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• 1. [Article] Dendrochronology and Middle Miocene Petrified Oak: Modern Counterparts and Interpretation

  This study reports the first successful statistical crossdating among many ring width time series from petrified wood, thus providing a replicable continuous annual resolution window into tree growth and ...

  Citation × Citation Citation Abstract Copy Title: Dendrochronology and Middle Miocene Petrified Oak: Modern Counterparts and Interpretation Author: Wright, William E., Streck, Martin J., Baisan, Christopher, Wright, W. Walton, Szejner, Paul Year: 2015 This study reports the first successful statistical crossdating among many ring width time series from petrified wood, thus providing a replicable continuous annual resolution window into tree growth and environmental influences during the middle Miocene. The petrified samples, of the genus Quercus, originated at the Stinking Water (SW) locality in Oregon, a Miocene-aged exposure associated with the Columbia River Basalts. 40AR/39AR dating on pillow basalt from the locality yielded a weighted Plateau Age of 13.79 ±0.09 Ma placing the death of the trees at the end of the Langhian Stage of the Middle Miocene (15.97±0.05 to 13.65±0.05 Ma), during the middle Miocene Climate Transition (MMCT). Ring width time series from 26 radii, 17 different trees, show significant intercorrelation. A Modified Coexistence Approach was applied to determine the likely climate range when the SW trees were growing. The modified approach included regression of site-mean ring width time series statistic values on estimated soil moisture for the site locations, using site-mean data from 126 modern Quercus sites from across the United States. Identification of highly significant linearities indicated strong relationships between ring width intercorrelation and soil moisture and ring width variability and soil moisture. Comparison of individual modern site-mean statistical values with values calculated for the SW locality suggests a mesic growing environment for the SW Quercus, with moderate temperatures. Geographic placement of modern Quercus sites with site-mean statistics similar to the SW values indicates a modern analogue in the eastern United States. Modern distributions of mesic species in the genera present at the SW locality suggest similarities with the central and southern Appalachian Mountains and the Ozark/Ouachita Mountains, indicating a mean annual temperature range of between ring width intercorrelation and soil moisture and ring width variability and soil moisture. Comparison of individual modern site-mean statistical values with values calculated for the SW locality suggests a mesic growing environment for the SW Quercus, with moderate temperatures. Geographic placement of modern Quercus sites with site-mean statistics similar to the SW values indicates a modern analogue in the eastern United States. Modern distributions of mesic species in the genera present at the SW locality suggest similarities with the central and southern Appalachian Mountains and the Ozark/Ouachita Mountains, indicating a mean annual temperature range of ≅10 ˚C to ≅ 15 ˚C and a mean annual precipitation range of ≅750 mm to ≅1200 mm when the SW Quercus were growing. Title: Dendrochronology and Middle Miocene Petrified Oak: Modern Counterparts and Interpretation Author: Wright, William E., Streck, Martin J., Baisan, Christopher, Wright, W. Walton, Szejner, Paul Year: 2015 This study reports the first successful statistical crossdating among many ring width time series from petrified wood, thus providing a replicable continuous annual resolution window into tree growth and environmental influences during the middle Miocene. The petrified samples, of the genus Quercus, originated at the Stinking Water (SW) locality in Oregon, a Miocene-aged exposure associated with the Columbia River Basalts. 40AR/39AR dating on pillow basalt from the locality yielded a weighted Plateau Age of 13.79 ±0.09 Ma placing the death of the trees at the end of the Langhian Stage of the Middle Miocene (15.97±0.05 to 13.65±0.05 Ma), during the middle Miocene Climate Transition (MMCT). Ring width time series from 26 radii, 17 different trees, show significant intercorrelation. A Modified Coexistence Approach was applied to determine the likely climate range when the SW trees were growing. The modified approach included regression of site-mean ring width time series statistic values on estimated soil moisture for the site locations, using site-mean data from 126 modern Quercus sites from across the United States. Identification of highly significant linearities indicated strong relationships between ring width intercorrelation and soil moisture and ring width variability and soil moisture. Comparison of individual modern site-mean statistical values with values calculated for the SW locality suggests a mesic growing environment for the SW Quercus, with moderate temperatures. Geographic placement of modern Quercus sites with site-mean statistics similar to the SW values indicates a modern analogue in the eastern United States. Modern distributions of mesic species in the genera present at the SW locality suggest similarities with the central and southern Appalachian Mountains and the Ozark/Ouachita Mountains, indicating a mean annual temperature range of between ring width intercorrelation and soil moisture and ring width variability and soil moisture. Comparison of individual modern site-mean statistical values with values calculated for the SW locality suggests a mesic growing environment for the SW Quercus, with moderate temperatures. Geographic placement of modern Quercus sites with site-mean statistics similar to the SW values indicates a modern analogue in the eastern United States. Modern distributions of mesic species in the genera present at the SW locality suggest similarities with the central and southern Appalachian Mountains and the Ozark/Ouachita Mountains, indicating a mean annual temperature range of ≅10 ˚C to ≅ 15 ˚C and a mean annual precipitation range of ≅750 mm to ≅1200 mm when the SW Quercus were growing. Close

• 2. [Article] Geogenic Cadmium Pollution and Potential Health Risks, With Emphasis on Black Shale

  Cadmium (Cd) is a non-essential trace element that is toxic to humans. Previous studies of Cd in the environment have primarily focused on pollution resulted from anthropogenic sources, but little is known ...

  Citation × Citation Citation Abstract Copy Title: Geogenic Cadmium Pollution and Potential Health Risks, With Emphasis on Black Shale Author: Liu, Yizhang, Xiao, Tangfu, Perkins, Robert, Zhu, Jianming, Zhu, Zhengjie, Xiong, Yan, Ning, Zengping Year: 2016 Cadmium (Cd) is a non-essential trace element that is toxic to humans. Previous studies of Cd in the environment have primarily focused on pollution resulted from anthropogenic sources, but little is known on naturally occurring sources of Cd. This paper aims to review the geochemical distribution of geogenic Cd and associated environmental risk. The source, accumulation, mobility, transportation, and health risk of Cd are discussed in a geo-environmental perspective, with an emphasis on black shale soils. Cadmium generally occurs in sulfides in black shale, and is easily released when exposed to oxygen and water. Leaching of these rocks tends to elevate Cd concentrations in aquatic systems, and may pose the potential to produce acid rock drainage (ARD) as well. Weathering of Cd-rich rocks also elevates soil Cd concentrations, and influence the geochemical species of Cd. Crops grown in these soils tend to accumulate higher Cd and threaten the food safety. Local inhabitant exposed to high geogenic Cd via food chains may experience Cd-related health risk. High Cd concentrations are observed in urine, and renal damage is also detected in Cd naturally enriched area based on low molecular weight proteins in urine. Overall, the findings in literature have provided with insights for potential health risk of Cd in areas with high Cd geochemical background levels, particular for the black shale exposed areas, more attentions should be paid on the geogenic Cd pollution, and suitable strategies of remediation and geo-environmental management for geogenic Cd pollution need further research. Title: Geogenic Cadmium Pollution and Potential Health Risks, With Emphasis on Black Shale Author: Liu, Yizhang, Xiao, Tangfu, Perkins, Robert, Zhu, Jianming, Zhu, Zhengjie, Xiong, Yan, Ning, Zengping Year: 2016 Cadmium (Cd) is a non-essential trace element that is toxic to humans. Previous studies of Cd in the environment have primarily focused on pollution resulted from anthropogenic sources, but little is known on naturally occurring sources of Cd. This paper aims to review the geochemical distribution of geogenic Cd and associated environmental risk. The source, accumulation, mobility, transportation, and health risk of Cd are discussed in a geo-environmental perspective, with an emphasis on black shale soils. Cadmium generally occurs in sulfides in black shale, and is easily released when exposed to oxygen and water. Leaching of these rocks tends to elevate Cd concentrations in aquatic systems, and may pose the potential to produce acid rock drainage (ARD) as well. Weathering of Cd-rich rocks also elevates soil Cd concentrations, and influence the geochemical species of Cd. Crops grown in these soils tend to accumulate higher Cd and threaten the food safety. Local inhabitant exposed to high geogenic Cd via food chains may experience Cd-related health risk. High Cd concentrations are observed in urine, and renal damage is also detected in Cd naturally enriched area based on low molecular weight proteins in urine. Overall, the findings in literature have provided with insights for potential health risk of Cd in areas with high Cd geochemical background levels, particular for the black shale exposed areas, more attentions should be paid on the geogenic Cd pollution, and suitable strategies of remediation and geo-environmental management for geogenic Cd pollution need further research. Close

• 3. [Article] The Terroir of Pinot Noir Wine in the Willamette Valley, Oregon : A Broad Analysis of Vineyard Soils, Grape Juice and Wine Chemistry

  Terroir is determined by a combination of factors in the vineyard including the grape varietal, geology and soil, soil hydrology, physiography, and climate. Although most studies have examined regional ...

  Citation × Citation Citation Abstract Copy Title: The Terroir of Pinot Noir Wine in the Willamette Valley, Oregon : A Broad Analysis of Vineyard Soils, Grape Juice and Wine Chemistry Author: Barnard, Kathryn Nora Year: 2016 Terroir is determined by a combination of factors in the vineyard including the grape varietal, geology and soil, soil hydrology, physiography, and climate. Although most studies have examined regional differences in wine flavors and associated provenance of wine based on chemistry, few have examined the chemistry of the soil and the ability to trace that chemistry to grape juice and, finally, to the wine. This dissertation examines what soil physical and chemical differences specific to this region might influence grape juice chemistry and wine chemistry. Wine-grapes in the Willamette Valley, Oregon, are grown on three major soil parent materials: volcanic, marine sediments, and loess/volcanic. Winemakers have observed differences in the flavor of Pinot Noir wine made from grapes grown on these different parent materials. This dissertation examines differences in the soil properties and elemental chemistry of the soil parent materials at various vineyards to document their effect on wine chemistry as a step towards understanding differences in flavor. All aspects of the terroir are controlled by carefully selecting vineyards with similar exposure and elevation, the same grape varietal and wine making techniques, and only the soils vary. The hypothesis is that the chemistry of the grape juice and wine reflect the soil in which the grapes were grown and that the three parent materials have soils that can be distinguished by their physical and chemical characteristics. Soil pits were excavated in 20 vineyards, soil properties were described in the field, and soil samples were later analyzed in the laboratory particle size, organic matter, color, pH, cation exchange capacity (ammonium acetate method), clay mineralogy (x-ray diffraction), and elemental chemistry (ICP-MS/AES). X-ray fluorescence was used to examine the pisolites. ICP-MS/AES was used for elemental analysis of grape juice and wines produced from these vineyards. Principal component analysis was used to compare soil physical and chemical characteristics, grape juice and wine chemistry. The physical characteristics of soils from all the three parent materials indicate: they are old (>50,000 years) based on their high clay content, low cation exchange capacity, red colors, and high Fe and Al content. These features indicate enough time has passed to reduce organic matter and other cations at depth, leave behind insoluble Fe and Al, and develop pedogenic clays. In my study region, volcanic and marine sediment soils are more developed with slightly lower acidity than the loess/volcanic soils. A new finding for this region is the presence of pisolites (Fe/Mg concretions) in the volcanic and the loess/volcanic soils, but absent in the marine sediment soils. Winemakers hypothesized that pisolites were present only in loess soils and influenced wine flavor in some way. Volcanic soils have the highest P, S, Fe, Co, Mn, and V concentrations and the lowest As and Sr values. Marine sediment soils have higher Cl and Sr and lower P, Co, Mn, Ba, and V concentrations than volcanic soils. Loess soils have the highest values of K and Mg and are similar to volcanic soils with higher P and V values and similar to marine sediment soils with higher Sr values. The main elements found to be significant in determining one parent material from another are V and Mn (volcanic soils), Mg and K (loess soils), and Sr (marine sediment or loess soils). Sr is slightly higher in grape juice and wine from vines grown on marine sediment parent material compared to volcanic and loess parent material, whereas Mn is higher in the juice and wine from grapes grown in volcanic parent material. P, S, Fe, Co, V, Cl, Ba, Mg, and K did not maintain their relative concentration levels from soil to grape juice to wine. The principal component analysis shows that soil and wine chemistry differs between parent material, but is inconclusive for grape juice chemistry. Title: The Terroir of Pinot Noir Wine in the Willamette Valley, Oregon : A Broad Analysis of Vineyard Soils, Grape Juice and Wine Chemistry Author: Barnard, Kathryn Nora Year: 2016 Terroir is determined by a combination of factors in the vineyard including the grape varietal, geology and soil, soil hydrology, physiography, and climate. Although most studies have examined regional differences in wine flavors and associated provenance of wine based on chemistry, few have examined the chemistry of the soil and the ability to trace that chemistry to grape juice and, finally, to the wine. This dissertation examines what soil physical and chemical differences specific to this region might influence grape juice chemistry and wine chemistry. Wine-grapes in the Willamette Valley, Oregon, are grown on three major soil parent materials: volcanic, marine sediments, and loess/volcanic. Winemakers have observed differences in the flavor of Pinot Noir wine made from grapes grown on these different parent materials. This dissertation examines differences in the soil properties and elemental chemistry of the soil parent materials at various vineyards to document their effect on wine chemistry as a step towards understanding differences in flavor. All aspects of the terroir are controlled by carefully selecting vineyards with similar exposure and elevation, the same grape varietal and wine making techniques, and only the soils vary. The hypothesis is that the chemistry of the grape juice and wine reflect the soil in which the grapes were grown and that the three parent materials have soils that can be distinguished by their physical and chemical characteristics. Soil pits were excavated in 20 vineyards, soil properties were described in the field, and soil samples were later analyzed in the laboratory particle size, organic matter, color, pH, cation exchange capacity (ammonium acetate method), clay mineralogy (x-ray diffraction), and elemental chemistry (ICP-MS/AES). X-ray fluorescence was used to examine the pisolites. ICP-MS/AES was used for elemental analysis of grape juice and wines produced from these vineyards. Principal component analysis was used to compare soil physical and chemical characteristics, grape juice and wine chemistry. The physical characteristics of soils from all the three parent materials indicate: they are old (>50,000 years) based on their high clay content, low cation exchange capacity, red colors, and high Fe and Al content. These features indicate enough time has passed to reduce organic matter and other cations at depth, leave behind insoluble Fe and Al, and develop pedogenic clays. In my study region, volcanic and marine sediment soils are more developed with slightly lower acidity than the loess/volcanic soils. A new finding for this region is the presence of pisolites (Fe/Mg concretions) in the volcanic and the loess/volcanic soils, but absent in the marine sediment soils. Winemakers hypothesized that pisolites were present only in loess soils and influenced wine flavor in some way. Volcanic soils have the highest P, S, Fe, Co, Mn, and V concentrations and the lowest As and Sr values. Marine sediment soils have higher Cl and Sr and lower P, Co, Mn, Ba, and V concentrations than volcanic soils. Loess soils have the highest values of K and Mg and are similar to volcanic soils with higher P and V values and similar to marine sediment soils with higher Sr values. The main elements found to be significant in determining one parent material from another are V and Mn (volcanic soils), Mg and K (loess soils), and Sr (marine sediment or loess soils). Sr is slightly higher in grape juice and wine from vines grown on marine sediment parent material compared to volcanic and loess parent material, whereas Mn is higher in the juice and wine from grapes grown in volcanic parent material. P, S, Fe, Co, V, Cl, Ba, Mg, and K did not maintain their relative concentration levels from soil to grape juice to wine. The principal component analysis shows that soil and wine chemistry differs between parent material, but is inconclusive for grape juice chemistry. Close

• 4. [Article] Naturally Occurring Background Levels of Arsenic in the Soils of Southwestern Oregon

  Abstract This study examines the natural background concentrations of arsenic in the soils of southwest Oregon, using new samples in addition to data collected from previous theses (Khandoker, 1997 and ...

  Citation × Citation Citation Abstract Copy Title: Naturally Occurring Background Levels of Arsenic in the Soils of Southwestern Oregon Author: Hurtado, Heather Ann Year: 2015 Abstract This study examines the natural background concentrations of arsenic in the soils of southwest Oregon, using new samples in addition to data collected from previous theses (Khandoker, 1997 and Douglas, 1999). The original 213 samples were run by ICP-AES with a reporting limit of 20 ppm, and only three samples had detected values. The original samples were tested again (2013) at a lower reporting limit of 0.2 ppm by ICP-MS, as were 42 new samples (2013), to better ascertain the natural levels of arsenic in undisturbed soils. The aim is to add to the existing DEQ data set, which has been used to establish new regulatory levels based on natural levels in the environment that are both safer and more economically viable than the former risk-based remediation levels (DEQ, 2013). The maximum and mean concentrations, respectively, for each province (with high formation map unit) are 85.4 and 21.99 ppm for South Willamette Valley (Tfee), 45.4 and 5.42 ppm for the Klamath Mountains (Jub), 11.9 and 2.76 ppm for the Cascade Range (Tbaa), 10.6 and 5.15 ppm for the Coast Range (Ty), 2.32 and 1.29 ppm for the Basin and Range (Qba) and 1.5 and 1.20 ppm for the High Lava Plains (Tmv). In addition, the distribution and variance of arsenic in the A and B soil horizons is assessed in this study by comparing deviation at a single site, and also by comparing A and B horizons of 119 PSU sites. One of 18 new sites sampled for this study (distinguished with the HH prefix), site HH11, was randomly chosen to evaluate differences at a single location. Site HH11 is an Inceptisol soil above volcanic rock (KJdv map unit) located at 275 meters elevation in Douglas County within the Klamath province. Five samples were taken from the A and from the B horizons at site HH11. The means and standard deviations were 3.74 ± 0.44 for the A horizon and 4.53 ± 0.39 for the B horizon. The consistency and low deviation within each horizon indicate that a single sample within a horizon is a good representative of that horizon and supports the field methodology used in this study of taking only one sample in the A horizon and one sample in the B horizon. Wilcoxon Rank-Sum test determined that A and B horizons for the 119 sites that had data for both the A and B horizons were not statistically different (p-value 0.76). Arsenic concentration is not associated with a particular horizon for these sites. However, differentiation between soil horizons increases with age (Birkeland, 1999), as does accumulation of the iron oxides and sulfide minerals on clay surfaces (McLaren et al., 2006) which concentrate in the B horizon. These associations warrant further study to see how they relate to arsenic level, soil development and age in Oregon soils. Lastly, this study statistically examines six potentially important environmental predictors of naturally occurring arsenic in southwestern Oregon: site elevation, geomorphic province, mapped rock type and age, and sample soil order and color (redness). A Classification and Regression Tree Model (CART) determined soil order, elevation and rock type to be of significant importance in determining arsenic concentrations in the natural environment. According to the regression tree, arsenic concentrations are greater within Alfisol and Ultisol/Alfisol and Vertisol soil orders, at lower elevations below 1,207 meters, and within soils from sedimentary, mixed volcanic/sedimentary and unconsolidated rock types. Title: Naturally Occurring Background Levels of Arsenic in the Soils of Southwestern Oregon Author: Hurtado, Heather Ann Year: 2015 Abstract This study examines the natural background concentrations of arsenic in the soils of southwest Oregon, using new samples in addition to data collected from previous theses (Khandoker, 1997 and Douglas, 1999). The original 213 samples were run by ICP-AES with a reporting limit of 20 ppm, and only three samples had detected values. The original samples were tested again (2013) at a lower reporting limit of 0.2 ppm by ICP-MS, as were 42 new samples (2013), to better ascertain the natural levels of arsenic in undisturbed soils. The aim is to add to the existing DEQ data set, which has been used to establish new regulatory levels based on natural levels in the environment that are both safer and more economically viable than the former risk-based remediation levels (DEQ, 2013). The maximum and mean concentrations, respectively, for each province (with high formation map unit) are 85.4 and 21.99 ppm for South Willamette Valley (Tfee), 45.4 and 5.42 ppm for the Klamath Mountains (Jub), 11.9 and 2.76 ppm for the Cascade Range (Tbaa), 10.6 and 5.15 ppm for the Coast Range (Ty), 2.32 and 1.29 ppm for the Basin and Range (Qba) and 1.5 and 1.20 ppm for the High Lava Plains (Tmv). In addition, the distribution and variance of arsenic in the A and B soil horizons is assessed in this study by comparing deviation at a single site, and also by comparing A and B horizons of 119 PSU sites. One of 18 new sites sampled for this study (distinguished with the HH prefix), site HH11, was randomly chosen to evaluate differences at a single location. Site HH11 is an Inceptisol soil above volcanic rock (KJdv map unit) located at 275 meters elevation in Douglas County within the Klamath province. Five samples were taken from the A and from the B horizons at site HH11. The means and standard deviations were 3.74 ± 0.44 for the A horizon and 4.53 ± 0.39 for the B horizon. The consistency and low deviation within each horizon indicate that a single sample within a horizon is a good representative of that horizon and supports the field methodology used in this study of taking only one sample in the A horizon and one sample in the B horizon. Wilcoxon Rank-Sum test determined that A and B horizons for the 119 sites that had data for both the A and B horizons were not statistically different (p-value 0.76). Arsenic concentration is not associated with a particular horizon for these sites. However, differentiation between soil horizons increases with age (Birkeland, 1999), as does accumulation of the iron oxides and sulfide minerals on clay surfaces (McLaren et al., 2006) which concentrate in the B horizon. These associations warrant further study to see how they relate to arsenic level, soil development and age in Oregon soils. Lastly, this study statistically examines six potentially important environmental predictors of naturally occurring arsenic in southwestern Oregon: site elevation, geomorphic province, mapped rock type and age, and sample soil order and color (redness). A Classification and Regression Tree Model (CART) determined soil order, elevation and rock type to be of significant importance in determining arsenic concentrations in the natural environment. According to the regression tree, arsenic concentrations are greater within Alfisol and Ultisol/Alfisol and Vertisol soil orders, at lower elevations below 1,207 meters, and within soils from sedimentary, mixed volcanic/sedimentary and unconsolidated rock types. Close

• 5. [Article] Compositional and Physical Gradients in the Magmas of the Devine Canyon Tuff, Eastern Oregon: Constraints for Evolution Models of Voluminous High-silica Rhyolites

  Large-volume silicic ignimbrites erupt from reservoirs that vary in composition, temperature, volatile content and crystallinity. The 9.7 Ma Devine Canyon Tuff (DCT) of eastern Oregon is a large-volume ...

  Citation × Citation Citation Abstract Copy Title: Compositional and Physical Gradients in the Magmas of the Devine Canyon Tuff, Eastern Oregon: Constraints for Evolution Models of Voluminous High-silica Rhyolites Author: Isom, Shelby Lee Year: 2017 Large-volume silicic ignimbrites erupt from reservoirs that vary in composition, temperature, volatile content and crystallinity. The 9.7 Ma Devine Canyon Tuff (DCT) of eastern Oregon is a large-volume (>250 km3), compositionally zoned and variably welded ignimbrite. The ignimbrite exhibits heterogeneous trace element compositions, variable volatile content and crystallinity. These observations were utilized in the investigation into the generation, accumulation and evolution of the magmas composing the DCT. Building off previous research, pumices were selected from the range of trace element compositions and analyzed with respect to crystallinity, mineral abundances and assemblages. The DCT displays a gradational trace element enrichment and decrease in crystallinity from least evolved, dacite, at ~22% crystals to most evolved high-silica rhyolite at 3% crystals. Two distinct mineral populations of feldspar and clinopyroxene were identified in previous work, one belonging to the rhyolitic magma and the other to the dacitic magma. Volatile content derived from melt inclusion Fourier Transform Infrared (FTIR) spectrometer analysis revealed an increase in water content from 1.2 to 3.7 wt.% in the most evolved rhyolite. The DCT exhibits low and variable δ18O signatures, 4.52% to 5.76%, based on δ18O values measured on quartz and sanidine. Low δ18O signatures of all DCT rhyolites suggest the incorporation of hydrothermally altered crust into the melt. Furthermore, quartz phenocrysts from all high-silica rhyolite groups display dark oscillatory zoned cores and Ti-rich bright rims. These data provide insight into how these magmas were generated and subsequently stored in the crust. Commonalities of petrographic and compositional features among rhyolites, especially the zoning characteristics of quartz phenocrysts, exclude the possibility of storage and evolution in multiple reservoirs. Envisioning a scenario where all magmas are stored within a single reservoir prior to eruption and assuming rhyolites A and D are the product of partial melting. The mixing of A and D rhyolites produced rhyolite B, and subsequent mixing of intermediate rhyolite B and end-member rhyolite D generated rhyolite C. However, some trace element inconsistencies, between mixing model and observed intermediate rhyolites suggest a secondary process. Post mixing, rhyolites B and C require some modification by fractional crystallization to account for LREE and other inconsistencies between mixed models and observed rhyolites. Finally, the origin of the dacite is likely through mixing of group D rhyolite and an intrusive fractionated basalt, which could have led to the eruption of the Devine Canyon Tuff. Title: Compositional and Physical Gradients in the Magmas of the Devine Canyon Tuff, Eastern Oregon: Constraints for Evolution Models of Voluminous High-silica Rhyolites Author: Isom, Shelby Lee Year: 2017 Large-volume silicic ignimbrites erupt from reservoirs that vary in composition, temperature, volatile content and crystallinity. The 9.7 Ma Devine Canyon Tuff (DCT) of eastern Oregon is a large-volume (>250 km3), compositionally zoned and variably welded ignimbrite. The ignimbrite exhibits heterogeneous trace element compositions, variable volatile content and crystallinity. These observations were utilized in the investigation into the generation, accumulation and evolution of the magmas composing the DCT. Building off previous research, pumices were selected from the range of trace element compositions and analyzed with respect to crystallinity, mineral abundances and assemblages. The DCT displays a gradational trace element enrichment and decrease in crystallinity from least evolved, dacite, at ~22% crystals to most evolved high-silica rhyolite at 3% crystals. Two distinct mineral populations of feldspar and clinopyroxene were identified in previous work, one belonging to the rhyolitic magma and the other to the dacitic magma. Volatile content derived from melt inclusion Fourier Transform Infrared (FTIR) spectrometer analysis revealed an increase in water content from 1.2 to 3.7 wt.% in the most evolved rhyolite. The DCT exhibits low and variable δ18O signatures, 4.52% to 5.76%, based on δ18O values measured on quartz and sanidine. Low δ18O signatures of all DCT rhyolites suggest the incorporation of hydrothermally altered crust into the melt. Furthermore, quartz phenocrysts from all high-silica rhyolite groups display dark oscillatory zoned cores and Ti-rich bright rims. These data provide insight into how these magmas were generated and subsequently stored in the crust. Commonalities of petrographic and compositional features among rhyolites, especially the zoning characteristics of quartz phenocrysts, exclude the possibility of storage and evolution in multiple reservoirs. Envisioning a scenario where all magmas are stored within a single reservoir prior to eruption and assuming rhyolites A and D are the product of partial melting. The mixing of A and D rhyolites produced rhyolite B, and subsequent mixing of intermediate rhyolite B and end-member rhyolite D generated rhyolite C. However, some trace element inconsistencies, between mixing model and observed intermediate rhyolites suggest a secondary process. Post mixing, rhyolites B and C require some modification by fractional crystallization to account for LREE and other inconsistencies between mixed models and observed rhyolites. Finally, the origin of the dacite is likely through mixing of group D rhyolite and an intrusive fractionated basalt, which could have led to the eruption of the Devine Canyon Tuff. Close

• 6. [Article] Earthquake and Tsunami Forecasts: Relation of Slow Slip Events to Subsequent Earthquake Rupture

  The 5 September 2012 Mw 7.6 earthquake on the Costa Rica subduction plate boundary followed a 62-y interseismic period. High-precision GPS recorded numerous slow slip events (SSEs) in the decade leading ...

  Citation × Citation Citation Abstract Copy Title: Earthquake and Tsunami Forecasts: Relation of Slow Slip Events to Subsequent Earthquake Rupture Author: Dixon, Timothy H., Jiang, Yan, Malservisi, Rocco, McCaffrey, Robert, Voss, Nicholas, Protti, Marino, Gonzalez, Victor Year: 2014 The 5 September 2012 Mw 7.6 earthquake on the Costa Rica subduction plate boundary followed a 62-y interseismic period. High-precision GPS recorded numerous slow slip events (SSEs) in the decade leading up to the earthquake, both up-dip and down-dip of seismic rupture. Deeper SSEs were larger than shallower ones and, if characteristic of the interseismic period, release most locking down-dip of the earthquake, limiting down-dip rupture and earthquake magnitude. Shallower SSEs were smaller, accounting for some but not all interseismic locking. One SSE occurred several months before the earthquake, but changes in Mohr–Coulomb failure stress were probably too small to trigger the earthquake. Because many SSEs have occurred without subsequent rupture, their individual predictive value is limited, but taken together they released a significant amount of accumulated interseismic strain before the earthquake, effectively defining the area of subsequent seismic rupture (rupture did not occur where slow slip was common). Because earthquake magnitude depends on rupture area, this has important implications for earthquake hazard assessment. Specifically, if this behavior is representative of future earthquake cycles and other subduction zones, it implies that monitoring SSEs, including shallow up-dip events that lie offshore, could lead to accurate forecasts of earthquake magnitude and tsunami potential. Title: Earthquake and Tsunami Forecasts: Relation of Slow Slip Events to Subsequent Earthquake Rupture Author: Dixon, Timothy H., Jiang, Yan, Malservisi, Rocco, McCaffrey, Robert, Voss, Nicholas, Protti, Marino, Gonzalez, Victor Year: 2014 The 5 September 2012 Mw 7.6 earthquake on the Costa Rica subduction plate boundary followed a 62-y interseismic period. High-precision GPS recorded numerous slow slip events (SSEs) in the decade leading up to the earthquake, both up-dip and down-dip of seismic rupture. Deeper SSEs were larger than shallower ones and, if characteristic of the interseismic period, release most locking down-dip of the earthquake, limiting down-dip rupture and earthquake magnitude. Shallower SSEs were smaller, accounting for some but not all interseismic locking. One SSE occurred several months before the earthquake, but changes in Mohr–Coulomb failure stress were probably too small to trigger the earthquake. Because many SSEs have occurred without subsequent rupture, their individual predictive value is limited, but taken together they released a significant amount of accumulated interseismic strain before the earthquake, effectively defining the area of subsequent seismic rupture (rupture did not occur where slow slip was common). Because earthquake magnitude depends on rupture area, this has important implications for earthquake hazard assessment. Specifically, if this behavior is representative of future earthquake cycles and other subduction zones, it implies that monitoring SSEs, including shallow up-dip events that lie offshore, could lead to accurate forecasts of earthquake magnitude and tsunami potential. Close

• 7. [Article] A Morphologic Proxy for Debris Flow Erosion With Application to the Earthquake Deformation Cycle, Cascadia Subduction Zone, USA

  In unglaciated steeplands, valley reaches dominated by debris flow scour and incision set landscape form as they often account for > 80% of valley network length and relief. While hillslope and fluvial ...

  Citation × Citation Citation Abstract Copy Title: A Morphologic Proxy for Debris Flow Erosion With Application to the Earthquake Deformation Cycle, Cascadia Subduction Zone, USA Author: Penserini, Brian D., Roering, Joshua J., Strieg, Ashley Year: 2017 In unglaciated steeplands, valley reaches dominated by debris flow scour and incision set landscape form as they often account for > 80% of valley network length and relief. While hillslope and fluvial process models have frequently been combined with digital topography to develop morphologic proxies for erosion rate and drainage divide migration, debris-flow-dominated networks, despite their ubiquity, have not been exploited for this purpose. Here, we applied an empirical function that describes how slope-area data systematically deviate from so-called fluvial power-law behavior at small drainage areas. Using airborne LiDAR data for 83 small (~ 1 km2) catchments in the western Oregon Coast Range, we quantified variation in model parameters and observed that the curvature of the power-law scaling deviation varies with catchment-averaged erosion rate estimated from cosmogenic nuclides in stream sediments. Given consistent climate and lithology across our study area and assuming steady erosion, we used this calibrated denudation-morphology relationship to map spatial patterns of long-term uplift for our study catchments. By combining our predicted pattern of long-term uplift rate with paleoseismic and geodetic (tide gauge, GPS, and leveling) data, we estimated the spatial distribution of coseismic subsidence experienced during megathrust earthquakes along the Cascadia Subduction Zone. Our estimates of coseismic subsidence near the coast (0.4 to 0.7 m for earthquake recurrence intervals of 300 to 500 years) agree with field measurements from numerous stratigraphic studies. Our results also demonstrate that coseismic subsidence decreases inland to negligible values > 25 km from the coast, reflecting the diminishing influence of the earthquake deformation cycle on vertical changes of the interior coastal ranges. More generally, our results demonstrate that debris flow valley networks serve as highly localized, yet broadly distributed indicators of erosion (and rock uplift), making them invaluable for mapping crustal deformation and landscape adjustment. © 2017 Elsevier B.V. Title: A Morphologic Proxy for Debris Flow Erosion With Application to the Earthquake Deformation Cycle, Cascadia Subduction Zone, USA Author: Penserini, Brian D., Roering, Joshua J., Strieg, Ashley Year: 2017 In unglaciated steeplands, valley reaches dominated by debris flow scour and incision set landscape form as they often account for > 80% of valley network length and relief. While hillslope and fluvial process models have frequently been combined with digital topography to develop morphologic proxies for erosion rate and drainage divide migration, debris-flow-dominated networks, despite their ubiquity, have not been exploited for this purpose. Here, we applied an empirical function that describes how slope-area data systematically deviate from so-called fluvial power-law behavior at small drainage areas. Using airborne LiDAR data for 83 small (~ 1 km2) catchments in the western Oregon Coast Range, we quantified variation in model parameters and observed that the curvature of the power-law scaling deviation varies with catchment-averaged erosion rate estimated from cosmogenic nuclides in stream sediments. Given consistent climate and lithology across our study area and assuming steady erosion, we used this calibrated denudation-morphology relationship to map spatial patterns of long-term uplift for our study catchments. By combining our predicted pattern of long-term uplift rate with paleoseismic and geodetic (tide gauge, GPS, and leveling) data, we estimated the spatial distribution of coseismic subsidence experienced during megathrust earthquakes along the Cascadia Subduction Zone. Our estimates of coseismic subsidence near the coast (0.4 to 0.7 m for earthquake recurrence intervals of 300 to 500 years) agree with field measurements from numerous stratigraphic studies. Our results also demonstrate that coseismic subsidence decreases inland to negligible values > 25 km from the coast, reflecting the diminishing influence of the earthquake deformation cycle on vertical changes of the interior coastal ranges. More generally, our results demonstrate that debris flow valley networks serve as highly localized, yet broadly distributed indicators of erosion (and rock uplift), making them invaluable for mapping crustal deformation and landscape adjustment. © 2017 Elsevier B.V. Close

• 8. [Article] The West Tidewater Earthflow, Northern Oregon Coast Range

  The West Tidewater earthflow, one of the largest in Oregon's history, occurred in December of 1994. The earthflow is located approximately 15 km north of Jewel, Oregon near the summit ofthe Northern Oregon ...

  Citation × Citation Citation Abstract Copy Title: The West Tidewater Earthflow, Northern Oregon Coast Range Author: Sanford, Barry A. Year: 2014 The West Tidewater earthflow, one of the largest in Oregon's history, occurred in December of 1994. The earthflow is located approximately 15 km north of Jewel, Oregon near the summit ofthe Northern Oregon Coast Range Mountains. The earthflow is 900 m long and 250 m wide, giving it a surface area of 9 ha, or 22 acres. Volume is 3.5 million m3. The earthflow occurred in low strength, well-bedded, tuffaceous, carbonaceous, micaceous, clay-rich mudstone, and very fine-grained, feldspathic, clay-rich siltstone of the lower Miocene age Northrup Creek Formation. The soil clay fractions contain up to 90% smectite with indications ofhalloysite. This earthflow is a reactivation ofa 650-year-old landslide (C-14 dating of uncovered buried trees). The failure mode is examined using a Janbu slope analysis and includes double wedge failure near the headscarp. High soil pore water pressure is one of the major causes of this slope failure. Rainfall levels for October, November, and December of 1994 were twice the previous five-year average. Present day groundwater level within the basin is less than one meter below ground surface. The earthflow is partially controlled by two faults of regional extent that dissect the basin near the headscarp in NW-SE and NE-SW directions. The Inceptisol soils in the basin remain moist below 20 cm year around. Soil in the basin may have been further weakened due to loss of root strength following timber harvest on the site in 1991. Soil liquid limits range from 42% to 95%, with PI values ranging from 2% to 77%. Soil clay content ranges between 18% and 30%. Direct shear tests on the mudstone and siltstone bedrock in both drained and undrained conditions produced internal friction angles of 14-18°, with cohesion values of 4 - 8 kPa. Back calculation of study area soil strength using the modified Bishop method results in a residual friction angle of 20.7°. The failure mode ofthe earthflow is from the headscarp downward and is modeled using Janbu methods. The study includes a detailed topographic map and a failure analysis of the earthflow basin. Title: The West Tidewater Earthflow, Northern Oregon Coast Range Author: Sanford, Barry A. Year: 2014 The West Tidewater earthflow, one of the largest in Oregon's history, occurred in December of 1994. The earthflow is located approximately 15 km north of Jewel, Oregon near the summit ofthe Northern Oregon Coast Range Mountains. The earthflow is 900 m long and 250 m wide, giving it a surface area of 9 ha, or 22 acres. Volume is 3.5 million m3. The earthflow occurred in low strength, well-bedded, tuffaceous, carbonaceous, micaceous, clay-rich mudstone, and very fine-grained, feldspathic, clay-rich siltstone of the lower Miocene age Northrup Creek Formation. The soil clay fractions contain up to 90% smectite with indications ofhalloysite. This earthflow is a reactivation ofa 650-year-old landslide (C-14 dating of uncovered buried trees). The failure mode is examined using a Janbu slope analysis and includes double wedge failure near the headscarp. High soil pore water pressure is one of the major causes of this slope failure. Rainfall levels for October, November, and December of 1994 were twice the previous five-year average. Present day groundwater level within the basin is less than one meter below ground surface. The earthflow is partially controlled by two faults of regional extent that dissect the basin near the headscarp in NW-SE and NE-SW directions. The Inceptisol soils in the basin remain moist below 20 cm year around. Soil in the basin may have been further weakened due to loss of root strength following timber harvest on the site in 1991. Soil liquid limits range from 42% to 95%, with PI values ranging from 2% to 77%. Soil clay content ranges between 18% and 30%. Direct shear tests on the mudstone and siltstone bedrock in both drained and undrained conditions produced internal friction angles of 14-18°, with cohesion values of 4 - 8 kPa. Back calculation of study area soil strength using the modified Bishop method results in a residual friction angle of 20.7°. The failure mode ofthe earthflow is from the headscarp downward and is modeled using Janbu methods. The study includes a detailed topographic map and a failure analysis of the earthflow basin. Close