources applications including flood control, agricultural production and effective water resources management which collectively control the behavior of the climate system. Soil moisture is a key state variable in land surface?atmosphere interactions affecting surface energy fluxes, runoff and the radiation balance. Snow processes also have a large influence on land-atmosphere energy exchanges due to snow high albedo, low thermal conductivity and considerable spatial and temporal variability resulting in the dramatic change on surface and ground temperature. Measurement of these two variables is possible through variety of methods using ground-based and remote sensing procedures. Remote sensing, however, holds great promise for soil moisture and snow measurements which have considerable spatial and temporal variability. Merging these measurements with hydrologic model outputs in a systematic and effective way results in an improvement of land surface model prediction. Data Assimilation provides a mechanism to combine these two sources of estimation. Much success has been attained in recent years in using data from passive microwave sensors and assimilating them into the models. This paper provides an overview of the remote sensing measurement techniques for soil moisture and snow data and describes the advances in data assimilation techniques through the ensemble filtering, mainly Ensemble Kalman filter (EnKF) and Particle filter (PF), for improving the model prediction and reducing the uncertainties involved in prediction process. It is believed that PF provides a complete representation of the probability distribution of state variables of interests (according to sequential Bayes law) and could be a strong alternative to EnKF which is subject to some limitations including the linear updating rule and assumption of jointly normal distribution of errors in state variables and observation. Title: Hydrologic Remote Sensing and Land Surface Data Assimilation Author: Moradkhani, Hamid Year: 2008 Accurate, reliable and skillful forecasting of key environmental variables such as soil moisture and snow are of paramount importance due to their strong influence on many water resources applications including flood control, agricultural production and effective water resources management which collectively control the behavior of the climate system. Soil moisture is a key state variable in land surface?atmosphere interactions affecting surface energy fluxes, runoff and the radiation balance. Snow processes also have a large influence on land-atmosphere energy exchanges due to snow high albedo, low thermal conductivity and considerable spatial and temporal variability resulting in the dramatic change on surface and ground temperature. Measurement of these two variables is possible through variety of methods using ground-based and remote sensing procedures. Remote sensing, however, holds great promise for soil moisture and snow measurements which have considerable spatial and temporal variability. Merging these measurements with hydrologic model outputs in a systematic and effective way results in an improvement of land surface model prediction. Data Assimilation provides a mechanism to combine these two sources of estimation. Much success has been attained in recent years in using data from passive microwave sensors and assimilating them into the models. This paper provides an overview of the remote sensing measurement techniques for soil moisture and snow data and describes the advances in data assimilation techniques through the ensemble filtering, mainly Ensemble Kalman filter (EnKF) and Particle filter (PF), for improving the model prediction and reducing the uncertainties involved in prediction process. It is believed that PF provides a complete representation of the probability distribution of state variables of interests (according to sequential Bayes law) and could be a strong alternative to EnKF which is subject to some limitations including the linear updating rule and assumption of jointly normal distribution of errors in state variables and observation. Close

• 75. [Article] Temporal Variations in Physical and Chemical Features of Cryoconite Holes on Canada Glacier, McMurdo Dry Valleys, Antarctica

  Cryoconite holes in the McMurdo Dry Valleys are ice-lidded, thus isolating the pools of water from the atmosphere and from potential surface melt. Hourly measurements of ice and water temperature and water ...

  Citation × Citation Citation Abstract Copy Title: Temporal Variations in Physical and Chemical Features of Cryoconite Holes on Canada Glacier, McMurdo Dry Valleys, Antarctica Author: Fountain, Andrew G., Nylen, Thomas H., Tranter, Martyn, Bagshaw, Elizabeth A. Year: 2008 Cryoconite holes in the McMurdo Dry Valleys are ice-lidded, thus isolating the pools of water from the atmosphere and from potential surface melt. Hourly measurements of ice and water temperature and water electrical conductivity (EC) were recorded to broadly characterize the physical and chemical changes on daily to seasonal timescales. Overall, subsurface ice/water temperatures were typically several degrees warmer than air temperatures, underscoring the importance of subsurface solar heating. At no time was surface melt observed and the holes melted from within. Detailed differences in the timing and magnitude of both temperature and EC variations during melt-out and freezeup existed between holes despite short separation distances (m). We attribute these differences to small-scale changes in the optical characteristics of the ice and perhaps different efficiencies in hydrologic connections between holes. The holes melt-deepened quickly in the first half of the summer before slowing to a rate equal to the rate of surface ablation that kept hole depth constant for the remainder of the season. The relatively constant EC of the hole waters during midsummer indicates that these holes were connected to a subsurface water system that flushed the holes with fresher meltwater. The early and late season ECs are dominated by freeze-thaw effects that concentrate/dilute the solutes. We speculate that high solute concentrations imply high nutrient concentrations in early summer that may help alleviate potential stresses caused by the production of new biomass after the winter freeze. Title: Temporal Variations in Physical and Chemical Features of Cryoconite Holes on Canada Glacier, McMurdo Dry Valleys, Antarctica Author: Fountain, Andrew G., Nylen, Thomas H., Tranter, Martyn, Bagshaw, Elizabeth A. Year: 2008 Cryoconite holes in the McMurdo Dry Valleys are ice-lidded, thus isolating the pools of water from the atmosphere and from potential surface melt. Hourly measurements of ice and water temperature and water electrical conductivity (EC) were recorded to broadly characterize the physical and chemical changes on daily to seasonal timescales. Overall, subsurface ice/water temperatures were typically several degrees warmer than air temperatures, underscoring the importance of subsurface solar heating. At no time was surface melt observed and the holes melted from within. Detailed differences in the timing and magnitude of both temperature and EC variations during melt-out and freezeup existed between holes despite short separation distances (m). We attribute these differences to small-scale changes in the optical characteristics of the ice and perhaps different efficiencies in hydrologic connections between holes. The holes melt-deepened quickly in the first half of the summer before slowing to a rate equal to the rate of surface ablation that kept hole depth constant for the remainder of the season. The relatively constant EC of the hole waters during midsummer indicates that these holes were connected to a subsurface water system that flushed the holes with fresher meltwater. The early and late season ECs are dominated by freeze-thaw effects that concentrate/dilute the solutes. We speculate that high solute concentrations imply high nutrient concentrations in early summer that may help alleviate potential stresses caused by the production of new biomass after the winter freeze. Close

• 76. [Article] Jet Bounce in Low Gravity

  Liquid jets rebound (‘bounce’) from superhydrophobic surfaces when they impinge at oblique angles. We call this interesting phenomena ‘jet bounce’ and in this work we investigate the phenomena at large ...

  Citation × Citation Citation Abstract Copy Title: Jet Bounce in Low Gravity Author: Turner, Caleb Year: 2017 Liquid jets rebound (‘bounce’) from superhydrophobic surfaces when they impinge at oblique angles. We call this interesting phenomena ‘jet bounce’ and in this work we investigate the phenomena at large length scales in a reduced gravitational environment. For example, for water at Reynolds numbers 0 < Re < 3500 and surface normal Weber numbers 0 < We < 60 we characterize the response of the jets on the hydrophobic surface in the brief 2.1s micro-gravity environment achieved using a drop tower. It is observed that by varying jet velocity, flow rate, jet diameter, and incident angle we observe up to four distinct regimes of behavior. The various regimes may be targeted for specific applications and we demonstrate a variety of unique jet bounce behaviors for applications such as no-touch, no-contact fluid-thermal transport for spacecraft unit operations such as contaminated water processing, device cooling, and cryogenic fluids transport and management. Stable jet bounce from small diameter jet ≈ 1 mm and low impact angle. Characterizing Reynolds number ≈ 900 and normal Weber number ≤ 10 allow jet bounce to rebound in non-destructive behavior. Title: Jet Bounce in Low Gravity Author: Turner, Caleb Year: 2017 Liquid jets rebound (‘bounce’) from superhydrophobic surfaces when they impinge at oblique angles. We call this interesting phenomena ‘jet bounce’ and in this work we investigate the phenomena at large length scales in a reduced gravitational environment. For example, for water at Reynolds numbers 0 < Re < 3500 and surface normal Weber numbers 0 < We < 60 we characterize the response of the jets on the hydrophobic surface in the brief 2.1s micro-gravity environment achieved using a drop tower. It is observed that by varying jet velocity, flow rate, jet diameter, and incident angle we observe up to four distinct regimes of behavior. The various regimes may be targeted for specific applications and we demonstrate a variety of unique jet bounce behaviors for applications such as no-touch, no-contact fluid-thermal transport for spacecraft unit operations such as contaminated water processing, device cooling, and cryogenic fluids transport and management. Stable jet bounce from small diameter jet ≈ 1 mm and low impact angle. Characterizing Reynolds number ≈ 900 and normal Weber number ≤ 10 allow jet bounce to rebound in non-destructive behavior. Close

• 77. [Article] Use of Water Indices Derived from Landsat OLI Imagery and GIS to Estimate the Hydrologic Connectivity of Wetlands in the Tualatin River National Wildlife Refuge

  This study compared two remote sensing water indices: the Normalized Difference Water Index (NDWI) and the Modified NDWI (MNDWI). Both indices were calculated using publically-available data from the Landsat ...

  Citation × Citation Citation Abstract Copy Title: Use of Water Indices Derived from Landsat OLI Imagery and GIS to Estimate the Hydrologic Connectivity of Wetlands in the Tualatin River National Wildlife Refuge Author: Blackmore, Debra Sue Year: 2016 This study compared two remote sensing water indices: the Normalized Difference Water Index (NDWI) and the Modified NDWI (MNDWI). Both indices were calculated using publically-available data from the Landsat 8 Operational Land Imager (OLI). The research goal was to determine whether the indices are effective in locating open water and measuring surface soil moisture. To demonstrate the application of water indices, analysis was conducted for freshwater wetlands in the Tualatin River Basin in northwestern Oregon to estimate hydrologic connectivity and hydrological permanence between these wetlands and nearby water bodies. Remote sensing techniques have been used to study wetlands in recent decades; however, scientific studies have rarely addressed hydrologic connectivity and hydrologic permanence, in spite of the documented importance of these properties. Research steps were designed to be straightforward for easy repeatability: 1) locate sample sites, 2) predict wetness with water indices, 3) estimate wetness with soil samples from the field, 4) validate the index predictions against the soil samples from the field, and 5) in the demonstration step, estimate hydrologic connectivity and hydrological permanence. Results indicate that both indices predicted the presence of large, open water features with clarity; that dry conditions were predicted by MNDWI with more subtle differentiation; and that NDWI results seem more sensitive to sites with vegetation. Use of this low-cost method to discover patterns of surface moisture in the landscape could directly improve the ability to manage wetland environments. Title: Use of Water Indices Derived from Landsat OLI Imagery and GIS to Estimate the Hydrologic Connectivity of Wetlands in the Tualatin River National Wildlife Refuge Author: Blackmore, Debra Sue Year: 2016 This study compared two remote sensing water indices: the Normalized Difference Water Index (NDWI) and the Modified NDWI (MNDWI). Both indices were calculated using publically-available data from the Landsat 8 Operational Land Imager (OLI). The research goal was to determine whether the indices are effective in locating open water and measuring surface soil moisture. To demonstrate the application of water indices, analysis was conducted for freshwater wetlands in the Tualatin River Basin in northwestern Oregon to estimate hydrologic connectivity and hydrological permanence between these wetlands and nearby water bodies. Remote sensing techniques have been used to study wetlands in recent decades; however, scientific studies have rarely addressed hydrologic connectivity and hydrologic permanence, in spite of the documented importance of these properties. Research steps were designed to be straightforward for easy repeatability: 1) locate sample sites, 2) predict wetness with water indices, 3) estimate wetness with soil samples from the field, 4) validate the index predictions against the soil samples from the field, and 5) in the demonstration step, estimate hydrologic connectivity and hydrological permanence. Results indicate that both indices predicted the presence of large, open water features with clarity; that dry conditions were predicted by MNDWI with more subtle differentiation; and that NDWI results seem more sensitive to sites with vegetation. Use of this low-cost method to discover patterns of surface moisture in the landscape could directly improve the ability to manage wetland environments. Close

• 78. [Article] Effects of Evaporative Cooling in the Thermal Performance of Green Roofs

  Green roofs have become an important urban mitigation technology due to their ability to address multiple environmental issues. One of the most common benefits attributed to green roofs is the reduction ...

  Citation × Citation Citation Abstract Copy Title: Effects of Evaporative Cooling in the Thermal Performance of Green Roofs Author: Castillo Garcia, Giorgina Beatriz Year: 2011 Green roofs have become an important urban mitigation technology due to their ability to address multiple environmental issues. One of the most common benefits attributed to green roofs is the reduction in heating and cooling loads in buildings by dissipating heat through evaporation. This study focuses on evaluating the effect that evaporative cooling has on the thermal performance of green roofs. Sponge and floral foam were used as porous media for their ability to retain water inside its body, transport it to the surface, evaporate it at a constant rate and for their different pore sizes. Test trays containing sponge or floral foam saturated with water were tested in a low speed wind tunnel equipped to measure weight, temperature and heat flux. Two types of experiments were conducted: one with evaporation at the surface, and the other with evaporation blocked by an impervious layer. The testing conditions for all tests were kept constant except for the ability of evaporation to happen. Evaporation rate for floral foam was 0.14 kg/m2hr and 0.29 kg/m2hr for sponge. Results of tests with evaporation show a decrease of 45-49% in heat conducted through the roof when compared to the tests without evaporation. For optimal thermal performance of green roofs, a material that enhances water transport and thus evaporation at the surface is necessary with large pores and low field capacity. Surface temperatures on test with evaporation were found to be between 3-7°C lower than those without evaporation. Applying a 2 sample t-test to the data, the relationship between heat flux and evaporation was found to be statistically significant. Title: Effects of Evaporative Cooling in the Thermal Performance of Green Roofs Author: Castillo Garcia, Giorgina Beatriz Year: 2011 Green roofs have become an important urban mitigation technology due to their ability to address multiple environmental issues. One of the most common benefits attributed to green roofs is the reduction in heating and cooling loads in buildings by dissipating heat through evaporation. This study focuses on evaluating the effect that evaporative cooling has on the thermal performance of green roofs. Sponge and floral foam were used as porous media for their ability to retain water inside its body, transport it to the surface, evaporate it at a constant rate and for their different pore sizes. Test trays containing sponge or floral foam saturated with water were tested in a low speed wind tunnel equipped to measure weight, temperature and heat flux. Two types of experiments were conducted: one with evaporation at the surface, and the other with evaporation blocked by an impervious layer. The testing conditions for all tests were kept constant except for the ability of evaporation to happen. Evaporation rate for floral foam was 0.14 kg/m2hr and 0.29 kg/m2hr for sponge. Results of tests with evaporation show a decrease of 45-49% in heat conducted through the roof when compared to the tests without evaporation. For optimal thermal performance of green roofs, a material that enhances water transport and thus evaporation at the surface is necessary with large pores and low field capacity. Surface temperatures on test with evaporation were found to be between 3-7°C lower than those without evaporation. Applying a 2 sample t-test to the data, the relationship between heat flux and evaporation was found to be statistically significant. Close

• 79. [Article] Introduction to Special Section on Microcosms in Ice: The Biogeochemistry of Cryoconite Holes

  Cryoconite holes are small, water filled, cylindrical melt-holes on glacial ice surface. Cryoconite, 'cold dust,' refers to the thin layer of sediment at the hole bottom. The holes form from surficial ...

  Citation × Citation Citation Abstract Copy Title: Introduction to Special Section on Microcosms in Ice: The Biogeochemistry of Cryoconite Holes Author: Fountain, Andrew G., Tranter, Martyn Year: 2008 Cryoconite holes are small, water filled, cylindrical melt-holes on glacial ice surface. Cryoconite, 'cold dust,' refers to the thin layer of sediment at the hole bottom. The holes form from surficial sediment patches that absorbs more solar radiation than the surrounding ice and which preferentially melt into the glacier forming a cylindrical water-filled hole. These holes form on the ice-covered, as opposed to snow covered, parts of glaciers world-wide, wherever there is sufficient energy for melting. Biogeochemically, cryoconite holes are interesting because the sediment is inncoculated with biologic material, a fraction of which thrives in the cryoconite environment of near-freezing waters and limited nutrient supply. The holes are thus oases for microbial life and biologically mediated chemical reactions on otherwise relatively inert glacier surfaces. Examining the chemical evolution of waters in cryoconite holes, showing how biogeochemical processes in cryoconite holes lead to increasing concentrations of dissolved organic carbon over time, which in may enhance adsorption of solar radiation by the water, aiding the development of deeper holes. If this is true, it suggests that there are a number of complex interactions between the biology, chemistry and biology of cryoconite holes, which act in concert to maintain life on glacier surfaces. Title: Introduction to Special Section on Microcosms in Ice: The Biogeochemistry of Cryoconite Holes Author: Fountain, Andrew G., Tranter, Martyn Year: 2008 Cryoconite holes are small, water filled, cylindrical melt-holes on glacial ice surface. Cryoconite, 'cold dust,' refers to the thin layer of sediment at the hole bottom. The holes form from surficial sediment patches that absorbs more solar radiation than the surrounding ice and which preferentially melt into the glacier forming a cylindrical water-filled hole. These holes form on the ice-covered, as opposed to snow covered, parts of glaciers world-wide, wherever there is sufficient energy for melting. Biogeochemically, cryoconite holes are interesting because the sediment is inncoculated with biologic material, a fraction of which thrives in the cryoconite environment of near-freezing waters and limited nutrient supply. The holes are thus oases for microbial life and biologically mediated chemical reactions on otherwise relatively inert glacier surfaces. Examining the chemical evolution of waters in cryoconite holes, showing how biogeochemical processes in cryoconite holes lead to increasing concentrations of dissolved organic carbon over time, which in may enhance adsorption of solar radiation by the water, aiding the development of deeper holes. If this is true, it suggests that there are a number of complex interactions between the biology, chemistry and biology of cryoconite holes, which act in concert to maintain life on glacier surfaces. Close

• 80. [Article] Modeling Liquid Solid Separation in a Coalescing Plate Oil Water Separator

  When precipitation occurs in undeveloped areas a number of abstractions catch and absorb the precipitation. Abstractions include plants and trees, which catch a portion of the water, pervious soils that ...

  Citation × Citation Citation Abstract Copy Title: Modeling Liquid Solid Separation in a Coalescing Plate Oil Water Separator Author: Gorski, Jacob Year: 2013 When precipitation occurs in undeveloped areas a number of abstractions catch and absorb the precipitation. Abstractions include plants and trees, which catch a portion of the water, pervious soils that infiltrate stormwater until saturated and natural changes in topography where stormwater accumulates. During more intense, longer storm evens the abstraction limit in a watershed can be reached and runoff occurs. In the process of developing areas for cities, towns, industrial sites and transportation the watershed characteristics of that area are changed and the quantity of abstraction in the developed area is reduced. Pervious soils are replaced with impervious surfaces and plants that abstract, absorb and release moisture through evapotranspiration are removed. As a result a significantly larger quantity of surface runoff is generated in these areas. There are a number of methods used to manage the quantity of runoff. Two popular options are the combined sewer system and the separate sewer system. The combined sewer system conveys stormwater runoff and sanitary sewage from households to a wastewater treatment plant. After treatment water is released into a receiving body and the quality of the effluent is monitored to comply with water quality regulations in general, or for water quality regulations at a particular receiving body of water. The separate sewer system, also known as the municipal separate storm sewer system (MS4) conveys stormwater separate from sanitary waste. The MS4 generally discharges stormwater to a receiving body of water through a system of outfalls while sanitary sewage is conveyed to a wastewater treatment plant. Because stormwater picks up and transports pollutants deposited in urban areas, and is then discharged to a receiving body, or treated along with sanitary waste it is necessary reduce pollutants and/or reduce quantity of runoff for water quality and economic reasons. Within stormwater management methods that reduce runoff volume and or runoff pollution are called best management practices (BMP). Title: Modeling Liquid Solid Separation in a Coalescing Plate Oil Water Separator Author: Gorski, Jacob Year: 2013 When precipitation occurs in undeveloped areas a number of abstractions catch and absorb the precipitation. Abstractions include plants and trees, which catch a portion of the water, pervious soils that infiltrate stormwater until saturated and natural changes in topography where stormwater accumulates. During more intense, longer storm evens the abstraction limit in a watershed can be reached and runoff occurs. In the process of developing areas for cities, towns, industrial sites and transportation the watershed characteristics of that area are changed and the quantity of abstraction in the developed area is reduced. Pervious soils are replaced with impervious surfaces and plants that abstract, absorb and release moisture through evapotranspiration are removed. As a result a significantly larger quantity of surface runoff is generated in these areas. There are a number of methods used to manage the quantity of runoff. Two popular options are the combined sewer system and the separate sewer system. The combined sewer system conveys stormwater runoff and sanitary sewage from households to a wastewater treatment plant. After treatment water is released into a receiving body and the quality of the effluent is monitored to comply with water quality regulations in general, or for water quality regulations at a particular receiving body of water. The separate sewer system, also known as the municipal separate storm sewer system (MS4) conveys stormwater separate from sanitary waste. The MS4 generally discharges stormwater to a receiving body of water through a system of outfalls while sanitary sewage is conveyed to a wastewater treatment plant. Because stormwater picks up and transports pollutants deposited in urban areas, and is then discharged to a receiving body, or treated along with sanitary waste it is necessary reduce pollutants and/or reduce quantity of runoff for water quality and economic reasons. Within stormwater management methods that reduce runoff volume and or runoff pollution are called best management practices (BMP). Close

• 81. [Article] A Method to Derivatize Surface Silanol Groups to Si-Alkyl Groups in Carbon-Doped Silicon Oxides

  A carbon-doped silicon oxide (CDO) finds use as a material with a low dielectric constant (k) for copper interconnects in multilayered integrated circuits (ICs). Hydrophilic silanol groups (Si–OH) on its ...

  Citation × Citation Citation Abstract Copy Title: A Method to Derivatize Surface Silanol Groups to Si-Alkyl Groups in Carbon-Doped Silicon Oxides Author: Darmakkolla, Srikar Rao, Tran, Hoang, Gupta, Atul, Rananavare, Shankar B. Year: 2016 A carbon-doped silicon oxide (CDO) finds use as a material with a low dielectric constant (k) for copper interconnects in multilayered integrated circuits (ICs). Hydrophilic silanol groups (Si–OH) on its surface, however, can attract moisture, thereby causing an undesirable increase in the dielectric constant. Modification of the exposed hydrophilic surface to a hydrophobic functional group provides one solution to this problem. We report here a strategy for converting surface Si–OH to hydrophobic silicon hydride (Si–H) without affecting the internal oxide network in CDO. The approach involves esterification of the exposed silanol to its triflate (silyltrifluoromethanesulfonate, Si–O–Tf), followed by reduction to Si–H with diisobutylaluminum hydride. Si–H is further modified by a photochemical reaction with an alkene (1-octadecene) to yield Si–R (R = –C18H37) to provide a more moisture resistant, and less polar Si–C as opposed to the Si–O backbone. Fourier transform infrared (FT-IR) spectroscopy, X-ray photoelectron spectrometry (XPS), and measurements of the contact angle with water substantiated the successful conversion. The reaction scheme is versatile, transforming silanol groups to silicon hydride in widely varying chemical sites, from small molecules to the surfaces of silica gels, SiOx and CDO wafers. A comparison with the films (self-assembled monolayers) derivatized with the octadecyltrichlorosilane indicated that the new method leads to a thicker (≈5 nm) but more loosely packed hydrocarbon film with slightly lower contact angles. Title: A Method to Derivatize Surface Silanol Groups to Si-Alkyl Groups in Carbon-Doped Silicon Oxides Author: Darmakkolla, Srikar Rao, Tran, Hoang, Gupta, Atul, Rananavare, Shankar B. Year: 2016 A carbon-doped silicon oxide (CDO) finds use as a material with a low dielectric constant (k) for copper interconnects in multilayered integrated circuits (ICs). Hydrophilic silanol groups (Si–OH) on its surface, however, can attract moisture, thereby causing an undesirable increase in the dielectric constant. Modification of the exposed hydrophilic surface to a hydrophobic functional group provides one solution to this problem. We report here a strategy for converting surface Si–OH to hydrophobic silicon hydride (Si–H) without affecting the internal oxide network in CDO. The approach involves esterification of the exposed silanol to its triflate (silyltrifluoromethanesulfonate, Si–O–Tf), followed by reduction to Si–H with diisobutylaluminum hydride. Si–H is further modified by a photochemical reaction with an alkene (1-octadecene) to yield Si–R (R = –C18H37) to provide a more moisture resistant, and less polar Si–C as opposed to the Si–O backbone. Fourier transform infrared (FT-IR) spectroscopy, X-ray photoelectron spectrometry (XPS), and measurements of the contact angle with water substantiated the successful conversion. The reaction scheme is versatile, transforming silanol groups to silicon hydride in widely varying chemical sites, from small molecules to the surfaces of silica gels, SiOx and CDO wafers. A comparison with the films (self-assembled monolayers) derivatized with the octadecyltrichlorosilane indicated that the new method leads to a thicker (≈5 nm) but more loosely packed hydrocarbon film with slightly lower contact angles. Close

• 82. [Article] Distributed Modeling of Ablation (1996–2011) and Climate Sensitivity on the Glaciers of Taylor Valley, Antarctica

  The McMurdo Dry Valleys of Antarctica host the coldest and driest ecosystem on Earth, which is acutely sensitive to the availability of water coming from glacial runoff. We modeled the spatial variability ...

  Citation × Citation Citation Abstract Copy Title: Distributed Modeling of Ablation (1996–2011) and Climate Sensitivity on the Glaciers of Taylor Valley, Antarctica Author: Hoffman, Matthew J., Fountain, Andrew G., Liston, Glen E. Year: 2016 The McMurdo Dry Valleys of Antarctica host the coldest and driest ecosystem on Earth, which is acutely sensitive to the availability of water coming from glacial runoff. We modeled the spatial variability in ablation and assessed climate sensitivity of the glacier ablation zones using 16 years of meteorological and surface mass-balance observations collected in Taylor Valley. Sublimation was the primary form of mass loss over much of the ablation zones, except for near the termini where melt, primarily below the surface, dominated. Microclimates in ~10 m scale topographic basins generated melt rates up to ten times higher than over smooth glacier surfaces. In contrast, the vertical terminal cliffs on the glaciers can have higher or lower melt rates than the horizontal surfaces due to differences in incoming solar radiation. The model systematically underpredicted ablation for the final 5 years studied, possibly due to an increase of windblown sediment. Surface mass-balance sensitivity to temperature was ~−0.02 m w.e. K−1, which is among the smallest magnitudes observed globally. We also identified a high sensitivity to ice albedo, with a decrease of 0.02 having similar effects as a 1 K increase in temperature, and a complex sensitivity to wind speed. Title: Distributed Modeling of Ablation (1996–2011) and Climate Sensitivity on the Glaciers of Taylor Valley, Antarctica Author: Hoffman, Matthew J., Fountain, Andrew G., Liston, Glen E. Year: 2016 The McMurdo Dry Valleys of Antarctica host the coldest and driest ecosystem on Earth, which is acutely sensitive to the availability of water coming from glacial runoff. We modeled the spatial variability in ablation and assessed climate sensitivity of the glacier ablation zones using 16 years of meteorological and surface mass-balance observations collected in Taylor Valley. Sublimation was the primary form of mass loss over much of the ablation zones, except for near the termini where melt, primarily below the surface, dominated. Microclimates in ~10 m scale topographic basins generated melt rates up to ten times higher than over smooth glacier surfaces. In contrast, the vertical terminal cliffs on the glaciers can have higher or lower melt rates than the horizontal surfaces due to differences in incoming solar radiation. The model systematically underpredicted ablation for the final 5 years studied, possibly due to an increase of windblown sediment. Surface mass-balance sensitivity to temperature was ~−0.02 m w.e. K−1, which is among the smallest magnitudes observed globally. We also identified a high sensitivity to ice albedo, with a decrease of 0.02 having similar effects as a 1 K increase in temperature, and a complex sensitivity to wind speed. Close

• 83. [Article] Discontinuities in Hygroscopic Growth Below and Above Water Saturation for Laboratory Surrogates of Oligomers in Organic Atmospheric Aerosols

  Discontinuities in apparent hygroscopicity below and above water saturation have been observed for organic and mixed organic–inorganic aerosol particles in both laboratory studies and in the ambient atmosphere. ...

  Citation × Citation Citation Abstract Copy Title: Discontinuities in Hygroscopic Growth Below and Above Water Saturation for Laboratory Surrogates of Oligomers in Organic Atmospheric Aerosols Author: Hodas, Natasha, Zuend, Andreas, Schilling, Katherine, Berkemeier, Thomas, Shiraiwa, Manabu, Flagan, Richard C., Seinfeld, John H. Year: 2016 Discontinuities in apparent hygroscopicity below and above water saturation have been observed for organic and mixed organic–inorganic aerosol particles in both laboratory studies and in the ambient atmosphere. However, uncertainty remains regarding the factors that contribute to observations of low hygroscopic growth below water saturation but enhanced cloud condensation nuclei (CCN) activity for a given aerosol population. Utilizing laboratory surrogates for oligomers in atmospheric aerosols, we explore the extent to which such discontinuities are influenced by organic component molecular mass and viscosity, non-ideal thermodynamic interactions between aerosol components, and the combination of these factors. Measurements of hygroscopic growth under subsaturated conditions and the CCN activity of aerosols comprised of polyethylene glycol (PEG) with average molecular masses ranging from 200 to 10 000 g mol−1 and mixtures of PEG with ammonium sulfate (AS) were conducted. Experimental results are compared to calculations of hygroscopic growth at thermodynamic equilibrium conducted with the Aerosol Inorganic Organic Mixtures Functional groups Activity Coefficients (AIOMFAC) model, and the potential influence of kinetic limitations on observed water uptake was further explored through estimations of water diffusivity in the PEG oligomers. Particle-phase behavior, including the prevalence of liquid–liquid phase separation (LLPS), was also modeled with AIOMFAC. Under subsaturated relative humidity (RH) conditions, we observed little variability in hygroscopic growth across PEG systems with different molecular masses; however, an increase in CCN activity with increasing PEG molecular mass was observed. This effect is most pronounced for PEG–AS mixtures, and, in fact, an enhancement in CCN activity was ob-served for the PEG10000–AS mixture as compared to pure AS, as evidenced by a 15 % reduction in critical activation diameter at a supersaturation of 0.8 %. We also observed a marked increase in apparent hygroscopicity for mixtures of higher molecular mass PEG and AS under supersaturated conditions as compared to subsaturated hygroscopic growth. AIOMFAC-based predictions and estimations of water diffusivity in PEG suggest that such discontinuities in apparent hygroscopicity above and below water saturation can be attributed, at least in part, to differences in the sensitivity of water uptake behavior to surface tension effects. There is no evidence that kinetic limitations to water uptake due to the presence of viscous aerosol components influenced hygroscopic growth. For the systems that display an enhancement in apparent hygroscopicity above water saturation, LLPS is predicted to persist to high RH. This indicates a miscibility gap and is likely to influence bulk-to-surface partitioning of PEG at high RH, impacting droplet surface tension and CCN activity. This work provides insight into the factors likely to be contributing to discontinuities in aerosol water-uptake behavior below and above water saturation that have been ob-served previously in the ambient atmosphere. Title: Discontinuities in Hygroscopic Growth Below and Above Water Saturation for Laboratory Surrogates of Oligomers in Organic Atmospheric Aerosols Author: Hodas, Natasha, Zuend, Andreas, Schilling, Katherine, Berkemeier, Thomas, Shiraiwa, Manabu, Flagan, Richard C., Seinfeld, John H. Year: 2016 Discontinuities in apparent hygroscopicity below and above water saturation have been observed for organic and mixed organic–inorganic aerosol particles in both laboratory studies and in the ambient atmosphere. However, uncertainty remains regarding the factors that contribute to observations of low hygroscopic growth below water saturation but enhanced cloud condensation nuclei (CCN) activity for a given aerosol population. Utilizing laboratory surrogates for oligomers in atmospheric aerosols, we explore the extent to which such discontinuities are influenced by organic component molecular mass and viscosity, non-ideal thermodynamic interactions between aerosol components, and the combination of these factors. Measurements of hygroscopic growth under subsaturated conditions and the CCN activity of aerosols comprised of polyethylene glycol (PEG) with average molecular masses ranging from 200 to 10 000 g mol−1 and mixtures of PEG with ammonium sulfate (AS) were conducted. Experimental results are compared to calculations of hygroscopic growth at thermodynamic equilibrium conducted with the Aerosol Inorganic Organic Mixtures Functional groups Activity Coefficients (AIOMFAC) model, and the potential influence of kinetic limitations on observed water uptake was further explored through estimations of water diffusivity in the PEG oligomers. Particle-phase behavior, including the prevalence of liquid–liquid phase separation (LLPS), was also modeled with AIOMFAC. Under subsaturated relative humidity (RH) conditions, we observed little variability in hygroscopic growth across PEG systems with different molecular masses; however, an increase in CCN activity with increasing PEG molecular mass was observed. This effect is most pronounced for PEG–AS mixtures, and, in fact, an enhancement in CCN activity was ob-served for the PEG10000–AS mixture as compared to pure AS, as evidenced by a 15 % reduction in critical activation diameter at a supersaturation of 0.8 %. We also observed a marked increase in apparent hygroscopicity for mixtures of higher molecular mass PEG and AS under supersaturated conditions as compared to subsaturated hygroscopic growth. AIOMFAC-based predictions and estimations of water diffusivity in PEG suggest that such discontinuities in apparent hygroscopicity above and below water saturation can be attributed, at least in part, to differences in the sensitivity of water uptake behavior to surface tension effects. There is no evidence that kinetic limitations to water uptake due to the presence of viscous aerosol components influenced hygroscopic growth. For the systems that display an enhancement in apparent hygroscopicity above water saturation, LLPS is predicted to persist to high RH. This indicates a miscibility gap and is likely to influence bulk-to-surface partitioning of PEG at high RH, impacting droplet surface tension and CCN activity. This work provides insight into the factors likely to be contributing to discontinuities in aerosol water-uptake behavior below and above water saturation that have been ob-served previously in the ambient atmosphere. Close

• 84. [Article] Processes Controlling Carbon Cycling in Antarctic Glacier Surface Ecosystems

  Glacier surface ecosystems, including cryoconite holes and cryolakes, are significant contributors to regional carbon cycles. Incubation experiments to determine the net production (NEP) of organic matter ...

  Citation × Citation Citation Abstract Copy Title: Processes Controlling Carbon Cycling in Antarctic Glacier Surface Ecosystems Author: Bagshaw, Elizabeth A., Tranter, Martyn, Wadham, Jemma L., Fountain, Andrew G., Dubnick, A., Fitzsimons, S. Year: 2016 Glacier surface ecosystems, including cryoconite holes and cryolakes, are significant contributors to regional carbon cycles. Incubation experiments to determine the net production (NEP) of organic matter in cryoconite typically have durations of 6-24 hours, and produce a wide range of results, many of which indicate that the system is net heterotrophic. We employ longer term incubations to examine the temporal variation of NEP in cryoconite from the McMurdo Dry Valleys, Antarctica to examine the effect of sediment disturbance on system production, and to understand processes controlling production over the lifetimes of glacier surface ecosystems. The shorter-term incubations have durations of one week and show net heterotrophy. The longer term incubations of approximately one year show net autotrophy, but only after a period of about 40 days (~1000 hours). The control on net organic carbon production is a combination of the rate of diffusion of dissolved inorganic carbon from heterotrophic activity within cryoconite into the water, the rate of carbonate dissolution, and the saturation of carbonate in the water (which is a result of photosynthesis in a closed system). We demonstrate that sediment on glacier surfaces has the potential to accumulate carbon over timescales of months to years. Title: Processes Controlling Carbon Cycling in Antarctic Glacier Surface Ecosystems Author: Bagshaw, Elizabeth A., Tranter, Martyn, Wadham, Jemma L., Fountain, Andrew G., Dubnick, A., Fitzsimons, S. Year: 2016 Glacier surface ecosystems, including cryoconite holes and cryolakes, are significant contributors to regional carbon cycles. Incubation experiments to determine the net production (NEP) of organic matter in cryoconite typically have durations of 6-24 hours, and produce a wide range of results, many of which indicate that the system is net heterotrophic. We employ longer term incubations to examine the temporal variation of NEP in cryoconite from the McMurdo Dry Valleys, Antarctica to examine the effect of sediment disturbance on system production, and to understand processes controlling production over the lifetimes of glacier surface ecosystems. The shorter-term incubations have durations of one week and show net heterotrophy. The longer term incubations of approximately one year show net autotrophy, but only after a period of about 40 days (~1000 hours). The control on net organic carbon production is a combination of the rate of diffusion of dissolved inorganic carbon from heterotrophic activity within cryoconite into the water, the rate of carbonate dissolution, and the saturation of carbonate in the water (which is a result of photosynthesis in a closed system). We demonstrate that sediment on glacier surfaces has the potential to accumulate carbon over timescales of months to years. Close

• 85. [Article] Determinants of Single Family Residential Water Use Across Scales in Four Western US Cities

  A growing body of literature examines urban water sustainability with increasing evidence that locally-based physical and social spatial interactions contribute to water use. These studies however are ...

  Citation × Citation Citation Abstract Copy Title: Determinants of Single Family Residential Water Use Across Scales in Four Western US Cities Author: Chang, Heejun, Bonnette, Matthew Ryan, Stoker, Philip, Crow-Miller, Britt, Wentz, Elizabeth A, Year: 2017 A growing body of literature examines urban water sustainability with increasing evidence that locally-based physical and social spatial interactions contribute to water use. These studies however are based on single-city analysis and often fail to consider whether these interactions occur more generally. We examine a multi-city comparison using a common set of spatially-explicit water, socioeconomic, and biophysical data. We investigate the relative importance of variables for explaining the variations of single family residential (SFR) water uses at Census Block Group (CBG) and Census Tract (CT) scales in four representative western US cities - Austin, Phoenix, Portland, and Salt Lake City, - which cover a wide range of climate and development density. We used both ordinary least squares regression and spatial error regression models to identify the influence of spatial dependence on water use patterns. Our results show that older downtown areas show lower water use than newer suburban areas in all four cities. Tax assessed value and building age are the main determinants of SFR water use across the four cities regardless of the scale. Impervious surface area becomes an important variable for summer water use in all cities, and it is important in all seasons for arid environments such as Phoenix. CT level analysis shows better model predictability than CBG analysis. In all cities, seasons, and spatial scales, spatial error regression models better explain the variations of SFR water use. Such a spatially-varying relationship of urban water consumption provides additional evidence for the need to integrate urban land use planning and municipal water planning. (C) 2017 Elsevier B.V. All rights reserved. Title: Determinants of Single Family Residential Water Use Across Scales in Four Western US Cities Author: Chang, Heejun, Bonnette, Matthew Ryan, Stoker, Philip, Crow-Miller, Britt, Wentz, Elizabeth A, Year: 2017 A growing body of literature examines urban water sustainability with increasing evidence that locally-based physical and social spatial interactions contribute to water use. These studies however are based on single-city analysis and often fail to consider whether these interactions occur more generally. We examine a multi-city comparison using a common set of spatially-explicit water, socioeconomic, and biophysical data. We investigate the relative importance of variables for explaining the variations of single family residential (SFR) water uses at Census Block Group (CBG) and Census Tract (CT) scales in four representative western US cities - Austin, Phoenix, Portland, and Salt Lake City, - which cover a wide range of climate and development density. We used both ordinary least squares regression and spatial error regression models to identify the influence of spatial dependence on water use patterns. Our results show that older downtown areas show lower water use than newer suburban areas in all four cities. Tax assessed value and building age are the main determinants of SFR water use across the four cities regardless of the scale. Impervious surface area becomes an important variable for summer water use in all cities, and it is important in all seasons for arid environments such as Phoenix. CT level analysis shows better model predictability than CBG analysis. In all cities, seasons, and spatial scales, spatial error regression models better explain the variations of SFR water use. Such a spatially-varying relationship of urban water consumption provides additional evidence for the need to integrate urban land use planning and municipal water planning. (C) 2017 Elsevier B.V. All rights reserved. Close

• 86. [Article] Development of an Atmospheric Pressure Laser Induced Fluorimeter (AP-LIF) for NO₂ and Application of AP-LIF for Study of Heterogeneous NO₂ Chemistry

  Nitrogen dioxide (NO₂) is a pollutant of interest for study both because of its controlling role in the oxidant capacity of the atmosphere and the health risks it poses. Concerns about the health effects ...

  Citation × Citation Citation Abstract Copy Title: Development of an Atmospheric Pressure Laser Induced Fluorimeter (AP-LIF) for NO₂ and Application of AP-LIF for Study of Heterogeneous NO₂ Chemistry Author: Parra, Jeremy Year: 2012 Nitrogen dioxide (NO₂) is a pollutant of interest for study both because of its controlling role in the oxidant capacity of the atmosphere and the health risks it poses. Concerns about the health effects of NO₂ and its role in forming deleterious atmospheric species have made it desirable to have low-cost, sensitive ambient measurements of NO₂. A continuous-wave laser-diode laser-induced fluorescence (LIF) system for NO₂ was developed here which operates at ambient pressure, thereby eliminating the need for an expensive pumping system. The current prototype system has achieved sensitivity several orders of magnitude beyond previous efforts at ambient pressure (limit of detection of 2 ppb, 60 s averaging time). Ambient measurements of NO₂ were made in Portland, Oregon using both the standard NO₂ chemiluminescence method and the LIF instrument and showed good agreement (r² = 0.92). In addition, investigations into surface mediated chemistry involving oxides of nitrogen (namely, NO₂) have stimulated new inquiry into potential heterogeneous sources of NO₂ as well as challenged the stability of permanent sinks for NO₂. The possibility that surface mediated chemistry plays a significant role in NOy chemistry in urban air has for the past few decades received considerable attention. The AP-LIF NO₂ instrument is uniquely suited to measure surface chemistry under near ambient conditions. The so called 'renoxification' reaction of gaseous NO with surface bound HNO₃ yielding NO₂ (2HNO₃(surface) + NO--> 3NO₂ +H₂O(surface)) was suggested as a potentially important source of NO₂ which also degraded the stability of nitric acid as a sink of active oxides of nitrogen. Yet, there is disagreement in the literature as to the importance of this reaction. The disagreement stems from differing measurements of the rate for the renoxification reaction. Because there are differences in experimental setups no one research group has studied the renoxification reaction under ambient conditions, i.e., at moderate concentrations of NOy and in a static cell held at 1 atm. In this work, the production of NO₂ was measured using a novel AP-LIF. This setup made it possible to measure the rate of production of NO₂ due to the heterogeneous reaction of NO with HNO₃ under ambient conditions. Under these conditions it was found that renoxification due to gas-phase NO on surface HNO₃ is not a significant source of NO₂. However, this study did show the importance of water vapor in the renoxification of surface HNO₃. Title: Development of an Atmospheric Pressure Laser Induced Fluorimeter (AP-LIF) for NO₂ and Application of AP-LIF for Study of Heterogeneous NO₂ Chemistry Author: Parra, Jeremy Year: 2012 Nitrogen dioxide (NO₂) is a pollutant of interest for study both because of its controlling role in the oxidant capacity of the atmosphere and the health risks it poses. Concerns about the health effects of NO₂ and its role in forming deleterious atmospheric species have made it desirable to have low-cost, sensitive ambient measurements of NO₂. A continuous-wave laser-diode laser-induced fluorescence (LIF) system for NO₂ was developed here which operates at ambient pressure, thereby eliminating the need for an expensive pumping system. The current prototype system has achieved sensitivity several orders of magnitude beyond previous efforts at ambient pressure (limit of detection of 2 ppb, 60 s averaging time). Ambient measurements of NO₂ were made in Portland, Oregon using both the standard NO₂ chemiluminescence method and the LIF instrument and showed good agreement (r² = 0.92). In addition, investigations into surface mediated chemistry involving oxides of nitrogen (namely, NO₂) have stimulated new inquiry into potential heterogeneous sources of NO₂ as well as challenged the stability of permanent sinks for NO₂. The possibility that surface mediated chemistry plays a significant role in NOy chemistry in urban air has for the past few decades received considerable attention. The AP-LIF NO₂ instrument is uniquely suited to measure surface chemistry under near ambient conditions. The so called 'renoxification' reaction of gaseous NO with surface bound HNO₃ yielding NO₂ (2HNO₃(surface) + NO--> 3NO₂ +H₂O(surface)) was suggested as a potentially important source of NO₂ which also degraded the stability of nitric acid as a sink of active oxides of nitrogen. Yet, there is disagreement in the literature as to the importance of this reaction. The disagreement stems from differing measurements of the rate for the renoxification reaction. Because there are differences in experimental setups no one research group has studied the renoxification reaction under ambient conditions, i.e., at moderate concentrations of NOy and in a static cell held at 1 atm. In this work, the production of NO₂ was measured using a novel AP-LIF. This setup made it possible to measure the rate of production of NO₂ due to the heterogeneous reaction of NO with HNO₃ under ambient conditions. Under these conditions it was found that renoxification due to gas-phase NO on surface HNO₃ is not a significant source of NO₂. However, this study did show the importance of water vapor in the renoxification of surface HNO₃. Close

• 87. [Article] A Dynamic Physical Model for Soil Temperature and Water in Taylor Valley, Antarctica

  We developed a simulation model for terrestrial sites including sensible heat exchange between the atmosphere and ground surface, inter- and intra-layer heat conduction by rock and soil, and shortwave ...

  Citation × Citation Citation Abstract Copy Title: A Dynamic Physical Model for Soil Temperature and Water in Taylor Valley, Antarctica Author: Hunt, H. W., Fountain, Andrew G., Doran, Peter T., Basagic, Hassan J. Year: 2010 We developed a simulation model for terrestrial sites including sensible heat exchange between the atmosphere and ground surface, inter- and intra-layer heat conduction by rock and soil, and shortwave and longwave radiation. Water fluxes included snowmelt, freezing/thawing of soil water, soil capillary flow, and vapour flows among atmosphere, soil, and snow. The model accounted for 96-99% of variation in soil temperature data. No long-term temporal trends in soil temperature were apparent. Soil water vapour concentration in thawed surface soil in summer often was higher than in frozen deeper soils, leading to downward vapour fluxes. Katabatic winds caused a reversal of the usual winter pattern of upward vapour fluxes. The model exhibited a steady state depth distribution of soil water due to vapour flows and in the absence of capillary flows below the top 0.5 cm soil layer. Beginning with a completely saturated soil profile, soil water was lost rapidly, and within a few hundred years approached a steady state characterized by dry soil (,0.5% gravimetric) down to one metre depth and saturated soil below that. In contrast, it took 42,000 years to approach steady state beginning from a completely dry initial condition. Title: A Dynamic Physical Model for Soil Temperature and Water in Taylor Valley, Antarctica Author: Hunt, H. W., Fountain, Andrew G., Doran, Peter T., Basagic, Hassan J. Year: 2010 We developed a simulation model for terrestrial sites including sensible heat exchange between the atmosphere and ground surface, inter- and intra-layer heat conduction by rock and soil, and shortwave and longwave radiation. Water fluxes included snowmelt, freezing/thawing of soil water, soil capillary flow, and vapour flows among atmosphere, soil, and snow. The model accounted for 96-99% of variation in soil temperature data. No long-term temporal trends in soil temperature were apparent. Soil water vapour concentration in thawed surface soil in summer often was higher than in frozen deeper soils, leading to downward vapour fluxes. Katabatic winds caused a reversal of the usual winter pattern of upward vapour fluxes. The model exhibited a steady state depth distribution of soil water due to vapour flows and in the absence of capillary flows below the top 0.5 cm soil layer. Beginning with a completely saturated soil profile, soil water was lost rapidly, and within a few hundred years approached a steady state characterized by dry soil (,0.5% gravimetric) down to one metre depth and saturated soil below that. In contrast, it took 42,000 years to approach steady state beginning from a completely dry initial condition. Close

• 88. [Article] Water track modification of soil ecosystems in the Lake Hoare basin, Taylor Valley, Antarctica

  Water tracks are zones of high soil moisture that route shallow groundwater down-slope, through the active layer and above the ice table. A water track in Taylor Valley, McMurdo Dry Valleys, was analysed ...

  Citation × Citation Citation Abstract Copy Title: Water track modification of soil ecosystems in the Lake Hoare basin, Taylor Valley, Antarctica Author: Levy, Joseph S., Fountain, Andrew G., Gooseff, Michael N., Barrett, John E., Vantreese, Robert, Welch, Kathleen A., Lyons, W. Berry, Nielsen, Uffe N., Wall, Diana H. Year: 2013 Water tracks are zones of high soil moisture that route shallow groundwater down-slope, through the active layer and above the ice table. A water track in Taylor Valley, McMurdo Dry Valleys, was analysed for surface hydrogeological, geochemical, and biological characteristics in order to test the hypothesis that water tracks provide spatial structure to Antarctic soil ecosystems by changing the physical conditions in the soil environment within the water tracks from those outside the water tracks. The presence of the water track significantly affected the distribution of biotic and abiotic ecosystem parameters: increasing soil moisture, soil salinity, and soil organic matter within the water track relative to soils outside the water track, and reducing soil phosphate, soil pH, and the population of nematodes and other invertebrates in water track soils relative to off track soils. These results suggest that water tracks are distinct and extreme ecological zones in Taylor Valley that provide long-range (kilometre to multikilometre) structure to Antarctic hillslope ecosystems through physical control on soil moisture and solute content. Contrary to expectations, these high soil-moisture sites are not hotspots for faunal biological activity because high soil salinity makes them suitable habitats for only the most halo-tolerant organisms Title: Water track modification of soil ecosystems in the Lake Hoare basin, Taylor Valley, Antarctica Author: Levy, Joseph S., Fountain, Andrew G., Gooseff, Michael N., Barrett, John E., Vantreese, Robert, Welch, Kathleen A., Lyons, W. Berry, Nielsen, Uffe N., Wall, Diana H. Year: 2013 Water tracks are zones of high soil moisture that route shallow groundwater down-slope, through the active layer and above the ice table. A water track in Taylor Valley, McMurdo Dry Valleys, was analysed for surface hydrogeological, geochemical, and biological characteristics in order to test the hypothesis that water tracks provide spatial structure to Antarctic soil ecosystems by changing the physical conditions in the soil environment within the water tracks from those outside the water tracks. The presence of the water track significantly affected the distribution of biotic and abiotic ecosystem parameters: increasing soil moisture, soil salinity, and soil organic matter within the water track relative to soils outside the water track, and reducing soil phosphate, soil pH, and the population of nematodes and other invertebrates in water track soils relative to off track soils. These results suggest that water tracks are distinct and extreme ecological zones in Taylor Valley that provide long-range (kilometre to multikilometre) structure to Antarctic hillslope ecosystems through physical control on soil moisture and solute content. Contrary to expectations, these high soil-moisture sites are not hotspots for faunal biological activity because high soil salinity makes them suitable habitats for only the most halo-tolerant organisms Close

• 89. [Article] Bioaerosol Deposition on an Air-Conditioning Cooling Coil

  This study is concerned with the role of a fin-and-tube heat exchanger in modifying microbial indoor air quality. Specifically, depositional losses of ambient bioaerosols and particles onto dry (not cooled) ...

  Citation × Citation Citation Abstract Copy Title: Bioaerosol Deposition on an Air-Conditioning Cooling Coil Author: Wu, Yan, Chen, Ailu, Luhung, Irvan, Gall, Elliot T., Cao, Qingliang, Wei-Chung Chang, Victor, Nazaroff, William W. Year: 2016 This study is concerned with the role of a fin-and-tube heat exchanger in modifying microbial indoor air quality. Specifically, depositional losses of ambient bioaerosols and particles onto dry (not cooled) and wet (cool) coil surfaces were measured for different airspeeds passing through the test coil. Total, bacterial and fungal DNA concentrations in condensate water produced by a wet coil were also quantified by means of fluorescent dsDNA-binding dye and qPCR assays. Results revealed that the deposition of bioaerosols and total particles is substantial on coil surfaces, especially when wet and cool. The average deposition fraction was 0.14 for total DNA, 0.18 for bacterial DNA and 0.22 for fungal DNA on the dry coil, increasing to 0.51 for total DNA, 0.50 for bacterial DNA and 0.68 for fungal DNA on the wet coil. Overall, as expected, deposition fractions increased with increasing particle size and increasing airspeed. Deposited DNA was removed from the cooling coil surfaces through the flow of condensing water at a rate comparable to the rate of direct deposition from air. A downward trend of bacterial and fungal DNA measured in condensate water over time provides suggestive evidence of biological growth on heat exchangers during nonoperational times of a ventilation system. This investigation provides new information about bioaerosol deposition onto a conventional fin-and-tube cooling coil, a potentially important factor influencing indoor exposure to microbial aerosols in air-conditioned buildings. Title: Bioaerosol Deposition on an Air-Conditioning Cooling Coil Author: Wu, Yan, Chen, Ailu, Luhung, Irvan, Gall, Elliot T., Cao, Qingliang, Wei-Chung Chang, Victor, Nazaroff, William W. Year: 2016 This study is concerned with the role of a fin-and-tube heat exchanger in modifying microbial indoor air quality. Specifically, depositional losses of ambient bioaerosols and particles onto dry (not cooled) and wet (cool) coil surfaces were measured for different airspeeds passing through the test coil. Total, bacterial and fungal DNA concentrations in condensate water produced by a wet coil were also quantified by means of fluorescent dsDNA-binding dye and qPCR assays. Results revealed that the deposition of bioaerosols and total particles is substantial on coil surfaces, especially when wet and cool. The average deposition fraction was 0.14 for total DNA, 0.18 for bacterial DNA and 0.22 for fungal DNA on the dry coil, increasing to 0.51 for total DNA, 0.50 for bacterial DNA and 0.68 for fungal DNA on the wet coil. Overall, as expected, deposition fractions increased with increasing particle size and increasing airspeed. Deposited DNA was removed from the cooling coil surfaces through the flow of condensing water at a rate comparable to the rate of direct deposition from air. A downward trend of bacterial and fungal DNA measured in condensate water over time provides suggestive evidence of biological growth on heat exchangers during nonoperational times of a ventilation system. This investigation provides new information about bioaerosol deposition onto a conventional fin-and-tube cooling coil, a potentially important factor influencing indoor exposure to microbial aerosols in air-conditioned buildings. Close

• 90. [Article] Estimation of Transient Temperature Distribution during Quenching, via a Parabolic Model

  A material-independent model to estimate the transient temperature distribution in a test probe quenched by immersion is presented in this study. This model is based on the assumption that, under one-dimensional ...

  Citation × Citation Citation Abstract Copy Title: Estimation of Transient Temperature Distribution during Quenching, via a Parabolic Model Author: Lozano, Diego E., Martinez-Solis, Gabriela, Mercado-Solis, Rafael David, Colás, Rafael, Totten, George E. Year: 2015 A material-independent model to estimate the transient temperature distribution in a test probe quenched by immersion is presented in this study. This model is based on the assumption that, under one-dimensional unsteady heat conduction, the radial temperature distribution at the end of an interval belongs to the equation of a parabola. The model was validated using AISI 304 stainless steel test probes (Φ8×40 mm and Φ12×60 mm) quenched from 850 to 900 °C in water and in water-based NaNO2 solutions at 25 °C and in canola oil at 50 °C. Additionally, square test probes (20×20×100 mm) were quenched from 550 °C in water. The test probes were equipped with embedded thermocouples for temperature-versus-time data logging at the core, one-quarter thickness and 1 mm below the surface. In each experiment, the data recordings from the core and near-surface thermocouples were employed for the temperature calculations while the data from the one-quarter thickness thermocouple were employed for model validity verifications. In all cases, the calculated temperature distributions showed good correlations with the experimentally obtained values. Based on the results of this work, it is concluded that this approach constitutes a simple, quick and efficient tool for estimating transient surface and radial temperature distributions and represents a useful resource for quenchant cooling rate calculations and heat transfer characterizations. Title: Estimation of Transient Temperature Distribution during Quenching, via a Parabolic Model Author: Lozano, Diego E., Martinez-Solis, Gabriela, Mercado-Solis, Rafael David, Colás, Rafael, Totten, George E. Year: 2015 A material-independent model to estimate the transient temperature distribution in a test probe quenched by immersion is presented in this study. This model is based on the assumption that, under one-dimensional unsteady heat conduction, the radial temperature distribution at the end of an interval belongs to the equation of a parabola. The model was validated using AISI 304 stainless steel test probes (Φ8×40 mm and Φ12×60 mm) quenched from 850 to 900 °C in water and in water-based NaNO2 solutions at 25 °C and in canola oil at 50 °C. Additionally, square test probes (20×20×100 mm) were quenched from 550 °C in water. The test probes were equipped with embedded thermocouples for temperature-versus-time data logging at the core, one-quarter thickness and 1 mm below the surface. In each experiment, the data recordings from the core and near-surface thermocouples were employed for the temperature calculations while the data from the one-quarter thickness thermocouple were employed for model validity verifications. In all cases, the calculated temperature distributions showed good correlations with the experimentally obtained values. Based on the results of this work, it is concluded that this approach constitutes a simple, quick and efficient tool for estimating transient surface and radial temperature distributions and represents a useful resource for quenchant cooling rate calculations and heat transfer characterizations. Close

• 91. [Article] Design and Application of a 3D Photocatalyst Material for Water Purification

  This dissertation presents a method for enhancement of the efficiency and scalability of photocatalytic water purification systems, along with an experimental validation of the concept. A 3-dimensional ...

  Citation × Citation Citation Abstract Copy Title: Design and Application of a 3D Photocatalyst Material for Water Purification Author: Fowler, Simon Paul Year: 2017 This dissertation presents a method for enhancement of the efficiency and scalability of photocatalytic water purification systems, along with an experimental validation of the concept. A 3-dimensional photocatalyst structure, made from a TiO2-SiO2 composite, has been designed and fabricated for use in a custom designed LED-source illumination chamber of rotational symmetry that corresponds with the symmetry of the photocatalyst material. The design of the photocatalyst material has two defining characteristics: geometrical form and material composition. The design of the material was developed through the creation of a theoretical model for consideration of the system's photonic efficiency. Fabrication of the material was accomplished using a Ti alkoxide solution to coat a novel 3D support structure. The coatings were then heat treated to form a semiconducting thin-film. The resulting films were evaluated by SEM, TEM, UV-vis spectroscopy and Raman spectroscopy. The surface of the material was then modified by implantation of TiO2 and SiO2 nanoparticles in order to increase catalytic surface area and improve the photoactivity of the material, resulting in increased degradation performance by more than 500%. Finally, the efficiency of the photocatalytic reactor was considered with respect to energy usage as defined by the Electrical Energy per Order (EEO) characterization model. The effects of catalyst surface modification and UV-illumination intensity on the EEO value were measured and analyzed. The result of the modifications was an 81.9% reduction in energy usage. The lowest EEO achieved was 54 kWh per cubic meter of water for each order of magnitude reduction in pollutant concentration -- an improvement in EEO over previously reported thin-film based photoreactors. Title: Design and Application of a 3D Photocatalyst Material for Water Purification Author: Fowler, Simon Paul Year: 2017 This dissertation presents a method for enhancement of the efficiency and scalability of photocatalytic water purification systems, along with an experimental validation of the concept. A 3-dimensional photocatalyst structure, made from a TiO2-SiO2 composite, has been designed and fabricated for use in a custom designed LED-source illumination chamber of rotational symmetry that corresponds with the symmetry of the photocatalyst material. The design of the photocatalyst material has two defining characteristics: geometrical form and material composition. The design of the material was developed through the creation of a theoretical model for consideration of the system's photonic efficiency. Fabrication of the material was accomplished using a Ti alkoxide solution to coat a novel 3D support structure. The coatings were then heat treated to form a semiconducting thin-film. The resulting films were evaluated by SEM, TEM, UV-vis spectroscopy and Raman spectroscopy. The surface of the material was then modified by implantation of TiO2 and SiO2 nanoparticles in order to increase catalytic surface area and improve the photoactivity of the material, resulting in increased degradation performance by more than 500%. Finally, the efficiency of the photocatalytic reactor was considered with respect to energy usage as defined by the Electrical Energy per Order (EEO) characterization model. The effects of catalyst surface modification and UV-illumination intensity on the EEO value were measured and analyzed. The result of the modifications was an 81.9% reduction in energy usage. The lowest EEO achieved was 54 kWh per cubic meter of water for each order of magnitude reduction in pollutant concentration -- an improvement in EEO over previously reported thin-film based photoreactors. Close

• 92. [Article] Spatial and Temporal Variability of Glacier Melt in the McMurdo Dry Valleys, Antarctica

  In the McMurdo Dry Valleys, Victoria Land, East Antarctica, melting of glacial ice is the primary source of water to streams, lakes, and associated ecosystems. To better understand meltwater production, ...

  Citation × Citation Citation Abstract Copy Title: Spatial and Temporal Variability of Glacier Melt in the McMurdo Dry Valleys, Antarctica Author: Hoffman, Matthew James Year: 2011 In the McMurdo Dry Valleys, Victoria Land, East Antarctica, melting of glacial ice is the primary source of water to streams, lakes, and associated ecosystems. To better understand meltwater production, three hypotheses are tested: 1) that small changes in the surface energy balance on these glaciers will result in large changes in melt, 2) that subsurface melt does not contribute significantly to runoff, and 3) that melt from 25-m high terminal cliffs is the dominant source of baseflow during cold periods. These hypotheses were investigated using a surface energy balance model applied to the glaciers of Taylor Valley using 14 years of meteorological data and calibrated to ablation measurements. Inclusion of transmission of solar radiation into the ice through a source term in a one-dimensional heat transfer equation was necessary to accurately model summer ablation and ice temperatures. Results showed good correspondence between calculated and measured ablation and ice temperatures over the 14 years using both daily and hourly time steps, but an hourly time step allowed resolution of short duration melt events and melt within the upper 15 cm of the ice. Resolution of short duration melt events was not important for properly resolving seasonal ablation totals. Across the smooth surfaces of the glaciers, ablation was dominated by sublimation and melting was rare. Above freezing air temperatures did not necessarily result in melt, and low wind speed was important for melt initiation. According to the model, subsurface melt between 5 and 15 cm depth was extensive and lasted for up to six weeks in some summers. The model was better able to predict ablation if some subsurface melt was assumed to drain, lowering ice density, consistent with observations of a low density weathering crust that forms over the course of the summer on Dry Valley glaciers. In extreme summers, drainage of subsurface melt may have contributed up to half of the observed surface lowering through reduction of ice density and possibly through collapse of highly weathered ice. When applied spatially, the model successfully predicted proglacial streamflow at seasonal and daily time scales. This was despite omitting a routing scheme, and instead assuming that all melt generated exits the glacier on the same day, suggesting refreezing is not substantial. Including subsurface melt as runoff improved predictions of runoff volume and timing, particularly for the recession of large flood peaks. Because overland flow was rarely observed over much of these glaciers, these model results suggest that runoff may be predominantly transported beneath the surface in a partially melted permeable layer of weathered ice. According to the model, topographic basins, particularly the low albedo basin floors, played a prominent role in runoff production. Smooth glacier surfaces exhibited low melt rates, but were important during high melt conditions due to their large surface area. Estimated runoff contributions from cliffs and cryoconite holes was somewhat smaller than suggested in previous studies. Spatial and temporal variability in albedo due to snow and debris played a dominant role in flow variations between streams and seasons. In general, the model supported the existing assumption that snowmelt is insignificant, but in extreme melt years snowmelt in the accumulation area may contribute significantly to runoff in some locations. Title: Spatial and Temporal Variability of Glacier Melt in the McMurdo Dry Valleys, Antarctica Author: Hoffman, Matthew James Year: 2011 In the McMurdo Dry Valleys, Victoria Land, East Antarctica, melting of glacial ice is the primary source of water to streams, lakes, and associated ecosystems. To better understand meltwater production, three hypotheses are tested: 1) that small changes in the surface energy balance on these glaciers will result in large changes in melt, 2) that subsurface melt does not contribute significantly to runoff, and 3) that melt from 25-m high terminal cliffs is the dominant source of baseflow during cold periods. These hypotheses were investigated using a surface energy balance model applied to the glaciers of Taylor Valley using 14 years of meteorological data and calibrated to ablation measurements. Inclusion of transmission of solar radiation into the ice through a source term in a one-dimensional heat transfer equation was necessary to accurately model summer ablation and ice temperatures. Results showed good correspondence between calculated and measured ablation and ice temperatures over the 14 years using both daily and hourly time steps, but an hourly time step allowed resolution of short duration melt events and melt within the upper 15 cm of the ice. Resolution of short duration melt events was not important for properly resolving seasonal ablation totals. Across the smooth surfaces of the glaciers, ablation was dominated by sublimation and melting was rare. Above freezing air temperatures did not necessarily result in melt, and low wind speed was important for melt initiation. According to the model, subsurface melt between 5 and 15 cm depth was extensive and lasted for up to six weeks in some summers. The model was better able to predict ablation if some subsurface melt was assumed to drain, lowering ice density, consistent with observations of a low density weathering crust that forms over the course of the summer on Dry Valley glaciers. In extreme summers, drainage of subsurface melt may have contributed up to half of the observed surface lowering through reduction of ice density and possibly through collapse of highly weathered ice. When applied spatially, the model successfully predicted proglacial streamflow at seasonal and daily time scales. This was despite omitting a routing scheme, and instead assuming that all melt generated exits the glacier on the same day, suggesting refreezing is not substantial. Including subsurface melt as runoff improved predictions of runoff volume and timing, particularly for the recession of large flood peaks. Because overland flow was rarely observed over much of these glaciers, these model results suggest that runoff may be predominantly transported beneath the surface in a partially melted permeable layer of weathered ice. According to the model, topographic basins, particularly the low albedo basin floors, played a prominent role in runoff production. Smooth glacier surfaces exhibited low melt rates, but were important during high melt conditions due to their large surface area. Estimated runoff contributions from cliffs and cryoconite holes was somewhat smaller than suggested in previous studies. Spatial and temporal variability in albedo due to snow and debris played a dominant role in flow variations between streams and seasons. In general, the model supported the existing assumption that snowmelt is insignificant, but in extreme melt years snowmelt in the accumulation area may contribute significantly to runoff in some locations. Close

• 93. [Article] Head Wave Correlations in Ambient Noise

  Ambient ocean noise is processed with a vertical line array to reveal coherent time-separated arrivals suggesting the presence of head wave multipath propagation. Head waves, which are critically propagating ...

  Citation × Citation Citation Abstract Copy Title: Head Wave Correlations in Ambient Noise Author: Gebbie, John Thomas, Siderius, Martin Year: 2016 Ambient ocean noise is processed with a vertical line array to reveal coherent time-separated arrivals suggesting the presence of head wave multipath propagation. Head waves, which are critically propagating water waves created by seabed waves traveling parallel to the water-sediment interface, can propagate faster than water-only waves. Such eigenrays are much weaker than water-only eigenrays, and are often completely overshadowed by them. Surface-generated noise is different whereby it amplifies the coherence between head waves and critically propagating water-only waves, which is measured by cross-correlating critically steered beams. This phenomenon is demonstrated both experimentally and with a full wave simulation. Title: Head Wave Correlations in Ambient Noise Author: Gebbie, John Thomas, Siderius, Martin Year: 2016 Ambient ocean noise is processed with a vertical line array to reveal coherent time-separated arrivals suggesting the presence of head wave multipath propagation. Head waves, which are critically propagating water waves created by seabed waves traveling parallel to the water-sediment interface, can propagate faster than water-only waves. Such eigenrays are much weaker than water-only eigenrays, and are often completely overshadowed by them. Surface-generated noise is different whereby it amplifies the coherence between head waves and critically propagating water-only waves, which is measured by cross-correlating critically steered beams. This phenomenon is demonstrated both experimentally and with a full wave simulation. Close

• 94. [Article] 3D Hydrodynamic Model Development and Verification

  A three-dimensional numerical model was developed to simulate hydrodynamic, temperature, and water quality distributions in rivers and lakes. In an attempt to get rid of the extra approximation and complexity, ...

  Citation × Citation Citation Abstract Copy Title: 3D Hydrodynamic Model Development and Verification Author: Al-Zubaidi, Hussein A. M. Year: 2016 A three-dimensional numerical model was developed to simulate hydrodynamic, temperature, and water quality distributions in rivers and lakes. In an attempt to get rid of the extra approximation and complexity, no coordinate transformation has been done and z-coordinate system has been employed. The governing equations are the continuity equation, free surface equation, momentum equations, and conservation equations of temperature and water quality. The model employs the time splitting technique which allows splitting the directions in which we end with two-dimensional governing equations and eventually the solution ends with a tri-diagonal matrix, which is easily solved by Thomas algorithm. The first step after developing a numerical model and before adding more features or applying the model to a real case, the model should be verified. The verification of the model was done by implementing the model to known solutions test cases in additional to evaluating whether the code preserves fluid mass. A series of test cases is performed by comparing the model results with the analytical solutions as proposed by many modelers. The model showed good agreement between the analytical and the numerical solution. Title: 3D Hydrodynamic Model Development and Verification Author: Al-Zubaidi, Hussein A. M. Year: 2016 A three-dimensional numerical model was developed to simulate hydrodynamic, temperature, and water quality distributions in rivers and lakes. In an attempt to get rid of the extra approximation and complexity, no coordinate transformation has been done and z-coordinate system has been employed. The governing equations are the continuity equation, free surface equation, momentum equations, and conservation equations of temperature and water quality. The model employs the time splitting technique which allows splitting the directions in which we end with two-dimensional governing equations and eventually the solution ends with a tri-diagonal matrix, which is easily solved by Thomas algorithm. The first step after developing a numerical model and before adding more features or applying the model to a real case, the model should be verified. The verification of the model was done by implementing the model to known solutions test cases in additional to evaluating whether the code preserves fluid mass. A series of test cases is performed by comparing the model results with the analytical solutions as proposed by many modelers. The model showed good agreement between the analytical and the numerical solution. Close

• 95. [Article] Engineering a Healthier Watershed: Middle School Students Use Engineering Design to Lessen the Impact of Their Campus' Impervious Surfaces on Their Local Watershed

  It is important that students understand not only how their local watershed functions, but also how it is being impacted by impervious surfaces. Additionally, students need experience exploring the scientific ...

  Citation × Citation Citation Abstract Copy Title: Engineering a Healthier Watershed: Middle School Students Use Engineering Design to Lessen the Impact of Their Campus' Impervious Surfaces on Their Local Watershed Author: Gardner, Elizabeth Claire Year: 2015 It is important that students understand not only how their local watershed functions, but also how it is being impacted by impervious surfaces. Additionally, students need experience exploring the scientific and engineering practices that are necessary for a strong STEM background. With this knowledge students can be empowered to tackle this real and local problem using engineering design, a powerful practice gaining momentum and clarity through its prominence in the recent Framework for K-12 Science Education. Twenty classes of suburban sixth-graders participated in a new five-week Watershed Engineering Design Unit taught by their regular science teachers. Students engaged in scientific inquiry to learn about the structure, function, and health of their local watersheds, focusing on the effects of impervious surfaces. In small groups, students used the engineering design process to propose solutions to lessen the impact of runoff from their school campuses. The goal of this evaluation was to determine the effectiveness of the curriculum in terms of student gains in understanding of (1) watershed function, (2) the impact of impervious surfaces, and (3) the engineering design process. To determine the impact of this curriculum on their learning, students took multiple-choice pre- and post-assessments made up of items covering the three categories above. This data was analyzed for statistical significance using a lower-tailed paired sample t-test. All three objectives showed statistically significant learning gains and the results were used to recommend improvements to the curriculum and the assessment instrument for future iterations. Title: Engineering a Healthier Watershed: Middle School Students Use Engineering Design to Lessen the Impact of Their Campus' Impervious Surfaces on Their Local Watershed Author: Gardner, Elizabeth Claire Year: 2015 It is important that students understand not only how their local watershed functions, but also how it is being impacted by impervious surfaces. Additionally, students need experience exploring the scientific and engineering practices that are necessary for a strong STEM background. With this knowledge students can be empowered to tackle this real and local problem using engineering design, a powerful practice gaining momentum and clarity through its prominence in the recent Framework for K-12 Science Education. Twenty classes of suburban sixth-graders participated in a new five-week Watershed Engineering Design Unit taught by their regular science teachers. Students engaged in scientific inquiry to learn about the structure, function, and health of their local watersheds, focusing on the effects of impervious surfaces. In small groups, students used the engineering design process to propose solutions to lessen the impact of runoff from their school campuses. The goal of this evaluation was to determine the effectiveness of the curriculum in terms of student gains in understanding of (1) watershed function, (2) the impact of impervious surfaces, and (3) the engineering design process. To determine the impact of this curriculum on their learning, students took multiple-choice pre- and post-assessments made up of items covering the three categories above. This data was analyzed for statistical significance using a lower-tailed paired sample t-test. All three objectives showed statistically significant learning gains and the results were used to recommend improvements to the curriculum and the assessment instrument for future iterations. Close

• 96. [Article] Hydrophobic Surfactant Proteins Strongly Induce Negative Curvature

  The hydrophobic surfactant proteins SP-B and SP-C greatly accelerate the adsorption of vesicles containing the surfactant lipids to form a film that lowers the surface tension of the air/water interface ...

  Citation × Citation Citation Abstract Copy Title: Hydrophobic Surfactant Proteins Strongly Induce Negative Curvature Author: Chavarha, Mariya, Loney, Ryan W., Rananavare, Shankar B., Hall, Stephen B. Year: 2015 The hydrophobic surfactant proteins SP-B and SP-C greatly accelerate the adsorption of vesicles containing the surfactant lipids to form a film that lowers the surface tension of the air/water interface in the lungs. Pulmonary surfactant enters the interface by a process analogous to the fusion of two vesicles. As with fusion, several factors affect adsorption according to how they alter the curvature of lipid leaflets, suggesting that adsorption proceeds via a rate-limiting structure with negative curvature, in which the hydrophilic face of the phospholipid leaflets is concave. In the studies reported here, we tested whether the surfactant proteins might promote adsorption by inducing lipids to adopt a more negative curvature, closer to the configuration of the hypothetical intermediate. Our experiments used x-ray diffraction to determine how the proteins in their physiological ratio affect the radius of cylindrical monolayers in the negatively curved, inverse hexagonal phase. With binary mixtures of dioleoylphosphatidylethanolamine (DOPE) and dioleoylphosphatidylcholine (DOPC), the proteins produced a dose-related effect on curvature that depended on the phospholipid composition. With DOPE alone, the proteins produced no change. With an increasing mol fraction of DOPC, the response to the proteins increased, reaching a maximum 50% reduction in cylindrical radius at 5% (w/w) protein. This change represented a doubling of curvature at the outer cylindrical surface. The change in spontaneous curvature, defined at approximately the level of the glycerol group, would be greater. Analysis of the results in terms of a Langmuir model for binding to a surface suggests that the effect of the lipids is consistent with a change in the maximum binding capacity. Our findings show that surfactant proteins can promote negative curvature, and support the possibility that they facilitate adsorption by that mechanism. Title: Hydrophobic Surfactant Proteins Strongly Induce Negative Curvature Author: Chavarha, Mariya, Loney, Ryan W., Rananavare, Shankar B., Hall, Stephen B. Year: 2015 The hydrophobic surfactant proteins SP-B and SP-C greatly accelerate the adsorption of vesicles containing the surfactant lipids to form a film that lowers the surface tension of the air/water interface in the lungs. Pulmonary surfactant enters the interface by a process analogous to the fusion of two vesicles. As with fusion, several factors affect adsorption according to how they alter the curvature of lipid leaflets, suggesting that adsorption proceeds via a rate-limiting structure with negative curvature, in which the hydrophilic face of the phospholipid leaflets is concave. In the studies reported here, we tested whether the surfactant proteins might promote adsorption by inducing lipids to adopt a more negative curvature, closer to the configuration of the hypothetical intermediate. Our experiments used x-ray diffraction to determine how the proteins in their physiological ratio affect the radius of cylindrical monolayers in the negatively curved, inverse hexagonal phase. With binary mixtures of dioleoylphosphatidylethanolamine (DOPE) and dioleoylphosphatidylcholine (DOPC), the proteins produced a dose-related effect on curvature that depended on the phospholipid composition. With DOPE alone, the proteins produced no change. With an increasing mol fraction of DOPC, the response to the proteins increased, reaching a maximum 50% reduction in cylindrical radius at 5% (w/w) protein. This change represented a doubling of curvature at the outer cylindrical surface. The change in spontaneous curvature, defined at approximately the level of the glycerol group, would be greater. Analysis of the results in terms of a Langmuir model for binding to a surface suggests that the effect of the lipids is consistent with a change in the maximum binding capacity. Our findings show that surfactant proteins can promote negative curvature, and support the possibility that they facilitate adsorption by that mechanism. Close

• 97. [Article] Glacier Change on the Three Sisters Volcanoes, Oregon: 1900-2010

  A glacier responds to changes in climate by subsequent retreat and advance as a result of changes in snow inputs and outputs. Understanding these changes is important because shrinking glaciers limit and ...

  Citation × Citation Citation Abstract Copy Title: Glacier Change on the Three Sisters Volcanoes, Oregon: 1900-2010 Author: Ohlschlager, Justin George Year: 2015 A glacier responds to changes in climate by subsequent retreat and advance as a result of changes in snow inputs and outputs. Understanding these changes is important because shrinking glaciers limit and diminish local water resources. They contribute to alpine runoff in the late-summer months by delaying the maximum runoff until late in the melt season. A comprehensive glacier and perennial snowfield inventory has not been completed for the Three Sisters in Central Oregon. Using aerial photography, Digital Elevation Models (DEMs), previous studies, and historical ground based photographs these glacier and perennial snowfields were defined and their surface area change was quantified along with surface area and volume change for the 15 named glaciers for multiple years. The glaciers and perennial snowfields totaled 9.03 ± 1.65 km2 in 1949 and decreased to 7.1 ± 1.16 km2 in 2003 giving a total loss of -1.914 ± 0.974 km2 ( 21%). The 15 named glaciers totaled 12.43 ± 0.417 km2 in ~1900 and decreased to 5.65 ± 0.135 km2 in 2003 giving a total loss of -6.70 ± 0.439 km2 (54%) with more loss occurring in the early part of the century. It's estimated that the 15 named glaciers lost roughly 61% of volume from 1900 to 2010. From 1957 to 2010 their surface's dropped in elevation on average by -8.9m, losing an estimated 71.96 x 106 ± 2.87 x 106 m3 (53%) in total volume, seen across accumulation and ablation zones, with more loss happening from 1957 to 1990. There was no relationship found between topography and area. A small correlation was found between slope and increased volume change. Debris cover on glacier surfaces has increased and showed a correlation between decreasing area loss (no correlation with volume changes). Title: Glacier Change on the Three Sisters Volcanoes, Oregon: 1900-2010 Author: Ohlschlager, Justin George Year: 2015 A glacier responds to changes in climate by subsequent retreat and advance as a result of changes in snow inputs and outputs. Understanding these changes is important because shrinking glaciers limit and diminish local water resources. They contribute to alpine runoff in the late-summer months by delaying the maximum runoff until late in the melt season. A comprehensive glacier and perennial snowfield inventory has not been completed for the Three Sisters in Central Oregon. Using aerial photography, Digital Elevation Models (DEMs), previous studies, and historical ground based photographs these glacier and perennial snowfields were defined and their surface area change was quantified along with surface area and volume change for the 15 named glaciers for multiple years. The glaciers and perennial snowfields totaled 9.03 ± 1.65 km2 in 1949 and decreased to 7.1 ± 1.16 km2 in 2003 giving a total loss of -1.914 ± 0.974 km2 ( 21%). The 15 named glaciers totaled 12.43 ± 0.417 km2 in ~1900 and decreased to 5.65 ± 0.135 km2 in 2003 giving a total loss of -6.70 ± 0.439 km2 (54%) with more loss occurring in the early part of the century. It's estimated that the 15 named glaciers lost roughly 61% of volume from 1900 to 2010. From 1957 to 2010 their surface's dropped in elevation on average by -8.9m, losing an estimated 71.96 x 106 ± 2.87 x 106 m3 (53%) in total volume, seen across accumulation and ablation zones, with more loss happening from 1957 to 1990. There was no relationship found between topography and area. A small correlation was found between slope and increased volume change. Debris cover on glacier surfaces has increased and showed a correlation between decreasing area loss (no correlation with volume changes). Close

• 98. [Article] Surface Energy Balance and Melt Thresholds over 11 years at Taylor Glacier, Antarctica

  In the McMurdo Dry Valleys, Victoria Land, Antarctica, melting of glacial ice is the primary source of water to streams, lakes, and associated ecosystems. To understand geochemical fluxes and ecological ...

  Citation × Citation Citation Abstract Copy Title: Surface Energy Balance and Melt Thresholds over 11 years at Taylor Glacier, Antarctica Author: Hoffman, Matthew James, Fountain, Andrew G., Liston, Glen E. Year: 2008 In the McMurdo Dry Valleys, Victoria Land, Antarctica, melting of glacial ice is the primary source of water to streams, lakes, and associated ecosystems. To understand geochemical fluxes and ecological responses to past and future climates requires a physically based energy balance model. We applied a one-dimensional model to one site on Taylor Glacier using 11 years of daily meteorological data and seasonal ablation measurements. Inclusion of transmission of solar radiation into the ice was necessary to accurately model summer ablation and ice temperatures. Results showed good correspondence between calculated and measured ablation and ice temperatures over the 11 years. Ablation (18 cm a??) was dominated by sublimation with very few occurrences of melt (42 days during 11 years). Results also indicated that above freezing air temperatures did not necessarily result in melt and, in turn, melt occurred during subfreezing air temperatures under some conditions. For air temperatures near freezing, low wind speed was critically important for melt initiation. According to the model, subsurface melt, away from rocks and sediment in the ice, occurred three times more frequently than surface melt; occurs no deeper than 50 cm below the glacier surface; and was small, never exceeding 8% by mass. The magnitude of subsurface melting and the energy balance indicate that Taylor Title: Surface Energy Balance and Melt Thresholds over 11 years at Taylor Glacier, Antarctica Author: Hoffman, Matthew James, Fountain, Andrew G., Liston, Glen E. Year: 2008 In the McMurdo Dry Valleys, Victoria Land, Antarctica, melting of glacial ice is the primary source of water to streams, lakes, and associated ecosystems. To understand geochemical fluxes and ecological responses to past and future climates requires a physically based energy balance model. We applied a one-dimensional model to one site on Taylor Glacier using 11 years of daily meteorological data and seasonal ablation measurements. Inclusion of transmission of solar radiation into the ice was necessary to accurately model summer ablation and ice temperatures. Results showed good correspondence between calculated and measured ablation and ice temperatures over the 11 years. Ablation (18 cm a??) was dominated by sublimation with very few occurrences of melt (42 days during 11 years). Results also indicated that above freezing air temperatures did not necessarily result in melt and, in turn, melt occurred during subfreezing air temperatures under some conditions. For air temperatures near freezing, low wind speed was critically important for melt initiation. According to the model, subsurface melt, away from rocks and sediment in the ice, occurred three times more frequently than surface melt; occurs no deeper than 50 cm below the glacier surface; and was small, never exceeding 8% by mass. The magnitude of subsurface melting and the energy balance indicate that Taylor Close

• 99. [Article] High-Speed Quenching of High Carbon Steel

  Medium and high carbon steels are usually quenched in polymer and oil in order to avoid cracking and distortion; however, recent studies have proved that it is possible to minimize cracking using water ...

  Citation × Citation Citation Abstract Copy Title: High-Speed Quenching of High Carbon Steel Author: Martínez-Cázares, Gabriela M., Lozano, Diego E., Guerrero-Mata, Martha, Colás, Rafael, Totten, George E. Year: 2014 Medium and high carbon steels are usually quenched in polymer and oil in order to avoid cracking and distortion; however, recent studies have proved that it is possible to minimize cracking using water as a coolant of these steels by promoting extremely high cooling rates. By great agitation and velocity of quenchant, the vapor blanket is reduced or prevented during water quench, allowing uniform hardening of the surface. In this study, the cooling severity of a spray quenching system and a high-speed quenching chamber are studied. Cylindrical samples of AISI 304 stainless steel (20 mm in diameter and 100 mm length) were employed to characterize the cooling severity. Thermal data was acquired through K-type thermocouples placed in the sample at three positions, 1 mm below surface, mid-radius and at center of the specimen, connected to a data acquisition system. High thermal gradients were observed in both systems, being the high-speed chamber the severest cooling. The maximum cooling rate obtained at the surface was 470 and 300°C/s for the high-speed chamber and the spray system, respectively. In addition, 5160 spring steel samples were quenched for short times in both systems; the cooling was interrupted to avoid through transformation and to produce a case-core type microstructure. Different cooling times were used for the interrupted quenching to modify the martensite case thickness. No cracks were observed. Thermal results and microstructures are discussed. Title: High-Speed Quenching of High Carbon Steel Author: Martínez-Cázares, Gabriela M., Lozano, Diego E., Guerrero-Mata, Martha, Colás, Rafael, Totten, George E. Year: 2014 Medium and high carbon steels are usually quenched in polymer and oil in order to avoid cracking and distortion; however, recent studies have proved that it is possible to minimize cracking using water as a coolant of these steels by promoting extremely high cooling rates. By great agitation and velocity of quenchant, the vapor blanket is reduced or prevented during water quench, allowing uniform hardening of the surface. In this study, the cooling severity of a spray quenching system and a high-speed quenching chamber are studied. Cylindrical samples of AISI 304 stainless steel (20 mm in diameter and 100 mm length) were employed to characterize the cooling severity. Thermal data was acquired through K-type thermocouples placed in the sample at three positions, 1 mm below surface, mid-radius and at center of the specimen, connected to a data acquisition system. High thermal gradients were observed in both systems, being the high-speed chamber the severest cooling. The maximum cooling rate obtained at the surface was 470 and 300°C/s for the high-speed chamber and the spray system, respectively. In addition, 5160 spring steel samples were quenched for short times in both systems; the cooling was interrupted to avoid through transformation and to produce a case-core type microstructure. Different cooling times were used for the interrupted quenching to modify the martensite case thickness. No cracks were observed. Thermal results and microstructures are discussed. Close

• 100. [Article] Sediment Nutrient Accumulation and Nutrient Availability in Two Tidal Freshwater Marshes Along the Mattaponi River, Virginia, USA

  Sediment deposition is the main mechanism of nutrient delivery to tidal freshwater marshes (TFMs). We quantified sediment nutrient accumulation in TFMs upstream and downstream of a proposed water withdrawal ...

  Citation × Citation Citation Abstract Copy Title: Sediment Nutrient Accumulation and Nutrient Availability in Two Tidal Freshwater Marshes Along the Mattaponi River, Virginia, USA Author: Morse, Jennifer L., Megonigal, J. Patrick, Walbridge, Mark R. Year: 2004 Sediment deposition is the main mechanism of nutrient delivery to tidal freshwater marshes (TFMs). We quantified sediment nutrient accumulation in TFMs upstream and downstream of a proposed water withdrawal project on the Mattaponi River, Virginia. Our goal was to assess nutrient availability by comparing relative rates of carbon (C), nitrogen (N), and phosphorus (P) accumulated in sediments with the C, N, and P stoichiometries of surface soils and above ground plant tissues. Surface soil nutrient contents (0.60–0.92% N and 0.09–0.13% P) were low but within reported ranges for TFMs in the eastern US. In both marshes, soil nutrient pools and C, N, and P stoichiometries were closely associated with sedimentation patterns. Differences between marshes were more striking than spatial variations within marshes: both C, N, and P accumulation during summer, and annual P accumulation rates (0.16 and 0.04 g P m−2 year−1, respectively) in sediments were significantly higher at the downstream than at the upstream marsh. Nitrogen:P ratiosbiomass, surface soils, and sediments suggest that N limits primary production in these marshes, but experimental additions of N and/or P did not significantly increase above ground productivity in either marsh. Lower soil N:P ratios are consistent with higher rates of sediment P accumulation at the downstream site, perhaps due to its greater proximity to the estuarine turbidity maximum. Title: Sediment Nutrient Accumulation and Nutrient Availability in Two Tidal Freshwater Marshes Along the Mattaponi River, Virginia, USA Author: Morse, Jennifer L., Megonigal, J. Patrick, Walbridge, Mark R. Year: 2004 Sediment deposition is the main mechanism of nutrient delivery to tidal freshwater marshes (TFMs). We quantified sediment nutrient accumulation in TFMs upstream and downstream of a proposed water withdrawal project on the Mattaponi River, Virginia. Our goal was to assess nutrient availability by comparing relative rates of carbon (C), nitrogen (N), and phosphorus (P) accumulated in sediments with the C, N, and P stoichiometries of surface soils and above ground plant tissues. Surface soil nutrient contents (0.60–0.92% N and 0.09–0.13% P) were low but within reported ranges for TFMs in the eastern US. In both marshes, soil nutrient pools and C, N, and P stoichiometries were closely associated with sedimentation patterns. Differences between marshes were more striking than spatial variations within marshes: both C, N, and P accumulation during summer, and annual P accumulation rates (0.16 and 0.04 g P m−2 year−1, respectively) in sediments were significantly higher at the downstream than at the upstream marsh. Nitrogen:P ratiosbiomass, surface soils, and sediments suggest that N limits primary production in these marshes, but experimental additions of N and/or P did not significantly increase above ground productivity in either marsh. Lower soil N:P ratios are consistent with higher rates of sediment P accumulation at the downstream site, perhaps due to its greater proximity to the estuarine turbidity maximum. Close