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• 1. [Article] Intercomparison of Local Hydroxyl Measurements by Radiocarbon and FAGE Techniques

  A direct intercomparison of near-surface tropospheric HO concentration measurements by two different techniques was made in October–November 1992 at a rural site near Pullman, Washington. The atmosphere ...

  Citation × Citation Citation Abstract Copy Title: Intercomparison of Local Hydroxyl Measurements by Radiocarbon and FAGE Techniques Author: Campbell, Malcolm J., Hall, Brad D., Sheppard, John C., Utley, Philip L., O'Brien, Robert J., Hard, Thomas M., George, Linda Acha Year: 1995 A direct intercomparison of near-surface tropospheric HO concentration measurements by two different techniques was made in October–November 1992 at a rural site near Pullman, Washington. The atmosphere at the site is believed to contain low levels of anthropogenic pollution. The instruments' inlets were located at the same height (3.5 m) above the ground and were separated by 10 m along a line normal to the prevailing wind. Readings of the FAGE3 and radiocarbon instruments showed a high correlation (r² = 0.74) despite HO concentrations that were frequently near the detection limit of the instruments. An unweighted least squares regression shows a slope significantly different from unity, indicating different calibration scales of the two instruments Title: Intercomparison of Local Hydroxyl Measurements by Radiocarbon and FAGE Techniques Author: Campbell, Malcolm J., Hall, Brad D., Sheppard, John C., Utley, Philip L., O'Brien, Robert J., Hard, Thomas M., George, Linda Acha Year: 1995 A direct intercomparison of near-surface tropospheric HO concentration measurements by two different techniques was made in October–November 1992 at a rural site near Pullman, Washington. The atmosphere at the site is believed to contain low levels of anthropogenic pollution. The instruments' inlets were located at the same height (3.5 m) above the ground and were separated by 10 m along a line normal to the prevailing wind. Readings of the FAGE3 and radiocarbon instruments showed a high correlation (r² = 0.74) despite HO concentrations that were frequently near the detection limit of the instruments. An unweighted least squares regression shows a slope significantly different from unity, indicating different calibration scales of the two instruments Close

• 2. [Article] Effect of Reducing Maximum Cycle Length on Roadside Air Quality and Travel Times on a Corridor in Portland, OR

  The Sydney Coordinated Adaptive Traffic System (SCATS), an adaptive signal system designed to reduce congestion, has been installed on a heavily trafficked roadway in Portland, OR. In addition to traffic ...

  Citation × Citation Citation Abstract Copy Title: Effect of Reducing Maximum Cycle Length on Roadside Air Quality and Travel Times on a Corridor in Portland, OR Author: Kendrick, Christine M., Urowsky, David, Rotich, Willie, Koonce, Peter, George, Linda Acha Year: 2014 The Sydney Coordinated Adaptive Traffic System (SCATS), an adaptive signal system designed to reduce congestion, has been installed on a heavily trafficked roadway in Portland, OR. In addition to traffic performance metrics, we are investigating how this system affects roadway emissions of air pollutants. A twenty-second reduction to maximum cycle length was proposed for the SCATS system to address pedestrian delay concerns. A two-week trial period with this reduced cycle length was implemented. Travel times and roadside air pollution concentrations were monitored throughout this study period and compared to before and after periods with the current maximum cycle length. Average travel times were found to be significantly higher during the reduced maximum cycle length, but with a mean difference of only 4-5 seconds for travel time. Assessment of travel time for this roadway suggests that a twenty second decrease in maximum cycle length to help shorten pedestrian delay can be made without significant consequences to travel time. Total traffic volumes were consistent for all four weeks of the study. Meteorological conditions were similar for the first two weeks comparing maximum cycle lengths. A shift in ambient temperature led the second two weeks of the cycle length comparison to have more similar meteorological conditions versus the first two weeks. Average NO and NO2 concentrations were not significantly different for the first half of the study. However, NO and NO2 concentrations were significantly higher during the reduced maximum cycle length for the second half of the study. When there was a significant difference based on t-test statistics, the measurements did show an increase in roadside concentrations during the shorter maximum cycle length. Preliminary results are unclear if changes to air quality (as assessed by NO and NO2 concentrations) occur or not due to the reduced maximum cycle length. Results require further comparative analysis in which meteorology and traffic conditions are controlled for so that any difference in air quality due to maximum cycle length alone can be quantified. Title: Effect of Reducing Maximum Cycle Length on Roadside Air Quality and Travel Times on a Corridor in Portland, OR Author: Kendrick, Christine M., Urowsky, David, Rotich, Willie, Koonce, Peter, George, Linda Acha Year: 2014 The Sydney Coordinated Adaptive Traffic System (SCATS), an adaptive signal system designed to reduce congestion, has been installed on a heavily trafficked roadway in Portland, OR. In addition to traffic performance metrics, we are investigating how this system affects roadway emissions of air pollutants. A twenty-second reduction to maximum cycle length was proposed for the SCATS system to address pedestrian delay concerns. A two-week trial period with this reduced cycle length was implemented. Travel times and roadside air pollution concentrations were monitored throughout this study period and compared to before and after periods with the current maximum cycle length. Average travel times were found to be significantly higher during the reduced maximum cycle length, but with a mean difference of only 4-5 seconds for travel time. Assessment of travel time for this roadway suggests that a twenty second decrease in maximum cycle length to help shorten pedestrian delay can be made without significant consequences to travel time. Total traffic volumes were consistent for all four weeks of the study. Meteorological conditions were similar for the first two weeks comparing maximum cycle lengths. A shift in ambient temperature led the second two weeks of the cycle length comparison to have more similar meteorological conditions versus the first two weeks. Average NO and NO2 concentrations were not significantly different for the first half of the study. However, NO and NO2 concentrations were significantly higher during the reduced maximum cycle length for the second half of the study. When there was a significant difference based on t-test statistics, the measurements did show an increase in roadside concentrations during the shorter maximum cycle length. Preliminary results are unclear if changes to air quality (as assessed by NO and NO2 concentrations) occur or not due to the reduced maximum cycle length. Results require further comparative analysis in which meteorology and traffic conditions are controlled for so that any difference in air quality due to maximum cycle length alone can be quantified. Close

• 3. [Article] FAGE determination of tropospheric HO and HO₂

  FAGE (fluorescence assay with gas expansion) was developed as a sensitive technique for the detection of low-concentration free radicals in the atmosphere. The application of FAGE to tropospheric hydroxyl ...

  Citation × Citation Citation Abstract Copy Title: FAGE determination of tropospheric HO and HO₂ Author: George, Linda Acha, Hard, Thomas M., O'Brien, Robert J. Year: 1995 FAGE (fluorescence assay with gas expansion) was developed as a sensitive technique for the detection of low-concentration free radicals in the atmosphere. The application of FAGE to tropospheric hydroxyl (H0) and hydroperoxyl (H0₂) radicals has yielded calibrated measurements of both species in both clean air and highly polluted urban air. For HO calibration, a continuously stirred tank reactor provides a uniform external HO concentration, which can be measured by gas chromatography of an HO-reactive hydrocarbon. The aerodynamics of the air-sampling process has been modeled computationally, with results that agree with empirical observations of the effects of nozzle diameter on HO loss during sampling. The authors have also modeled airborne fluid dynamics of a FAGE probe. They have recently obtained FAGE sensitivity as high as ± 1 × 10⁶ cm-³ for a 6-minute averaging period, during field studies in highly polluted Los Angeles air, yielding a 7:1 signal-to-noise ratio near midday. Multipass excitation can further improve this sensitivity. The authors summarize their recent field studies of HO and HO², current work on improved calibration methods, other improvements, and future plans. Title: FAGE determination of tropospheric HO and HO₂ Author: George, Linda Acha, Hard, Thomas M., O'Brien, Robert J. Year: 1995 FAGE (fluorescence assay with gas expansion) was developed as a sensitive technique for the detection of low-concentration free radicals in the atmosphere. The application of FAGE to tropospheric hydroxyl (H0) and hydroperoxyl (H0₂) radicals has yielded calibrated measurements of both species in both clean air and highly polluted urban air. For HO calibration, a continuously stirred tank reactor provides a uniform external HO concentration, which can be measured by gas chromatography of an HO-reactive hydrocarbon. The aerodynamics of the air-sampling process has been modeled computationally, with results that agree with empirical observations of the effects of nozzle diameter on HO loss during sampling. The authors have also modeled airborne fluid dynamics of a FAGE probe. They have recently obtained FAGE sensitivity as high as ± 1 × 10⁶ cm-³ for a 6-minute averaging period, during field studies in highly polluted Los Angeles air, yielding a 7:1 signal-to-noise ratio near midday. Multipass excitation can further improve this sensitivity. The authors summarize their recent field studies of HO and HO², current work on improved calibration methods, other improvements, and future plans. Close