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• 1. [Article] Estimation of Transient Temperature Distribution during Quenching, via a Parabolic Model

  A material-independent model to estimate the transient temperature distribution in a test probe quenched by immersion is presented in this study. This model is based on the assumption that, under one-dimensional ...

  Citation × Citation Citation Abstract Copy Title: Estimation of Transient Temperature Distribution during Quenching, via a Parabolic Model Author: Lozano, Diego E., Martinez-Solis, Gabriela, Mercado-Solis, Rafael David, Colás, Rafael, Totten, George E. Year: 2015 A material-independent model to estimate the transient temperature distribution in a test probe quenched by immersion is presented in this study. This model is based on the assumption that, under one-dimensional unsteady heat conduction, the radial temperature distribution at the end of an interval belongs to the equation of a parabola. The model was validated using AISI 304 stainless steel test probes (Φ8×40 mm and Φ12×60 mm) quenched from 850 to 900 °C in water and in water-based NaNO2 solutions at 25 °C and in canola oil at 50 °C. Additionally, square test probes (20×20×100 mm) were quenched from 550 °C in water. The test probes were equipped with embedded thermocouples for temperature-versus-time data logging at the core, one-quarter thickness and 1 mm below the surface. In each experiment, the data recordings from the core and near-surface thermocouples were employed for the temperature calculations while the data from the one-quarter thickness thermocouple were employed for model validity verifications. In all cases, the calculated temperature distributions showed good correlations with the experimentally obtained values. Based on the results of this work, it is concluded that this approach constitutes a simple, quick and efficient tool for estimating transient surface and radial temperature distributions and represents a useful resource for quenchant cooling rate calculations and heat transfer characterizations. Title: Estimation of Transient Temperature Distribution during Quenching, via a Parabolic Model Author: Lozano, Diego E., Martinez-Solis, Gabriela, Mercado-Solis, Rafael David, Colás, Rafael, Totten, George E. Year: 2015 A material-independent model to estimate the transient temperature distribution in a test probe quenched by immersion is presented in this study. This model is based on the assumption that, under one-dimensional unsteady heat conduction, the radial temperature distribution at the end of an interval belongs to the equation of a parabola. The model was validated using AISI 304 stainless steel test probes (Φ8×40 mm and Φ12×60 mm) quenched from 850 to 900 °C in water and in water-based NaNO2 solutions at 25 °C and in canola oil at 50 °C. Additionally, square test probes (20×20×100 mm) were quenched from 550 °C in water. The test probes were equipped with embedded thermocouples for temperature-versus-time data logging at the core, one-quarter thickness and 1 mm below the surface. In each experiment, the data recordings from the core and near-surface thermocouples were employed for the temperature calculations while the data from the one-quarter thickness thermocouple were employed for model validity verifications. In all cases, the calculated temperature distributions showed good correlations with the experimentally obtained values. Based on the results of this work, it is concluded that this approach constitutes a simple, quick and efficient tool for estimating transient surface and radial temperature distributions and represents a useful resource for quenchant cooling rate calculations and heat transfer characterizations. Close

• 2. [Article] Long-Term Stability of 14YT-4Sc Alloy at High Temperature

  14YT alloy (Fe-14Cr-0.25wt.%Y2O3-0.4wt.%Ti) with 4 at.% Sc addition was previously reported to exhibit a nanoscale microstructure and high strength when annealed at temperatures up to 1000 °C (0.65Tm) ...

  Citation × Citation Citation Abstract Copy Title: Long-Term Stability of 14YT-4Sc Alloy at High Temperature Author: Li, Lulu, Xu, Weizong, Saber, Mostafa, Zhu, Yuntian, Koch, Carl C., Scattergood, Ronald O. Year: 2015 14YT alloy (Fe-14Cr-0.25wt.%Y2O3-0.4wt.%Ti) with 4 at.% Sc addition was previously reported to exhibit a nanoscale microstructure and high strength when annealed at temperatures up to 1000 °C (0.65Tm) for 1 hour. Here we report that the microstructure and mechanical behavior of 14YT-4Sc alloy after long-term annealing for up to 60 hours at 1000 °C. FIB analysis shows abnormal grain growth with annealing time, while a large fraction of the matrix still consists of nanoscale grains. TEM images reveal a slight growth of nano grains, with estimated grain growth exponent, n, to be 0.29. Sc-Ti-Y-O enriched nano oxide particles (nm) were observed in EDS mapping of the 14YT-4Sc-60h sample. The nano-structure retention at the high temperature of 1000 °C for 60 hours is attributed to these complex nano oxides. Title: Long-Term Stability of 14YT-4Sc Alloy at High Temperature Author: Li, Lulu, Xu, Weizong, Saber, Mostafa, Zhu, Yuntian, Koch, Carl C., Scattergood, Ronald O. Year: 2015 14YT alloy (Fe-14Cr-0.25wt.%Y2O3-0.4wt.%Ti) with 4 at.% Sc addition was previously reported to exhibit a nanoscale microstructure and high strength when annealed at temperatures up to 1000 °C (0.65Tm) for 1 hour. Here we report that the microstructure and mechanical behavior of 14YT-4Sc alloy after long-term annealing for up to 60 hours at 1000 °C. FIB analysis shows abnormal grain growth with annealing time, while a large fraction of the matrix still consists of nanoscale grains. TEM images reveal a slight growth of nano grains, with estimated grain growth exponent, n, to be 0.29. Sc-Ti-Y-O enriched nano oxide particles (nm) were observed in EDS mapping of the 14YT-4Sc-60h sample. The nano-structure retention at the high temperature of 1000 °C for 60 hours is attributed to these complex nano oxides. Close

• 3. [Article] Influence of Scandium Addition on the High-Temperature Grain Size Stabilization of Oxide-Dispersion-Strengthened (ODS) Ferritic Alloy

  The influence of 1–4 at% Sc addition on the thermal stability of mechanically alloyed ODS ferritic alloy was studied in this work. Sc addition was found to significantly stabilize grain size and microhardness ...

  Citation × Citation Citation Abstract Copy Title: Influence of Scandium Addition on the High-Temperature Grain Size Stabilization of Oxide-Dispersion-Strengthened (ODS) Ferritic Alloy Author: Li, Lulu, Xu, Weizong, Saber, Mostafa, Zhu, Yuntian, Koch, Carl C., Scattergood, Ronald O. Year: 2015 The influence of 1–4 at% Sc addition on the thermal stability of mechanically alloyed ODS ferritic alloy was studied in this work. Sc addition was found to significantly stabilize grain size and microhardness at high temperatures. Grain sizes of samples with 1 and 4 at% Sc was found maintained in the nanoscale range at temperatures up to 1000 °C with hardness maintained at 5.6 and 6.7 GPa, respectively. The detailed microstructure was also investigated from EDS elemental mapping, where nanofeatures [ScTiO] were observed, while nanosized [YTiO] particles were rarely seen. This is probably due to the concentration difference between Sc and Y, leading to the formation of [ScTiO] favoring that of [YTiO]. Precipitation was considered as the major source for the observed high temperature stabilization. In addition, 14YT–Sc alloys without large second phases such as Ti-oxide can exhibit better performance compared to conventional ODS materials. Title: Influence of Scandium Addition on the High-Temperature Grain Size Stabilization of Oxide-Dispersion-Strengthened (ODS) Ferritic Alloy Author: Li, Lulu, Xu, Weizong, Saber, Mostafa, Zhu, Yuntian, Koch, Carl C., Scattergood, Ronald O. Year: 2015 The influence of 1–4 at% Sc addition on the thermal stability of mechanically alloyed ODS ferritic alloy was studied in this work. Sc addition was found to significantly stabilize grain size and microhardness at high temperatures. Grain sizes of samples with 1 and 4 at% Sc was found maintained in the nanoscale range at temperatures up to 1000 °C with hardness maintained at 5.6 and 6.7 GPa, respectively. The detailed microstructure was also investigated from EDS elemental mapping, where nanofeatures [ScTiO] were observed, while nanosized [YTiO] particles were rarely seen. This is probably due to the concentration difference between Sc and Y, leading to the formation of [ScTiO] favoring that of [YTiO]. Precipitation was considered as the major source for the observed high temperature stabilization. In addition, 14YT–Sc alloys without large second phases such as Ti-oxide can exhibit better performance compared to conventional ODS materials. Close

• 4. [Article] Effect of Oxygen Content on Thermal Stability of Grain Size for Nanocrystalline Fe10Cr and Fe14Cr4Hf Alloy Powders

  Low oxygen content powders of high purity elemental Fe, Cr and Hf were produced in a glove box by mechanically filing the solid materials. Fe10Cr and Fe14Cr4Hf nanocrystalline alloy powders were processed ...

  Citation × Citation Citation Abstract Copy Title: Effect of Oxygen Content on Thermal Stability of Grain Size for Nanocrystalline Fe10Cr and Fe14Cr4Hf Alloy Powders Author: Roodposhti, Peiman Shahbeigi, Saber, Mostafa, Koch, Carl, Scattergood, Ronald Year: 2017 Low oxygen content powders of high purity elemental Fe, Cr and Hf were produced in a glove box by mechanically filing the solid materials. Fe10Cr and Fe14Cr4Hf nanocrystalline alloy powders were processed using these elemental powders in conjunction with SPEX ball milling. The grain-size stability of the nanocrystalline alloy powders was investigated for selected annealing temperatures. High temperature stabilization can be achieved by Zener pinning (kinetic mechanism) or segregation of Hf to grain boundaries (thermodynamic mechanism). Solute drag mechanisms can be effective at lower annealing temperatures. Recent regular solution models developed by the authors predict that Hf would facilitate thermodynamic grain-size stabilization in Fe14Cr4Hf alloys at high temperatures. However Hf-base reactions such as intermetallic phase or oxide formation can favor kinetic stabilization and this can dominate over a contribution from thermodynamic stabilization. In contrast, grain-size stabilization in Fe10Cr alloy would be a result of solute drag by the Cr solutes at lower temperatures. The results from previous investigations on Fe10Cr and Fe14Cr4Hf nanocrystalline alloys were (unknowingly at the time) influenced by the fact that the commercially available high purity elemental powders used for SPEX ball mill processing contained significant amounts of oxygen impurity. The results obtained in this investigation using identical processing methods with low oxygen content powders for synthesizing the alloys provide further insight into their stabilization mechanisms. Title: Effect of Oxygen Content on Thermal Stability of Grain Size for Nanocrystalline Fe10Cr and Fe14Cr4Hf Alloy Powders Author: Roodposhti, Peiman Shahbeigi, Saber, Mostafa, Koch, Carl, Scattergood, Ronald Year: 2017 Low oxygen content powders of high purity elemental Fe, Cr and Hf were produced in a glove box by mechanically filing the solid materials. Fe10Cr and Fe14Cr4Hf nanocrystalline alloy powders were processed using these elemental powders in conjunction with SPEX ball milling. The grain-size stability of the nanocrystalline alloy powders was investigated for selected annealing temperatures. High temperature stabilization can be achieved by Zener pinning (kinetic mechanism) or segregation of Hf to grain boundaries (thermodynamic mechanism). Solute drag mechanisms can be effective at lower annealing temperatures. Recent regular solution models developed by the authors predict that Hf would facilitate thermodynamic grain-size stabilization in Fe14Cr4Hf alloys at high temperatures. However Hf-base reactions such as intermetallic phase or oxide formation can favor kinetic stabilization and this can dominate over a contribution from thermodynamic stabilization. In contrast, grain-size stabilization in Fe10Cr alloy would be a result of solute drag by the Cr solutes at lower temperatures. The results from previous investigations on Fe10Cr and Fe14Cr4Hf nanocrystalline alloys were (unknowingly at the time) influenced by the fact that the commercially available high purity elemental powders used for SPEX ball mill processing contained significant amounts of oxygen impurity. The results obtained in this investigation using identical processing methods with low oxygen content powders for synthesizing the alloys provide further insight into their stabilization mechanisms. Close

• 5. [Article] Power core (PC) Embedding a Plurality of IC Devices and Sandwiched Between Two Dissimilar Insulated Metal Substrates (IMS’): Predicted Thermal Stresses

  Power core (PC) sandwiched between two insulated metal substrates (IMS) and embedding active and passive integrated circuit (IC) devices is currently viewed as an attractive advanced packaging option having ...

  Citation × Citation Citation Abstract Copy Title: Power core (PC) Embedding a Plurality of IC Devices and Sandwiched Between Two Dissimilar Insulated Metal Substrates (IMS’): Predicted Thermal Stresses Author: Suhir, Ephraim, Nicolics, Johann Year: 2016 Power core (PC) sandwiched between two insulated metal substrates (IMS) and embedding active and passive integrated circuit (IC) devices is currently viewed as an attractive advanced packaging option having a strong potential in the automotive industry and beyond. A natural reliability concern, however, is the level of the thermally induced stresses in a tri-material assembly of the type in question. Accordingly, an analytical (mathematical) stress model is developed for the evaluation of these stresses. The stresses include normal stresses acting in the cross-sections of the assembly components, and the interfacial shearing and peeling stresses acting at the interfaces of these components and at the interfaces of the embedded IC devices. The model can be helpful in the stress-analysis and physical design of the assemblies, in which the PC is sandwiched between two IMS’. It can be used also in other areas of engineering, where tri-material assemblies comprised of dissimilar materials and subjected to the change in temperature are employed. The general concepts are illustrated by a detailed numerical example. The analysis is an extension of the study carried out earlier for a bow-free assembly. It is noteworthy that although the calculations are carried out for the case when the assembly is cooled down from an elevated temperature to a low temperature, since a linear approach is used and the stresses are proportional to the change in temperature, whatever its sign or the magnitude is, the developed model is equally applicable to any change in temperature. Title: Power core (PC) Embedding a Plurality of IC Devices and Sandwiched Between Two Dissimilar Insulated Metal Substrates (IMS’): Predicted Thermal Stresses Author: Suhir, Ephraim, Nicolics, Johann Year: 2016 Power core (PC) sandwiched between two insulated metal substrates (IMS) and embedding active and passive integrated circuit (IC) devices is currently viewed as an attractive advanced packaging option having a strong potential in the automotive industry and beyond. A natural reliability concern, however, is the level of the thermally induced stresses in a tri-material assembly of the type in question. Accordingly, an analytical (mathematical) stress model is developed for the evaluation of these stresses. The stresses include normal stresses acting in the cross-sections of the assembly components, and the interfacial shearing and peeling stresses acting at the interfaces of these components and at the interfaces of the embedded IC devices. The model can be helpful in the stress-analysis and physical design of the assemblies, in which the PC is sandwiched between two IMS’. It can be used also in other areas of engineering, where tri-material assemblies comprised of dissimilar materials and subjected to the change in temperature are employed. The general concepts are illustrated by a detailed numerical example. The analysis is an extension of the study carried out earlier for a bow-free assembly. It is noteworthy that although the calculations are carried out for the case when the assembly is cooled down from an elevated temperature to a low temperature, since a linear approach is used and the stresses are proportional to the change in temperature, whatever its sign or the magnitude is, the developed model is equally applicable to any change in temperature. Close

• 6. [Article] The Effect of Plasma on Graphene Quality in an Inductively Couple Plasma Chemical Vapor Deposition Reactor

  Despite continued interest in research and application development, full scale graphene production is still limited by many factors including prohibitively high growth temperature requirements. Extremely ...

  Citation × Citation Citation Abstract Copy Title: The Effect of Plasma on Graphene Quality in an Inductively Couple Plasma Chemical Vapor Deposition Reactor Author: Coyne, Brendan Year: 2017 Despite continued interest in research and application development, full scale graphene production is still limited by many factors including prohibitively high growth temperature requirements. Extremely high quality graphene growth is possible at high temperatures using chemical vapor deposition (CVD). Use of an inductively coupled plasma chemical vapor deposition (ICP CVD) reactor with the benefit of precursor gas decomposition through plasma generation, may provide possibility to reduce growth temperature. Herein, we report plasma’s effects on graphene growth by comparing growths of increasing power supplied to plasma generation and changes in precursor gas ratios. Plasma composition was characterized by ultraviolet and visible light spectroscopy; graphene was characterized by Raman spectroscopy. Plasma was observed to change gradually and in a threshold shift. Gradual changes in plasma resulted in changes in graphene quality, both defect density and number of layers. The shift produced sudden changes in graphene quality. Further, increasing power before and after the shift produced opposite correlated trends. Finally, reduced hydrogen to acetylene gas ratios produced plasma associated with higher powers at a higher gas ratio. Though the comparative plasma spectra between the two reduced gas ratio growths were very similar, the quality of graphene was different. Additionally, both lower gas ratio growths produced quality different than what was expected by the trends suggested by the higher gas ratio growths. Though plasma demonstrated a role in graphene quality, a more detailed understand of its driving mechanisms must be developed in conjunction with other growth mechanisms if it is to be utilized to substantially reduce growth temperature. Title: The Effect of Plasma on Graphene Quality in an Inductively Couple Plasma Chemical Vapor Deposition Reactor Author: Coyne, Brendan Year: 2017 Despite continued interest in research and application development, full scale graphene production is still limited by many factors including prohibitively high growth temperature requirements. Extremely high quality graphene growth is possible at high temperatures using chemical vapor deposition (CVD). Use of an inductively coupled plasma chemical vapor deposition (ICP CVD) reactor with the benefit of precursor gas decomposition through plasma generation, may provide possibility to reduce growth temperature. Herein, we report plasma’s effects on graphene growth by comparing growths of increasing power supplied to plasma generation and changes in precursor gas ratios. Plasma composition was characterized by ultraviolet and visible light spectroscopy; graphene was characterized by Raman spectroscopy. Plasma was observed to change gradually and in a threshold shift. Gradual changes in plasma resulted in changes in graphene quality, both defect density and number of layers. The shift produced sudden changes in graphene quality. Further, increasing power before and after the shift produced opposite correlated trends. Finally, reduced hydrogen to acetylene gas ratios produced plasma associated with higher powers at a higher gas ratio. Though the comparative plasma spectra between the two reduced gas ratio growths were very similar, the quality of graphene was different. Additionally, both lower gas ratio growths produced quality different than what was expected by the trends suggested by the higher gas ratio growths. Though plasma demonstrated a role in graphene quality, a more detailed understand of its driving mechanisms must be developed in conjunction with other growth mechanisms if it is to be utilized to substantially reduce growth temperature. Close

• 7. [Article] Constant Interface Temperature Reliability Assessment Method: An Alternative Method for Testing Thermal Interface Material in Products

  As electronic packages and their thermal solutions become more complex the reliability margins in the thermal solutions diminish and become less tolerant to errors in reliability predictions. The current ...

  Citation × Citation Citation Abstract Copy Title: Constant Interface Temperature Reliability Assessment Method: An Alternative Method for Testing Thermal Interface Material in Products Author: Amoah-Kusi, Christian Year: 2015 As electronic packages and their thermal solutions become more complex the reliability margins in the thermal solutions diminish and become less tolerant to errors in reliability predictions. The current method of thermally stress testing thermal solutions can be over or under predicting end of life thermal performance. Benefits of accurate testing and modeling are improved silicon yield in manufacturing, improved performance, lower cost thermal solutions, and shortened test times. The current method of thermally stress testing is to place the entire unit in an elevated isothermal temperature and periodically measure thermal performance. Isothermally aging is not an accurate representation of how the unit will be used by the customer and does not capture the thermal gradients and mechanical stresses due to different coefficients of thermal expansion of the materials used in the thermal solution. A new testing system, CITRAM which is an acronym for Constant Interface Temperature Reliability Method, has been developed that uses an electronic test board. The approach captures the thermal and mechanical stresses accurately and improves test time by 20-30% as a result of automation. Through this study a difference in the two methods has been identified and the new CITRAM method should be adopted as current practice. Title: Constant Interface Temperature Reliability Assessment Method: An Alternative Method for Testing Thermal Interface Material in Products Author: Amoah-Kusi, Christian Year: 2015 As electronic packages and their thermal solutions become more complex the reliability margins in the thermal solutions diminish and become less tolerant to errors in reliability predictions. The current method of thermally stress testing thermal solutions can be over or under predicting end of life thermal performance. Benefits of accurate testing and modeling are improved silicon yield in manufacturing, improved performance, lower cost thermal solutions, and shortened test times. The current method of thermally stress testing is to place the entire unit in an elevated isothermal temperature and periodically measure thermal performance. Isothermally aging is not an accurate representation of how the unit will be used by the customer and does not capture the thermal gradients and mechanical stresses due to different coefficients of thermal expansion of the materials used in the thermal solution. A new testing system, CITRAM which is an acronym for Constant Interface Temperature Reliability Method, has been developed that uses an electronic test board. The approach captures the thermal and mechanical stresses accurately and improves test time by 20-30% as a result of automation. Through this study a difference in the two methods has been identified and the new CITRAM method should be adopted as current practice. Close

• 8. [Article] Partial Decarburization and Intensive Quenching to Increase Fatigue Limit of Quenched Small Parts

  The 5160 spring steel is mainly used to endure fatigue and since its Mf is below room temperature, retained austenite is usually present after conventional quenching, which is detrimental from a fatigue ...

  Citation × Citation Citation Abstract Copy Title: Partial Decarburization and Intensive Quenching to Increase Fatigue Limit of Quenched Small Parts Author: Lozano, Diego E., Totten, George E., Martínez Cázares, Gabriela M., Mercado-Solis, Rafael David Year: 2014 The 5160 spring steel is mainly used to endure fatigue and since its Mf is below room temperature, retained austenite is usually present after conventional quenching, which is detrimental from a fatigue point of view. To reduce the amount of retained austenite, a partial decarburization was promoted (to increase the Ms and Mf, respectively) by austenitizing the steel at different temperatures and times in air, prior to performing an interrupted quenching in an accelerated media (brine) instead of the conventional oil quenching. The same quenching conditions with partial decarburization and without decarburization are compared. In addition, conventional oil quenching was performed as reference. Results showed that with a controlled partial decarburization, it is possible to increase the fatigue limit compared to the conditions without decarburization (both interrupted quenching and oil quenching). Fatigue experiments were carried out in a rotating bending fatigue type tester. Cooling curves, decarburization profiles, fraction of martensite plots, and fatigue data are discussed. Title: Partial Decarburization and Intensive Quenching to Increase Fatigue Limit of Quenched Small Parts Author: Lozano, Diego E., Totten, George E., Martínez Cázares, Gabriela M., Mercado-Solis, Rafael David Year: 2014 The 5160 spring steel is mainly used to endure fatigue and since its Mf is below room temperature, retained austenite is usually present after conventional quenching, which is detrimental from a fatigue point of view. To reduce the amount of retained austenite, a partial decarburization was promoted (to increase the Ms and Mf, respectively) by austenitizing the steel at different temperatures and times in air, prior to performing an interrupted quenching in an accelerated media (brine) instead of the conventional oil quenching. The same quenching conditions with partial decarburization and without decarburization are compared. In addition, conventional oil quenching was performed as reference. Results showed that with a controlled partial decarburization, it is possible to increase the fatigue limit compared to the conditions without decarburization (both interrupted quenching and oil quenching). Fatigue experiments were carried out in a rotating bending fatigue type tester. Cooling curves, decarburization profiles, fraction of martensite plots, and fatigue data are discussed. Close

• 9. [Article] Ozone Reaction With Interior Building Materials: Influence of Diurnal Ozone Variation, Temperature and Humidity

  Elevated tropospheric ozone concentrations are associated with increased morbidity and mortality. Indoor ozone chemistry affects human exposure to ozone and reaction products that also may adversely affect ...

  Citation × Citation Citation Abstract Copy Title: Ozone Reaction With Interior Building Materials: Influence of Diurnal Ozone Variation, Temperature and Humidity Author: Rim, Donghyun, Gall, Elliot T., Maddalena, Randy L., Nazaroff, William W. Year: 2015 Elevated tropospheric ozone concentrations are associated with increased morbidity and mortality. Indoor ozone chemistry affects human exposure to ozone and reaction products that also may adversely affect health and comfort. Reactive uptake of ozone has been characterized for many building materials; however, scant information is available on how diurnal variation of ambient ozone influences ozone reaction with indoor surfaces. The primary objective of this study is to investigate ozone-surface reactions in response to a diurnally varying ozone exposure for three common building materials: ceiling tile, painted drywall, and carpet tile. A secondary objective is to examine the effects of air temperature and humidity. A third goal is to explore how conditioning of materials in an occupied office building might influence subsequent ozone-surface reactions. Experiments were performed at bench-scale with inlet ozone concentrations varied to simulate daytime (ozone elevated) and nighttime (ozone-free in these experiments) periods. To simulate office conditions, experiments were conducted at two temperatures (22 °C and 28 °C) and three relative humidity values (25%, 50%, 75%). Effects of indoor surface exposures were examined by placing material samples in an occupied office and repeating bench-scale characterization after exposure periods of 1 and 2 months. Deposition velocities were observed to be highest during the initial hour of ozone exposure with slow decrease in the subsequent hours of simulated daytime conditions. Daily-average ozone reaction probabilities for fresh materials are in the respective ranges of (1.7–2.7) × 10−5, (2.8–4.7) × 10−5, and (3.0–4.5) × 10−5 for ceiling tile, painted drywall, and carpet tile. The reaction probability decreases by 7%–47% across the three test materials after two 8-h periods of ozone exposure. Measurements with the samples from an occupied office reveal that deposition velocity can decrease or increase with time. Influence of temperature and humidity on ozone-surface reactivity was not strong. Title: Ozone Reaction With Interior Building Materials: Influence of Diurnal Ozone Variation, Temperature and Humidity Author: Rim, Donghyun, Gall, Elliot T., Maddalena, Randy L., Nazaroff, William W. Year: 2015 Elevated tropospheric ozone concentrations are associated with increased morbidity and mortality. Indoor ozone chemistry affects human exposure to ozone and reaction products that also may adversely affect health and comfort. Reactive uptake of ozone has been characterized for many building materials; however, scant information is available on how diurnal variation of ambient ozone influences ozone reaction with indoor surfaces. The primary objective of this study is to investigate ozone-surface reactions in response to a diurnally varying ozone exposure for three common building materials: ceiling tile, painted drywall, and carpet tile. A secondary objective is to examine the effects of air temperature and humidity. A third goal is to explore how conditioning of materials in an occupied office building might influence subsequent ozone-surface reactions. Experiments were performed at bench-scale with inlet ozone concentrations varied to simulate daytime (ozone elevated) and nighttime (ozone-free in these experiments) periods. To simulate office conditions, experiments were conducted at two temperatures (22 °C and 28 °C) and three relative humidity values (25%, 50%, 75%). Effects of indoor surface exposures were examined by placing material samples in an occupied office and repeating bench-scale characterization after exposure periods of 1 and 2 months. Deposition velocities were observed to be highest during the initial hour of ozone exposure with slow decrease in the subsequent hours of simulated daytime conditions. Daily-average ozone reaction probabilities for fresh materials are in the respective ranges of (1.7–2.7) × 10−5, (2.8–4.7) × 10−5, and (3.0–4.5) × 10−5 for ceiling tile, painted drywall, and carpet tile. The reaction probability decreases by 7%–47% across the three test materials after two 8-h periods of ozone exposure. Measurements with the samples from an occupied office reveal that deposition velocity can decrease or increase with time. Influence of temperature and humidity on ozone-surface reactivity was not strong. Close

• 10. [Article] Thermal Footprint Effect of Rooftop Urban Cooling Strategies

  Simulation results indicate that urban morphology plays an important role in determining the efficacy of rooftop urban cooling strategies for improving pedestrian thermal comfort. Results suggest that ...

  Citation × Citation Citation Abstract Copy Title: Thermal Footprint Effect of Rooftop Urban Cooling Strategies Author: Botham-Myint, Dylan, Recktenwald, Gerald W., Sailor, David J. Year: 2015 Simulation results indicate that urban morphology plays an important role in determining the efficacy of rooftop urban cooling strategies for improving pedestrian thermal comfort. Results suggest that a white roof has the greatest effect on near-surface air temperatures within the urban canyon when used on buildings of 1–2 stories height and almost no near-surface effect when applied to 4 story buildings. However, the near-surface effect is more substantial when complex urban morphology introduces enhanced vertical mixing. Of the cases studied the largest near-surface cooling benefit of implementing white roofs was found for the case when a taller building existed downwind from a building with a white roof. Using the Thermal Footprint Ratio it was found that by placing a tall building behind a building with a white roof in an otherwise uniform array of 2 story buildings, the cool roof would be twice as effective at reducing air temperatures at the pedestrian level. Calculations of the volumetric heat removal confirmed this result, indicating that the positioning of the tall building downwind of the modified roof would be 2.6 times as effective at cooling the pedestrian level air volume as compared to the case where all buildings were a uniform height. Title: Thermal Footprint Effect of Rooftop Urban Cooling Strategies Author: Botham-Myint, Dylan, Recktenwald, Gerald W., Sailor, David J. Year: 2015 Simulation results indicate that urban morphology plays an important role in determining the efficacy of rooftop urban cooling strategies for improving pedestrian thermal comfort. Results suggest that a white roof has the greatest effect on near-surface air temperatures within the urban canyon when used on buildings of 1–2 stories height and almost no near-surface effect when applied to 4 story buildings. However, the near-surface effect is more substantial when complex urban morphology introduces enhanced vertical mixing. Of the cases studied the largest near-surface cooling benefit of implementing white roofs was found for the case when a taller building existed downwind from a building with a white roof. Using the Thermal Footprint Ratio it was found that by placing a tall building behind a building with a white roof in an otherwise uniform array of 2 story buildings, the cool roof would be twice as effective at reducing air temperatures at the pedestrian level. Calculations of the volumetric heat removal confirmed this result, indicating that the positioning of the tall building downwind of the modified roof would be 2.6 times as effective at cooling the pedestrian level air volume as compared to the case where all buildings were a uniform height. Close