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• 1. [Article] Bicycle Level of Service: Where are the Gaps in Bicycle Flow Measures?

  Bicycle use is increasing in many parts of the U.S. Local and regional governments have set ambitious bicycle mode share goals as part of their strategy to curb greenhouse gas emissions and relieve traffic ...

  Citation × Citation Citation Abstract Copy Title: Bicycle Level of Service: Where are the Gaps in Bicycle Flow Measures? Author: Johnson, Pamela Christine Year: 2014 Bicycle use is increasing in many parts of the U.S. Local and regional governments have set ambitious bicycle mode share goals as part of their strategy to curb greenhouse gas emissions and relieve traffic congestion. In particular, Portland, Oregon has set a 25% mode share goal for 2030 (PBOT 2010). Currently bicycle mode share in Portland is 6.1% of all trips. Other cities and regional planning organizations are also setting ambitious bicycle mode share goals and increasing bicycle facilities and programs to encourage bicycling. Increases in bicycle mode share are being encouraged to increase. However, cities with higher-than-average bicycle mode share are beginning to experience locations with bicycle traffic congestion, especially during peak commute hours. Today, there are no established methods are used to describe or measure bicycle traffic flows. In the 1960s, the Highway Capacity Manual (HCM) introduced Level of Service (LOS) measurements to describe traffic flow and capacity of motor vehicles on highways using an A-to-F grading system; "A" describes free flow traffic with no maneuvering constraints for the driver and an "F" grade corresponds to over capacity situations in which traffic flow breaks down or becomes "jammed". LOS metrics were expanded to highway and road facilities, operations and design. In the 1990s, the HCM introduced LOS measurements for transit, pedestrians, and bicycles. Today, there are many well established and emerging bicycle level of service (BLOS) methods that measure the stress, comfort and perception of safety of bicycle facilities. However, it was been assumed that bicycle traffic volumes are low and do not warrant the use of a LOS measure for bicycle capacity and traffic flow. There are few BLOS methods that take bicycle flow into consideration, except for in the case of separated bicycle and bicycle-pedestrian paths. This thesis investigated the state of BLOS capacity methods that use bicycle volumes as a variable. The existing methods were applied to bicycle facility elements along a corridor that experiences high bicycle volumes in Portland, Oregon. Using data from the study corridor, BLOS was calculated and a sensitivity analysis was applied to each of the methods to determine how sensitive the models are to each of the variables used. An intercept survey was conducted to compare the BLOS capacity scores calculated for the corridor with the users' perception. In addition, 2030 bicycle mode share for the study corridor was estimated and the implications of increased future bicycle congestion were discussed. Gaps in the BLOS methods, limitations of the thesis study and future research were summarized. In general, the existing methods for BLOS capacity are intended for separated paths; they are not appropriate for existing high traffic flow facilities. Most of the BLOS traffic flow methods that have been developed are most sensitive to bicycle volumes. Some of these models may be a good starting point to improve BLOS capacity and traffic flow measures for high bicycle volume locations. Without the tools to measure and evaluate the patterns of bicycle capacity and traffic flow, it will be difficult to monitor and mitigate bicycle congestion and to plan for efficient bicycle facilities in the future. This report concludes that it is now time to develop new BLOS capacity measures that address bicycle traffic flow. Title: Bicycle Level of Service: Where are the Gaps in Bicycle Flow Measures? Author: Johnson, Pamela Christine Year: 2014 Bicycle use is increasing in many parts of the U.S. Local and regional governments have set ambitious bicycle mode share goals as part of their strategy to curb greenhouse gas emissions and relieve traffic congestion. In particular, Portland, Oregon has set a 25% mode share goal for 2030 (PBOT 2010). Currently bicycle mode share in Portland is 6.1% of all trips. Other cities and regional planning organizations are also setting ambitious bicycle mode share goals and increasing bicycle facilities and programs to encourage bicycling. Increases in bicycle mode share are being encouraged to increase. However, cities with higher-than-average bicycle mode share are beginning to experience locations with bicycle traffic congestion, especially during peak commute hours. Today, there are no established methods are used to describe or measure bicycle traffic flows. In the 1960s, the Highway Capacity Manual (HCM) introduced Level of Service (LOS) measurements to describe traffic flow and capacity of motor vehicles on highways using an A-to-F grading system; "A" describes free flow traffic with no maneuvering constraints for the driver and an "F" grade corresponds to over capacity situations in which traffic flow breaks down or becomes "jammed". LOS metrics were expanded to highway and road facilities, operations and design. In the 1990s, the HCM introduced LOS measurements for transit, pedestrians, and bicycles. Today, there are many well established and emerging bicycle level of service (BLOS) methods that measure the stress, comfort and perception of safety of bicycle facilities. However, it was been assumed that bicycle traffic volumes are low and do not warrant the use of a LOS measure for bicycle capacity and traffic flow. There are few BLOS methods that take bicycle flow into consideration, except for in the case of separated bicycle and bicycle-pedestrian paths. This thesis investigated the state of BLOS capacity methods that use bicycle volumes as a variable. The existing methods were applied to bicycle facility elements along a corridor that experiences high bicycle volumes in Portland, Oregon. Using data from the study corridor, BLOS was calculated and a sensitivity analysis was applied to each of the methods to determine how sensitive the models are to each of the variables used. An intercept survey was conducted to compare the BLOS capacity scores calculated for the corridor with the users' perception. In addition, 2030 bicycle mode share for the study corridor was estimated and the implications of increased future bicycle congestion were discussed. Gaps in the BLOS methods, limitations of the thesis study and future research were summarized. In general, the existing methods for BLOS capacity are intended for separated paths; they are not appropriate for existing high traffic flow facilities. Most of the BLOS traffic flow methods that have been developed are most sensitive to bicycle volumes. Some of these models may be a good starting point to improve BLOS capacity and traffic flow measures for high bicycle volume locations. Without the tools to measure and evaluate the patterns of bicycle capacity and traffic flow, it will be difficult to monitor and mitigate bicycle congestion and to plan for efficient bicycle facilities in the future. This report concludes that it is now time to develop new BLOS capacity measures that address bicycle traffic flow. Close

• 2. [Article] Variation in Green Roof Storage Capacity, Associated Drivers, and Implications for Stormwater Management in Portland, Oregon

  Greens roofs, also known as ecoroofs or living roofs, provide numerous ecosystem services and are becoming widely integrated into urban stormwater management systems. Despite a long and robust history ...

  Citation × Citation Citation Abstract Copy Title: Variation in Green Roof Storage Capacity, Associated Drivers, and Implications for Stormwater Management in Portland, Oregon Author: Estrella, Melecio Year: 2016 Greens roofs, also known as ecoroofs or living roofs, provide numerous ecosystem services and are becoming widely integrated into urban stormwater management systems. Despite a long and robust history of green roof projects in Portland, Oregon, there is a distinct lack of research on in situ performance. This thesis addressed this gap by investigating the hydrologic performance of five green roofs in Portland for a time period spanning November through February. Despite difficulty with the sensor calibrations, our analysis of moisture content data from these roofs revealed variation in: (1) total evapotranspiration, which serves as a proxy for total stormwater retention, and (2) storage capacity, which was defined as the difference between average maximum and minimum substrate volumetric water content measured under field conditions. Evapotranspiration was predicted by storage capacity following first order growth using non-linear regression analysis, suggesting that increasing storage capacity should correspond with increases in evapotranspiration and retention up until an inflection point of possibly 8-9mm beyond which the effect diminishes. Storage capacity was further shown to be correlated with substrate properties such as organic matter content and coefficient of curvature. Finally, retention values of 13.4% - 32.8% for Portland’s rainy season in 2015-2016 were found to be substantially lower than optimal annual values reported in other studies in Portland as well as cities around the world. This suggests that Portland’s green roofs may not perform as well as expected during months of high precipitation, which are the times when hydrologic performance is most critical. Further research should consider seasonal green roof performance in the Pacific Northwest and also revisit storage capacity as a parameter to include in future design standards. Title: Variation in Green Roof Storage Capacity, Associated Drivers, and Implications for Stormwater Management in Portland, Oregon Author: Estrella, Melecio Year: 2016 Greens roofs, also known as ecoroofs or living roofs, provide numerous ecosystem services and are becoming widely integrated into urban stormwater management systems. Despite a long and robust history of green roof projects in Portland, Oregon, there is a distinct lack of research on in situ performance. This thesis addressed this gap by investigating the hydrologic performance of five green roofs in Portland for a time period spanning November through February. Despite difficulty with the sensor calibrations, our analysis of moisture content data from these roofs revealed variation in: (1) total evapotranspiration, which serves as a proxy for total stormwater retention, and (2) storage capacity, which was defined as the difference between average maximum and minimum substrate volumetric water content measured under field conditions. Evapotranspiration was predicted by storage capacity following first order growth using non-linear regression analysis, suggesting that increasing storage capacity should correspond with increases in evapotranspiration and retention up until an inflection point of possibly 8-9mm beyond which the effect diminishes. Storage capacity was further shown to be correlated with substrate properties such as organic matter content and coefficient of curvature. Finally, retention values of 13.4% - 32.8% for Portland’s rainy season in 2015-2016 were found to be substantially lower than optimal annual values reported in other studies in Portland as well as cities around the world. This suggests that Portland’s green roofs may not perform as well as expected during months of high precipitation, which are the times when hydrologic performance is most critical. Further research should consider seasonal green roof performance in the Pacific Northwest and also revisit storage capacity as a parameter to include in future design standards. Close

• 3. [Article] Determining the Power and Energy Capacities of a Battery Energy Storage System to Accommodate High Photovoltaic Penetration on a Distribution Feeder

  The integration of distributed energy generation systems has begun to impact the operation of distribution feeders within the balancing areas of numerous electrical utilities. Battery energy storage systems ...

  Citation × Citation Citation Abstract Copy Title: Determining the Power and Energy Capacities of a Battery Energy Storage System to Accommodate High Photovoltaic Penetration on a Distribution Feeder Author: Bass, Robert B., Carr, Jennifer, Aguilar, José, Whitener, Kevin Year: 2016 The integration of distributed energy generation systems has begun to impact the operation of distribution feeders within the balancing areas of numerous electrical utilities. Battery energy storage systems may be used to facilitate greater integration of renewable energy generation. This paper describes a method for determining the power and energy capacities a battery energy storage system would need in order to accommodate a particular photovoltaic penetration level within a distribution feeder, or conversely, the amount of photovoltaic that could be installed on a feeder with a minimal investment in power and energy battery energy storage system (BESS) capacities. This method determines the BESS capacities required to compensate both intra-hour and inter-hour load and photovoltaic fluctuations to achieve a flat feeder power profile. By managing the feeder power, the voltage drop along the length of feeder may be managed, thereby mitigating the voltage fluctuation induced by the stochastic nature of both renewables generation and load. Doing so facilitates system benefits, such as conservation voltage reduction, fewer operations of load tap changers, and voltage regulators, and allows for deferment of capital expenditures. Title: Determining the Power and Energy Capacities of a Battery Energy Storage System to Accommodate High Photovoltaic Penetration on a Distribution Feeder Author: Bass, Robert B., Carr, Jennifer, Aguilar, José, Whitener, Kevin Year: 2016 The integration of distributed energy generation systems has begun to impact the operation of distribution feeders within the balancing areas of numerous electrical utilities. Battery energy storage systems may be used to facilitate greater integration of renewable energy generation. This paper describes a method for determining the power and energy capacities a battery energy storage system would need in order to accommodate a particular photovoltaic penetration level within a distribution feeder, or conversely, the amount of photovoltaic that could be installed on a feeder with a minimal investment in power and energy battery energy storage system (BESS) capacities. This method determines the BESS capacities required to compensate both intra-hour and inter-hour load and photovoltaic fluctuations to achieve a flat feeder power profile. By managing the feeder power, the voltage drop along the length of feeder may be managed, thereby mitigating the voltage fluctuation induced by the stochastic nature of both renewables generation and load. Doing so facilitates system benefits, such as conservation voltage reduction, fewer operations of load tap changers, and voltage regulators, and allows for deferment of capital expenditures. Close

• 4. [Article] Prussian Green: A High Rate Capacity Cathode for Potassium Ion Batteries

  The influence of the precursors, namely potassium ferrocyanide and potassium ferricyanide on the particles sizes of Prussian Blue (PB) and Prussian Green (PG), under identical reaction conditions have ...

  Citation × Citation Citation Abstract Copy Title: Prussian Green: A High Rate Capacity Cathode for Potassium Ion Batteries Author: Pradigi, Prasanna, Thiebes, Joseph, Swan, Mitchell, Goncher, Gary, Evans, David, Solanki, Raj Year: 2015 The influence of the precursors, namely potassium ferrocyanide and potassium ferricyanide on the particles sizes of Prussian Blue (PB) and Prussian Green (PG), under identical reaction conditions have been investigated. It was found that the particle sizes influence the gravimetric capacity utilization of these materials as cathodes for aqueous potassium (K+ ) ion batteries. The PG particle sizes were on the order of 50-75 nm, whereas PB particles size were on the order of 2-10 microns. The PG cathodes demonstrated a reversible capacity of 121.4 mAhr/g, with a coulombic efficiency of 98.7% compared to PB cathodes which demonstrated 53.8 mAhr/g, with a coulombic efficiency of 100%. We interpret the increased capacity of PG batteries relative to PB batteries as being a result of the smaller particle size of PG, which results in greater accessibility of the cathode to K+ ions. Title: Prussian Green: A High Rate Capacity Cathode for Potassium Ion Batteries Author: Pradigi, Prasanna, Thiebes, Joseph, Swan, Mitchell, Goncher, Gary, Evans, David, Solanki, Raj Year: 2015 The influence of the precursors, namely potassium ferrocyanide and potassium ferricyanide on the particles sizes of Prussian Blue (PB) and Prussian Green (PG), under identical reaction conditions have been investigated. It was found that the particle sizes influence the gravimetric capacity utilization of these materials as cathodes for aqueous potassium (K+ ) ion batteries. The PG particle sizes were on the order of 50-75 nm, whereas PB particles size were on the order of 2-10 microns. The PG cathodes demonstrated a reversible capacity of 121.4 mAhr/g, with a coulombic efficiency of 98.7% compared to PB cathodes which demonstrated 53.8 mAhr/g, with a coulombic efficiency of 100%. We interpret the increased capacity of PG batteries relative to PB batteries as being a result of the smaller particle size of PG, which results in greater accessibility of the cathode to K+ ions. Close

• 5. [Article] Determining the Power and Energy Capacity of a Battery Energy Storage System Utilizing a Smoothing Feeder Profile to Accommodate High Photovoltaic Penetration on a Distribution Feeder

  Electricity is a perishable commodity; once it is generated it needs to be consumed or stored. Electric energy storage provides both power and energy capacity. Power capacity applications reduce the need ...

  Citation × Citation Citation Abstract Copy Title: Determining the Power and Energy Capacity of a Battery Energy Storage System Utilizing a Smoothing Feeder Profile to Accommodate High Photovoltaic Penetration on a Distribution Feeder Author: Mansour, Osama Mohammed Abbas Aly Year: 2016 Electricity is a perishable commodity; once it is generated it needs to be consumed or stored. Electric energy storage provides both power and energy capacity. Power capacity applications reduce the need for generation, while energy capacity allows for energy consumption to be decoupled from generation. Previous research was done to develop an algorithm for determining the power (MW) and energy (MWh) capacities of a battery energy storage system (BESS) to mitigate the adverse impacts of high levels of photovoltaic (PV) generation. The algorithm used a flat feeder profile, and its performance was demonstrated on the equinoxes and solstices. Managing feeder power leads to fewer voltage fluctuations along the length of the feeder, potentially mitigating load management issues caused by variability of renewable generation and load profile. These issues include lighting flicker, compressor seizing, equipment shut-off, loss of motor torque, frequent transformer tap changes and even voltage collapse due to loss of reactive power support. The research described in this thesis builds on this algorithm by incorporating a smoothed feeder profile and testing it over an entire year. Incorporating a smoothing function reduces the requisite BESS energy capacity necessary to provide firming and shaping to accommodate the stochastic nature of PV. Specifically, this method is used to conduct a year-long study on a per second basis, as well as a one-minute basis, for a distribution feeder. Statistical analytical methods were performed to develop recommendations for appropriately sizing the BESS. This method may be used to determine the amount of PV generation that could be installed on a distribution feeder with a minimal investment in the BESS power and energy capacities that would be required to manage the distribution feeder power. Results are presented for PV penetration levels of 10%-50% of the distribution feeder capacity and show that the use of a smooth feeder profile reduces the required energy capacity by a minimum factor of 10 when compared to a flat feeder profile. Results indicated that it is sufficient to have a one-minute sampling rate, as it provides the necessary granularity to model cloud-induced fluctuations. This method can be applied to any distribution feeder where a load profile and a PV profile are available. Title: Determining the Power and Energy Capacity of a Battery Energy Storage System Utilizing a Smoothing Feeder Profile to Accommodate High Photovoltaic Penetration on a Distribution Feeder Author: Mansour, Osama Mohammed Abbas Aly Year: 2016 Electricity is a perishable commodity; once it is generated it needs to be consumed or stored. Electric energy storage provides both power and energy capacity. Power capacity applications reduce the need for generation, while energy capacity allows for energy consumption to be decoupled from generation. Previous research was done to develop an algorithm for determining the power (MW) and energy (MWh) capacities of a battery energy storage system (BESS) to mitigate the adverse impacts of high levels of photovoltaic (PV) generation. The algorithm used a flat feeder profile, and its performance was demonstrated on the equinoxes and solstices. Managing feeder power leads to fewer voltage fluctuations along the length of the feeder, potentially mitigating load management issues caused by variability of renewable generation and load profile. These issues include lighting flicker, compressor seizing, equipment shut-off, loss of motor torque, frequent transformer tap changes and even voltage collapse due to loss of reactive power support. The research described in this thesis builds on this algorithm by incorporating a smoothed feeder profile and testing it over an entire year. Incorporating a smoothing function reduces the requisite BESS energy capacity necessary to provide firming and shaping to accommodate the stochastic nature of PV. Specifically, this method is used to conduct a year-long study on a per second basis, as well as a one-minute basis, for a distribution feeder. Statistical analytical methods were performed to develop recommendations for appropriately sizing the BESS. This method may be used to determine the amount of PV generation that could be installed on a distribution feeder with a minimal investment in the BESS power and energy capacities that would be required to manage the distribution feeder power. Results are presented for PV penetration levels of 10%-50% of the distribution feeder capacity and show that the use of a smooth feeder profile reduces the required energy capacity by a minimum factor of 10 when compared to a flat feeder profile. Results indicated that it is sufficient to have a one-minute sampling rate, as it provides the necessary granularity to model cloud-induced fluctuations. This method can be applied to any distribution feeder where a load profile and a PV profile are available. Close

• 6. [Article] Organizational Change and Racial Equity: Implications for Capacity-Building Practice for Organizations and Networks

  The changing environment both locally and nationally has heightened the need of nonprofit leadership and organizations to address issues of racial and ethnic disparities with more equitable systems and ...

  Citation × Citation Citation Abstract Copy Title: Organizational Change and Racial Equity: Implications for Capacity-Building Practice for Organizations and Networks Author: Hill, Curdina, Curry-Stevens, Ann Year: 2016 The changing environment both locally and nationally has heightened the need of nonprofit leadership and organizations to address issues of racial and ethnic disparities with more equitable systems and practice. This article examines the research on nonprofit organizational change through a racial equity lens and looks at implications for nonprofit capacity builders in using this research to create more effective long-term change. Title: Organizational Change and Racial Equity: Implications for Capacity-Building Practice for Organizations and Networks Author: Hill, Curdina, Curry-Stevens, Ann Year: 2016 The changing environment both locally and nationally has heightened the need of nonprofit leadership and organizations to address issues of racial and ethnic disparities with more equitable systems and practice. This article examines the research on nonprofit organizational change through a racial equity lens and looks at implications for nonprofit capacity builders in using this research to create more effective long-term change. Close

• 7. [Article] Impact Analysis of Increased Dispatchable Resources on a Utility Feeder in OpenDSS

  Oregon utilities are replacing their portfolios of traditional fossil fuel generation with renewable generating sources. Stepping away from carbon-producing energy will leave a deficit of on-demand power, ...

  Citation × Citation Citation Abstract Copy Title: Impact Analysis of Increased Dispatchable Resources on a Utility Feeder in OpenDSS Author: Eppinger, Crystal Year: 2017 Oregon utilities are replacing their portfolios of traditional fossil fuel generation with renewable generating sources. Stepping away from carbon-producing energy will leave a deficit of on-demand power, resulting in decreased reliability. To overcome these technical challenges, utilities must maximize the use of their present dispatchable resources. One such resource is the Portland General Electric (PGE) Dispatchable Standby Generation Program (DSG), which is an aggregated 105 MWs of distributed generation (DG). These resources are brought on-line when there is a critical need for power. Resources are added to the program if a transfer trip scheme is in place or a modeling study reveals that the feeder load is at least three times the generator capacity. If the load-to-capacity ratio were lower, more assets could be added to the DSG program. To investigate the impacts of lowering the DG load-to-capacity ratio on existing distribution feeders, we use Open-Source Distribution System Simulator (OpenDSS). We modeled the Oxford Rural feeder by converting a utility CYME database to instantiation files using several MATLAB programs. A MATLAB control program varies the load-to-capacity ratio of the OpenDSS feeder model and monitors the generator behavior immediately following a fault. We analyzed the results to determine the ideal load-to-capacity ratio that prevents unintentional islanding. The results show that the instantaneous (50) relay element settings dictate both the minimum load-to-capacity ratio and the maximum DG capacity. The present three-to-one ratio is very conservative and can be reduced. Additional dispatchable resources include a five MW battery-inverter system currently used as grid-back up. The battery is grid-tied to a 12.4 kV feeder making it an ideal candidate for conservation voltage reduction (CVR). Using the same feeder model, we investigated the effects of lowering the system voltage to the allowable minimum using injections of reactive power. A lower system voltage reduces the load at peak times. Conversely, increasing the voltage prevents generation conflicts. To determine the benefit of CVR by VAr-injection on the Oxford Rural feeder, we created a MATLAB optimization program to output the optimal feeder voltage for reduced system power. We use a Simulink feedback model to determine the appropriate reactive power needed to achieve the voltage change. We analyze the system model to reveal that the feeder is ideal for CVR but the system capacity must be increased to achieve the maximum power reduction. Title: Impact Analysis of Increased Dispatchable Resources on a Utility Feeder in OpenDSS Author: Eppinger, Crystal Year: 2017 Oregon utilities are replacing their portfolios of traditional fossil fuel generation with renewable generating sources. Stepping away from carbon-producing energy will leave a deficit of on-demand power, resulting in decreased reliability. To overcome these technical challenges, utilities must maximize the use of their present dispatchable resources. One such resource is the Portland General Electric (PGE) Dispatchable Standby Generation Program (DSG), which is an aggregated 105 MWs of distributed generation (DG). These resources are brought on-line when there is a critical need for power. Resources are added to the program if a transfer trip scheme is in place or a modeling study reveals that the feeder load is at least three times the generator capacity. If the load-to-capacity ratio were lower, more assets could be added to the DSG program. To investigate the impacts of lowering the DG load-to-capacity ratio on existing distribution feeders, we use Open-Source Distribution System Simulator (OpenDSS). We modeled the Oxford Rural feeder by converting a utility CYME database to instantiation files using several MATLAB programs. A MATLAB control program varies the load-to-capacity ratio of the OpenDSS feeder model and monitors the generator behavior immediately following a fault. We analyzed the results to determine the ideal load-to-capacity ratio that prevents unintentional islanding. The results show that the instantaneous (50) relay element settings dictate both the minimum load-to-capacity ratio and the maximum DG capacity. The present three-to-one ratio is very conservative and can be reduced. Additional dispatchable resources include a five MW battery-inverter system currently used as grid-back up. The battery is grid-tied to a 12.4 kV feeder making it an ideal candidate for conservation voltage reduction (CVR). Using the same feeder model, we investigated the effects of lowering the system voltage to the allowable minimum using injections of reactive power. A lower system voltage reduces the load at peak times. Conversely, increasing the voltage prevents generation conflicts. To determine the benefit of CVR by VAr-injection on the Oxford Rural feeder, we created a MATLAB optimization program to output the optimal feeder voltage for reduced system power. We use a Simulink feedback model to determine the appropriate reactive power needed to achieve the voltage change. We analyze the system model to reveal that the feeder is ideal for CVR but the system capacity must be increased to achieve the maximum power reduction. Close

• 8. [Article] Computational Capacity and Energy Consumption of Complex Resistive Switch Networks

  Resistive switches are a class of emerging nanoelectronics devices that exhibit a wide variety of switching characteristics closely resembling behaviors of biological synapses. Assembled into random networks, ...

  Citation × Citation Citation Abstract Copy Title: Computational Capacity and Energy Consumption of Complex Resistive Switch Networks Author: Bürger, Jens, Goudarzi, Alireza, Stefanovic, Darko, Teuscher, Christof Year: 2015 Resistive switches are a class of emerging nanoelectronics devices that exhibit a wide variety of switching characteristics closely resembling behaviors of biological synapses. Assembled into random networks, such resistive switches produce emerging behaviors far more complex than that of individual devices. This was previously demonstrated in simulations that exploit information processing within these random networks to solve tasks that require nonlinear computation as well as memory. Physical assemblies of such networks manifest complex spatial structures and basic processing capabilities often related to biologically-inspired computing. We model and simulate random resistive switch networks and analyze their computational capacities. We provide a detailed discussion of the relevant design parameters and establish the link to the physical assemblies by relating the modeling parameters to physical parameters. More globally connected networks and an increased network switching activity are means to increase the computational capacity linearly at the expense of exponentially growing energy consumption. We discuss a new modular approach that exhibits higher computational capacities and energy consumption growing linearly with the number of networks used. The results show how to optimize the trade-off between computational capacity and energy efficiency and are relevant for the design and fabrication of novel computing architectures that harness random assemblies of emerging nanodevices. Title: Computational Capacity and Energy Consumption of Complex Resistive Switch Networks Author: Bürger, Jens, Goudarzi, Alireza, Stefanovic, Darko, Teuscher, Christof Year: 2015 Resistive switches are a class of emerging nanoelectronics devices that exhibit a wide variety of switching characteristics closely resembling behaviors of biological synapses. Assembled into random networks, such resistive switches produce emerging behaviors far more complex than that of individual devices. This was previously demonstrated in simulations that exploit information processing within these random networks to solve tasks that require nonlinear computation as well as memory. Physical assemblies of such networks manifest complex spatial structures and basic processing capabilities often related to biologically-inspired computing. We model and simulate random resistive switch networks and analyze their computational capacities. We provide a detailed discussion of the relevant design parameters and establish the link to the physical assemblies by relating the modeling parameters to physical parameters. More globally connected networks and an increased network switching activity are means to increase the computational capacity linearly at the expense of exponentially growing energy consumption. We discuss a new modular approach that exhibits higher computational capacities and energy consumption growing linearly with the number of networks used. The results show how to optimize the trade-off between computational capacity and energy efficiency and are relevant for the design and fabrication of novel computing architectures that harness random assemblies of emerging nanodevices. Close

• 9. [Article] Multivalent Rechargeable Batteries

  Li+ ion batteries have been the mainstay of high energy storage devices that have revolutionized the operating life time of consumer electronic devices for the past two decades. However, there is a steady ...

  Citation × Citation Citation Abstract Copy Title: Multivalent Rechargeable Batteries Author: Padigi, Sudhaprasanna Kumar Year: 2015 Li+ ion batteries have been the mainstay of high energy storage devices that have revolutionized the operating life time of consumer electronic devices for the past two decades. However, there is a steady increase in demand for energy storage devices with the ability to store more energy and deliver them at high power at low cost, without comprising safety and lifetime. Li-ion batteries have had significant challenges in increasing the amount of stored energy without affecting the overall lifetime and the ability to deliver stored energy. In order to store and deliver more energy, more lithium ions need to be inserted and extracted from a given electrode (cathode or anode). Upon inserting a large number of Li ions, the crystal lattice of the materials undergo severe mechanical distortions, leading to un-desirable structural changes. This results in underutilization of theoretical energy storage capacities of the electrodes and early failure of the batteries owing to instabilities in the electrode materials. Unlike monovalent Li+ ions, multivalent rechargeable batteries offer a potential solution to the above problems. Multivalent cations, such as Ca2+, are doubly-ionized as opposed to Li+ which is a monovalent cation. The advantages of using Ca2+ ions instead of Li+ ions are multifold. Due to the doubly-ionized nature, only half the number of Ca2+ ions need to be inserted and extracted from a given electrode to store and deliver energy from a high capacity cathode as compared to Li+ ions. This reduces the probability of lattice distortion and un-desirable structural changes, further leading to increased utilization of high theoretical energy storage capacities of the electrodes (cathode and anode). The use of Ca2+ ions also helps in delivering twice the amount of current density as compared to Li+ ions due to its doubly ionized nature. In this work, a set of eight metal hexacyanoferrate compounds were synthesized using the following metal ions: Ba2+, Mn2+, Zn2+, Co2+, Fe3+, Al3+, Sn4+, Mo5+. The resulting metal hexacyanoferrate compounds were subjected to physical characterization using scanning electron microscope (SEM) and powder x-ray diffraction (XRD), to determine physical properties such as size, morphology, unit cell symmetry and unit cell parameters. This was followed by electrochemical characterization utilizing cyclic voltammetry and galvanic cycling, to determine the specific capacity and kinetics involved in the transport of Ca2+ ions to store charge. Optical characterization of the metal hexacyanoferrates using Fourier transform infrared (FTIR) spectroscopy, allowed for the identification of metal-nitrogen stretching frequency, which was used as a measure of the strength of the metal-nitrogen bond to understand the role of the above mentioned metal ions in electron density distribution across the unit cell of the metal hexacyanoferrates. The specific capacity utilization of the metal hexacyanoferrates, when compared to the electronegativity values (Xi) of the above mentioned metal ions, the σ- parameter, and the metal-nitrogen stretching frequency (v), revealed an empirical trend suggesting that the materials (FeHCF, CaCoHCF and CaZnHCF) that possessed intermediates values for the above mentioned parameters demonstrated high capacity utilization (≥50%). Based on these empirical trends, it is hypothesized that a uniform distribution of electron density around a unit cell, as reflected by intermediate values of the electronegativity (Xi) of the above mentioned metal ions, the σ-parameter and the metal-nitrogen stretching frequency (v), results in minimal electrostatic interactions between the intercalating cation and the host unit cell lattice. This results in relatively easy diffusion of the cations, leading to high specific capacity utilization for metal hexacyanoferrate cathodes. These parameters may be used to select high efficiency cathode materials for multivalent batteries. Title: Multivalent Rechargeable Batteries Author: Padigi, Sudhaprasanna Kumar Year: 2015 Li+ ion batteries have been the mainstay of high energy storage devices that have revolutionized the operating life time of consumer electronic devices for the past two decades. However, there is a steady increase in demand for energy storage devices with the ability to store more energy and deliver them at high power at low cost, without comprising safety and lifetime. Li-ion batteries have had significant challenges in increasing the amount of stored energy without affecting the overall lifetime and the ability to deliver stored energy. In order to store and deliver more energy, more lithium ions need to be inserted and extracted from a given electrode (cathode or anode). Upon inserting a large number of Li ions, the crystal lattice of the materials undergo severe mechanical distortions, leading to un-desirable structural changes. This results in underutilization of theoretical energy storage capacities of the electrodes and early failure of the batteries owing to instabilities in the electrode materials. Unlike monovalent Li+ ions, multivalent rechargeable batteries offer a potential solution to the above problems. Multivalent cations, such as Ca2+, are doubly-ionized as opposed to Li+ which is a monovalent cation. The advantages of using Ca2+ ions instead of Li+ ions are multifold. Due to the doubly-ionized nature, only half the number of Ca2+ ions need to be inserted and extracted from a given electrode to store and deliver energy from a high capacity cathode as compared to Li+ ions. This reduces the probability of lattice distortion and un-desirable structural changes, further leading to increased utilization of high theoretical energy storage capacities of the electrodes (cathode and anode). The use of Ca2+ ions also helps in delivering twice the amount of current density as compared to Li+ ions due to its doubly ionized nature. In this work, a set of eight metal hexacyanoferrate compounds were synthesized using the following metal ions: Ba2+, Mn2+, Zn2+, Co2+, Fe3+, Al3+, Sn4+, Mo5+. The resulting metal hexacyanoferrate compounds were subjected to physical characterization using scanning electron microscope (SEM) and powder x-ray diffraction (XRD), to determine physical properties such as size, morphology, unit cell symmetry and unit cell parameters. This was followed by electrochemical characterization utilizing cyclic voltammetry and galvanic cycling, to determine the specific capacity and kinetics involved in the transport of Ca2+ ions to store charge. Optical characterization of the metal hexacyanoferrates using Fourier transform infrared (FTIR) spectroscopy, allowed for the identification of metal-nitrogen stretching frequency, which was used as a measure of the strength of the metal-nitrogen bond to understand the role of the above mentioned metal ions in electron density distribution across the unit cell of the metal hexacyanoferrates. The specific capacity utilization of the metal hexacyanoferrates, when compared to the electronegativity values (Xi) of the above mentioned metal ions, the σ- parameter, and the metal-nitrogen stretching frequency (v), revealed an empirical trend suggesting that the materials (FeHCF, CaCoHCF and CaZnHCF) that possessed intermediates values for the above mentioned parameters demonstrated high capacity utilization (≥50%). Based on these empirical trends, it is hypothesized that a uniform distribution of electron density around a unit cell, as reflected by intermediate values of the electronegativity (Xi) of the above mentioned metal ions, the σ-parameter and the metal-nitrogen stretching frequency (v), results in minimal electrostatic interactions between the intercalating cation and the host unit cell lattice. This results in relatively easy diffusion of the cations, leading to high specific capacity utilization for metal hexacyanoferrate cathodes. These parameters may be used to select high efficiency cathode materials for multivalent batteries. Close

• 10. [Article] High Performance Prussian Blue Cathode for Nonaqueous Ca-ion Intercalation Battery

  Potassium iron hexacyanoferrate, or Prussian blue (PB), is investigated as a cathode material for nonaqueous divalent calcium ion batteries. PB is an attractive prospect due to its high specific capacity, ...

  Citation × Citation Citation Abstract Copy Title: High Performance Prussian Blue Cathode for Nonaqueous Ca-ion Intercalation Battery Author: Kuperman, Neal, Padigi, Prasanna, Goncher, Gary, Evans, David, Thiebes, Joseph, Solanki, Raj Year: 2017 Potassium iron hexacyanoferrate, or Prussian blue (PB), is investigated as a cathode material for nonaqueous divalent calcium ion batteries. PB is an attractive prospect due to its high specific capacity, nontoxicity, low cost, and simple synthesis. Charge/discharge performances are examined at current densities of 23 mAg−1, 45 mAg−1, 90 mAg−1, and 125 mAg−1 that produced reversible specific capacities ranging from 150 mAhg−1 (at 23 mAg−1 current density) to over 120 mAhg−1 (at 125 mAg−1 current density). These are the highest storage capacities to date for a divalent calcium ion cathode over extended period of charge/discharge cycling and are comparable in performance to monovalent intercalating ions. Title: High Performance Prussian Blue Cathode for Nonaqueous Ca-ion Intercalation Battery Author: Kuperman, Neal, Padigi, Prasanna, Goncher, Gary, Evans, David, Thiebes, Joseph, Solanki, Raj Year: 2017 Potassium iron hexacyanoferrate, or Prussian blue (PB), is investigated as a cathode material for nonaqueous divalent calcium ion batteries. PB is an attractive prospect due to its high specific capacity, nontoxicity, low cost, and simple synthesis. Charge/discharge performances are examined at current densities of 23 mAg−1, 45 mAg−1, 90 mAg−1, and 125 mAg−1 that produced reversible specific capacities ranging from 150 mAhg−1 (at 23 mAg−1 current density) to over 120 mAhg−1 (at 125 mAg−1 current density). These are the highest storage capacities to date for a divalent calcium ion cathode over extended period of charge/discharge cycling and are comparable in performance to monovalent intercalating ions. Close