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• 1. [Article] Biogeochemical Evolution of Cryoconite Holes on Canada Glacier, Taylor Valley, Antarctica

  The cryoconite holes of the McMurdo Dry Valleys are simple, closed biogeochemical systems involving water, ice, mineral and organic debris, which serve as ecosystems for consortia of microorganisms. This ...

  Citation × Citation Citation Abstract Copy Title: Biogeochemical Evolution of Cryoconite Holes on Canada Glacier, Taylor Valley, Antarctica Author: Bagshaw, Elizabeth A., Tranter, Martyn, Fountain, Andrew G., Welch, Kathleen A., Basagic, Hassan J., Lyons, W. Berry Year: 2007 The cryoconite holes of the McMurdo Dry Valleys are simple, closed biogeochemical systems involving water, ice, mineral and organic debris, which serve as ecosystems for consortia of microorganisms. This study is the first to document the seasonal and annual chemical evolution of solutes in cryoconite holes. Samples of glacier ice, frozen cryoconite holes and those containing water were collected during the austral summer of 2005–2006. The isolation age was calculated from the excess Cl‾ in the holes, and varied from 0 to 5 years (a), consistent with the last hot summer when the cryoconite holes were open to the atmosphere. The holes progressively deepen with isolation age. Variations in DIC, DOC, K⁺ and SO²⁻₄ suggest that dissolution of primary minerals in the cryoconite debris, cyclical precipitation and dissolution of secondary carbonates, net photosynthesis over summer and net respiration during the autumnal freeze are the principal reactions which perturb the seasonal and annual solute concentrations in the holes. DOC is generated in the holes at a rate of 7.5 μg C cm⁻² a⁻¹, and non-sea-salt K⁺ accumulates in frozen holes at a rate of 0.073 μeq cm⁻² a⁻¹. We infer that C cycling is complex even in these otherwise simple systems. Title: Biogeochemical Evolution of Cryoconite Holes on Canada Glacier, Taylor Valley, Antarctica Author: Bagshaw, Elizabeth A., Tranter, Martyn, Fountain, Andrew G., Welch, Kathleen A., Basagic, Hassan J., Lyons, W. Berry Year: 2007 The cryoconite holes of the McMurdo Dry Valleys are simple, closed biogeochemical systems involving water, ice, mineral and organic debris, which serve as ecosystems for consortia of microorganisms. This study is the first to document the seasonal and annual chemical evolution of solutes in cryoconite holes. Samples of glacier ice, frozen cryoconite holes and those containing water were collected during the austral summer of 2005–2006. The isolation age was calculated from the excess Cl‾ in the holes, and varied from 0 to 5 years (a), consistent with the last hot summer when the cryoconite holes were open to the atmosphere. The holes progressively deepen with isolation age. Variations in DIC, DOC, K⁺ and SO²⁻₄ suggest that dissolution of primary minerals in the cryoconite debris, cyclical precipitation and dissolution of secondary carbonates, net photosynthesis over summer and net respiration during the autumnal freeze are the principal reactions which perturb the seasonal and annual solute concentrations in the holes. DOC is generated in the holes at a rate of 7.5 μg C cm⁻² a⁻¹, and non-sea-salt K⁺ accumulates in frozen holes at a rate of 0.073 μeq cm⁻² a⁻¹. We infer that C cycling is complex even in these otherwise simple systems. Close

• 2. [Article] Patterns and Processes of Salt Efflorescences in the McMurdo region, Antarctica

  Evaporite salts are abundant around the McMurdo region, Antarctica (~78°S) due to very low precipitation, low relative humidity, and limited overland flow. Hygroscopic salts in the McMurdo Dry Valleys ...

  Citation × Citation Citation Abstract Copy Title: Patterns and Processes of Salt Efflorescences in the McMurdo region, Antarctica Author: Bisson, Kelsey M., Welch, Kathleen A., Welch, Susan A., Sheets, Julia Meyer, Lyons, W. Berry, Levy, Joseph S., Fountain, Andrew G. Year: 2015 Evaporite salts are abundant around the McMurdo region, Antarctica (~78°S) due to very low precipitation, low relative humidity, and limited overland flow. Hygroscopic salts in the McMurdo Dry Valleys (MDVs) are preferentially formed in locations where liquid water is present in the austral summer, including along ephemeral streams, ice-covered lake boundaries, or shallow groundwater tracks. In this study, we collected salts from the Miers, Garwood, and Taylor Valleys on the Antarctic continent, as well as around McMurdo Station on Ross Island in close proximity to water sources with the goal of understanding salt geochemistry in relationship to the hydrology of the area. Halite is ubiquitous; sodium is the major cation (ranging from 70%–90% of cations by meq kg-1 sediment) and chloride is the major anion (>50%) in nearly all samples. However, a wide variety of salt phases and morphologies are tentatively identified through scanning electron microscopy (SEM) and X-ray diffraction (XRD) work. We present new data that identifies trona (Na3(CO3)(HCO3)·2H2O), tentative gaylussite (Na2Ca(CO3)2·5H2O), and tentative glauberite (Na2Ca(SO4)2) in the MDV, of which the later one has not been documented previously. Our work allows for the evaluation of processes that influence brine evolution on a local scale, consequently informing assumptions underlying large-scale processes (such as paleoclimate) in the MDV. Hydrological modeling conducted in FREZCHEM and PHREEQC suggests that a model based on aerosol deposition alone in low elevations on the valley floor inadequately characterizes salt distributions found on the surfaces of the soil because it does not account for other hydrologic inputs/outputs. Implications for the salt distributions include their use as tracers for paleolake levels, geochemical tracers of ephemeral water tracks or “wet patches” in the soil, indicators of chemical weathering products, and potential delineators of ecological communities. Title: Patterns and Processes of Salt Efflorescences in the McMurdo region, Antarctica Author: Bisson, Kelsey M., Welch, Kathleen A., Welch, Susan A., Sheets, Julia Meyer, Lyons, W. Berry, Levy, Joseph S., Fountain, Andrew G. Year: 2015 Evaporite salts are abundant around the McMurdo region, Antarctica (~78°S) due to very low precipitation, low relative humidity, and limited overland flow. Hygroscopic salts in the McMurdo Dry Valleys (MDVs) are preferentially formed in locations where liquid water is present in the austral summer, including along ephemeral streams, ice-covered lake boundaries, or shallow groundwater tracks. In this study, we collected salts from the Miers, Garwood, and Taylor Valleys on the Antarctic continent, as well as around McMurdo Station on Ross Island in close proximity to water sources with the goal of understanding salt geochemistry in relationship to the hydrology of the area. Halite is ubiquitous; sodium is the major cation (ranging from 70%–90% of cations by meq kg-1 sediment) and chloride is the major anion (>50%) in nearly all samples. However, a wide variety of salt phases and morphologies are tentatively identified through scanning electron microscopy (SEM) and X-ray diffraction (XRD) work. We present new data that identifies trona (Na3(CO3)(HCO3)·2H2O), tentative gaylussite (Na2Ca(CO3)2·5H2O), and tentative glauberite (Na2Ca(SO4)2) in the MDV, of which the later one has not been documented previously. Our work allows for the evaluation of processes that influence brine evolution on a local scale, consequently informing assumptions underlying large-scale processes (such as paleoclimate) in the MDV. Hydrological modeling conducted in FREZCHEM and PHREEQC suggests that a model based on aerosol deposition alone in low elevations on the valley floor inadequately characterizes salt distributions found on the surfaces of the soil because it does not account for other hydrologic inputs/outputs. Implications for the salt distributions include their use as tracers for paleolake levels, geochemical tracers of ephemeral water tracks or “wet patches” in the soil, indicators of chemical weathering products, and potential delineators of ecological communities. Close