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• 1. [Article] The Terroir of Pinot Noir Wine in the Willamette Valley, Oregon : A Broad Analysis of Vineyard Soils, Grape Juice and Wine Chemistry

  Terroir is determined by a combination of factors in the vineyard including the grape varietal, geology and soil, soil hydrology, physiography, and climate. Although most studies have examined regional ...

  Citation × Citation Citation Abstract Copy Title: The Terroir of Pinot Noir Wine in the Willamette Valley, Oregon : A Broad Analysis of Vineyard Soils, Grape Juice and Wine Chemistry Author: Barnard, Kathryn Nora Year: 2016 Terroir is determined by a combination of factors in the vineyard including the grape varietal, geology and soil, soil hydrology, physiography, and climate. Although most studies have examined regional differences in wine flavors and associated provenance of wine based on chemistry, few have examined the chemistry of the soil and the ability to trace that chemistry to grape juice and, finally, to the wine. This dissertation examines what soil physical and chemical differences specific to this region might influence grape juice chemistry and wine chemistry. Wine-grapes in the Willamette Valley, Oregon, are grown on three major soil parent materials: volcanic, marine sediments, and loess/volcanic. Winemakers have observed differences in the flavor of Pinot Noir wine made from grapes grown on these different parent materials. This dissertation examines differences in the soil properties and elemental chemistry of the soil parent materials at various vineyards to document their effect on wine chemistry as a step towards understanding differences in flavor. All aspects of the terroir are controlled by carefully selecting vineyards with similar exposure and elevation, the same grape varietal and wine making techniques, and only the soils vary. The hypothesis is that the chemistry of the grape juice and wine reflect the soil in which the grapes were grown and that the three parent materials have soils that can be distinguished by their physical and chemical characteristics. Soil pits were excavated in 20 vineyards, soil properties were described in the field, and soil samples were later analyzed in the laboratory particle size, organic matter, color, pH, cation exchange capacity (ammonium acetate method), clay mineralogy (x-ray diffraction), and elemental chemistry (ICP-MS/AES). X-ray fluorescence was used to examine the pisolites. ICP-MS/AES was used for elemental analysis of grape juice and wines produced from these vineyards. Principal component analysis was used to compare soil physical and chemical characteristics, grape juice and wine chemistry. The physical characteristics of soils from all the three parent materials indicate: they are old (>50,000 years) based on their high clay content, low cation exchange capacity, red colors, and high Fe and Al content. These features indicate enough time has passed to reduce organic matter and other cations at depth, leave behind insoluble Fe and Al, and develop pedogenic clays. In my study region, volcanic and marine sediment soils are more developed with slightly lower acidity than the loess/volcanic soils. A new finding for this region is the presence of pisolites (Fe/Mg concretions) in the volcanic and the loess/volcanic soils, but absent in the marine sediment soils. Winemakers hypothesized that pisolites were present only in loess soils and influenced wine flavor in some way. Volcanic soils have the highest P, S, Fe, Co, Mn, and V concentrations and the lowest As and Sr values. Marine sediment soils have higher Cl and Sr and lower P, Co, Mn, Ba, and V concentrations than volcanic soils. Loess soils have the highest values of K and Mg and are similar to volcanic soils with higher P and V values and similar to marine sediment soils with higher Sr values. The main elements found to be significant in determining one parent material from another are V and Mn (volcanic soils), Mg and K (loess soils), and Sr (marine sediment or loess soils). Sr is slightly higher in grape juice and wine from vines grown on marine sediment parent material compared to volcanic and loess parent material, whereas Mn is higher in the juice and wine from grapes grown in volcanic parent material. P, S, Fe, Co, V, Cl, Ba, Mg, and K did not maintain their relative concentration levels from soil to grape juice to wine. The principal component analysis shows that soil and wine chemistry differs between parent material, but is inconclusive for grape juice chemistry. Title: The Terroir of Pinot Noir Wine in the Willamette Valley, Oregon : A Broad Analysis of Vineyard Soils, Grape Juice and Wine Chemistry Author: Barnard, Kathryn Nora Year: 2016 Terroir is determined by a combination of factors in the vineyard including the grape varietal, geology and soil, soil hydrology, physiography, and climate. Although most studies have examined regional differences in wine flavors and associated provenance of wine based on chemistry, few have examined the chemistry of the soil and the ability to trace that chemistry to grape juice and, finally, to the wine. This dissertation examines what soil physical and chemical differences specific to this region might influence grape juice chemistry and wine chemistry. Wine-grapes in the Willamette Valley, Oregon, are grown on three major soil parent materials: volcanic, marine sediments, and loess/volcanic. Winemakers have observed differences in the flavor of Pinot Noir wine made from grapes grown on these different parent materials. This dissertation examines differences in the soil properties and elemental chemistry of the soil parent materials at various vineyards to document their effect on wine chemistry as a step towards understanding differences in flavor. All aspects of the terroir are controlled by carefully selecting vineyards with similar exposure and elevation, the same grape varietal and wine making techniques, and only the soils vary. The hypothesis is that the chemistry of the grape juice and wine reflect the soil in which the grapes were grown and that the three parent materials have soils that can be distinguished by their physical and chemical characteristics. Soil pits were excavated in 20 vineyards, soil properties were described in the field, and soil samples were later analyzed in the laboratory particle size, organic matter, color, pH, cation exchange capacity (ammonium acetate method), clay mineralogy (x-ray diffraction), and elemental chemistry (ICP-MS/AES). X-ray fluorescence was used to examine the pisolites. ICP-MS/AES was used for elemental analysis of grape juice and wines produced from these vineyards. Principal component analysis was used to compare soil physical and chemical characteristics, grape juice and wine chemistry. The physical characteristics of soils from all the three parent materials indicate: they are old (>50,000 years) based on their high clay content, low cation exchange capacity, red colors, and high Fe and Al content. These features indicate enough time has passed to reduce organic matter and other cations at depth, leave behind insoluble Fe and Al, and develop pedogenic clays. In my study region, volcanic and marine sediment soils are more developed with slightly lower acidity than the loess/volcanic soils. A new finding for this region is the presence of pisolites (Fe/Mg concretions) in the volcanic and the loess/volcanic soils, but absent in the marine sediment soils. Winemakers hypothesized that pisolites were present only in loess soils and influenced wine flavor in some way. Volcanic soils have the highest P, S, Fe, Co, Mn, and V concentrations and the lowest As and Sr values. Marine sediment soils have higher Cl and Sr and lower P, Co, Mn, Ba, and V concentrations than volcanic soils. Loess soils have the highest values of K and Mg and are similar to volcanic soils with higher P and V values and similar to marine sediment soils with higher Sr values. The main elements found to be significant in determining one parent material from another are V and Mn (volcanic soils), Mg and K (loess soils), and Sr (marine sediment or loess soils). Sr is slightly higher in grape juice and wine from vines grown on marine sediment parent material compared to volcanic and loess parent material, whereas Mn is higher in the juice and wine from grapes grown in volcanic parent material. P, S, Fe, Co, V, Cl, Ba, Mg, and K did not maintain their relative concentration levels from soil to grape juice to wine. The principal component analysis shows that soil and wine chemistry differs between parent material, but is inconclusive for grape juice chemistry. Close

• 2. [Article] Hydrogeochemical Characterization of the Alvord Valley Known Geothermal Resources Area, Harney County, Oregon

  The Alvord Valley Known Geothermal Resources Area (KGRA) , located east of the Steens Mountain-Pueblo Mountains fault block in southeastern Oregon, is within the northern Basin and Range province. This ...

  Citation × Citation Citation Abstract Copy Title: Hydrogeochemical Characterization of the Alvord Valley Known Geothermal Resources Area, Harney County, Oregon Author: St. John, Anna Maria Year: 1993 The Alvord Valley Known Geothermal Resources Area (KGRA) , located east of the Steens Mountain-Pueblo Mountains fault block in southeastern Oregon, is within the northern Basin and Range province. This investigation focuses on three thermal areas in the Alvord Basin: Borax Lake and the hot springs north of Borax Lake, Alvord Hot Springs and Mickey Springs. Mickey Springs and the springs north of Borax Lake are boiling at the surface (94 and 95° C, respectively). Inflow temperatures to Borax Lake, measured at a depth of 30 m, are greater than 100° C. Surface temperatures for Alvord Hot Springs and a flowing well northeast of Borax Lake are 78 and 59° C, respectively. Thermal fluids issue from Quaternary lacustrine and alluvial deposits. While silica sinter deposits are present at all three thermal areas, sinter is not presently being deposited. Minor calcite is being deposited at the springs north of Borax Lake. The springs discharge from N to NEstriking, high-angle, basin-bounding faults along the base of Steens Mountain and Mickey Mountain and NE-striking intrabasinal faults south of Alvord Lake. The thermal waters are dilute sodium-bicarbonate waters with significant amounts of sulfate and chloride. Conservative element plots (B, F, and Li vs. Cl) indicate good correlation between Cl and the other conservative elements. These correlations could result from mixing of thermal water with a dilute cold water or fluid evolution due to increased fluid-rock interaction, evaporation, and steam loss due to boiling. The small variations in chloride concentrations of thermal fluids during the sampling period argues against mixing of thermal fluids with cold water. The geothermal system is a hot-water rather than a vapordominated system. The ỎD content of thermal fluids is similar to the ỎD content of local cold water wells, springs, basinal pore fluids at a depth of 4 to 5 m, and perennial streams. Similarities in ỎD values indicate recharge for geothermal fluids is precipitation from the Steens Mountain fault block. The Ỏ18 content of thermal fluids is shifted 2 to 3°/oo to the right of the world meteoric water line indicating fluid-rock interaction at elevated temperatures in the reservoir. Tritium contents indicate relatively long residence times and/or low-velocity circulation of meteoric water through basement rocks. Values range from 0 to 0.25 T.U. The application of two end-member models, which calculate fluid residence times, generate a minimum of 57 years and a maximum of greater than 10,000 years. Estimated reservoir temperatures based on cation and silica geothermometry are between 170 and 200°C. Oxygensulfate isotope geothermometer estimates indicate reservoir temperatures between 198 and 207' C for Borax Lake and Alvord Hot Springs. Mickey Springs and a flowing well northeast of Borax Lake yield temperature estimates of 168 and 150° C, respectively. These values indicate partial reequilibration of the isotopic system. The Ỏ13C contents of carbon dioxide and methane of gas discharges from the thermal areas are similar to geothermal fluids from other sites. The Ỏ13C of methane indicate "normal" geothermal methane for Alvord Hot Springs and Mickey Springs (-27.8 and -27.6, respectively). The Ỏ13C of CH4 for springs north of Borax Lake (-33.6) indicates a small amount of thermogenic methane may be contributed by thermal alteration of organics in basinal sediments. The Ỏ13C contents for C02 at Alvord Hot Springs and Borax Lake are within the range expected for atmospheric, fumarolic, or mantle derived C02 (-6.5 and -6.6, respectively). The Ỏ13C content of C02 from Mickey Springs is isotopically lighter than gas released from fumaroles or the mantle (-9.4). N2/Ar ratios for Mickey Springs and Borax Lake gases (39.2 and 40.8, respectively) indicate interaction with airsaturated ground water during flow through the the zone of aeration. Helium is enriched relative to Ar and N2 in gas discharges from Alvord Hot Springs, indicating longer fluid residence times and/or increased crustal interaction at high temperatures. Ratios of B/Cl indicate the fluid reservoir is hosted in volcanic rocks. The Li/Cs ratios for the Borax Lake thermal area are consistent with a reservoir located in rhyoli tic rocks. The 228Ra/226Ra content of Borax Lake thermal fluids (1.14 ± 0.13 dpm/kg) indicates interaction with volcanic rocks for Borax Lake. The 228Ra/226Ra content of thermal fluids from Alvord Hot Springs and Mickey Springs (0.38~0.02 and 0.17 ~ 0.09) are lower than those expected for volcanic rocks and may indicate local uranium accumulation in the reservoir or zones of upflow. The 87Sr / 86Sr values for thermal waters and stratigraphic uni ts indicate the fluid reservoir is located in volcanic rocks beneath Steens Basalt. Equilibration of fluids in these units argues for thermal water circulation depths of 2 to 2.5 km in the Borax Lake thermal area, greater than 3 km in the Alvord Hot Springs area and 1 to 2 km in the Mickey Springs area. Data presented in this study do not preclude a single large deep reservoir system discharging at these three thermal areas in the Alvord basin. Differences in the chemical and isotopic composition of discharge from the three thermal areas are produced during upf low from the reservoir. During upflow, thermal waters follow a complex pathway of vertical and lateral fractures which includes short residence times in shallow reservoirs before reaching the surface. Boiling, mixing with condensate, oxidation, mixing with 1-3% tritium-bearing, near-surface cold water, relative differences in flow rate and volume, and slow cooling without vigorous boiling are processes that modify fluid composition during upflow from the deep geothermal reservoir. Title: Hydrogeochemical Characterization of the Alvord Valley Known Geothermal Resources Area, Harney County, Oregon Author: St. John, Anna Maria Year: 1993 The Alvord Valley Known Geothermal Resources Area (KGRA) , located east of the Steens Mountain-Pueblo Mountains fault block in southeastern Oregon, is within the northern Basin and Range province. This investigation focuses on three thermal areas in the Alvord Basin: Borax Lake and the hot springs north of Borax Lake, Alvord Hot Springs and Mickey Springs. Mickey Springs and the springs north of Borax Lake are boiling at the surface (94 and 95° C, respectively). Inflow temperatures to Borax Lake, measured at a depth of 30 m, are greater than 100° C. Surface temperatures for Alvord Hot Springs and a flowing well northeast of Borax Lake are 78 and 59° C, respectively. Thermal fluids issue from Quaternary lacustrine and alluvial deposits. While silica sinter deposits are present at all three thermal areas, sinter is not presently being deposited. Minor calcite is being deposited at the springs north of Borax Lake. The springs discharge from N to NEstriking, high-angle, basin-bounding faults along the base of Steens Mountain and Mickey Mountain and NE-striking intrabasinal faults south of Alvord Lake. The thermal waters are dilute sodium-bicarbonate waters with significant amounts of sulfate and chloride. Conservative element plots (B, F, and Li vs. Cl) indicate good correlation between Cl and the other conservative elements. These correlations could result from mixing of thermal water with a dilute cold water or fluid evolution due to increased fluid-rock interaction, evaporation, and steam loss due to boiling. The small variations in chloride concentrations of thermal fluids during the sampling period argues against mixing of thermal fluids with cold water. The geothermal system is a hot-water rather than a vapordominated system. The ỎD content of thermal fluids is similar to the ỎD content of local cold water wells, springs, basinal pore fluids at a depth of 4 to 5 m, and perennial streams. Similarities in ỎD values indicate recharge for geothermal fluids is precipitation from the Steens Mountain fault block. The Ỏ18 content of thermal fluids is shifted 2 to 3°/oo to the right of the world meteoric water line indicating fluid-rock interaction at elevated temperatures in the reservoir. Tritium contents indicate relatively long residence times and/or low-velocity circulation of meteoric water through basement rocks. Values range from 0 to 0.25 T.U. The application of two end-member models, which calculate fluid residence times, generate a minimum of 57 years and a maximum of greater than 10,000 years. Estimated reservoir temperatures based on cation and silica geothermometry are between 170 and 200°C. Oxygensulfate isotope geothermometer estimates indicate reservoir temperatures between 198 and 207' C for Borax Lake and Alvord Hot Springs. Mickey Springs and a flowing well northeast of Borax Lake yield temperature estimates of 168 and 150° C, respectively. These values indicate partial reequilibration of the isotopic system. The Ỏ13C contents of carbon dioxide and methane of gas discharges from the thermal areas are similar to geothermal fluids from other sites. The Ỏ13C of methane indicate "normal" geothermal methane for Alvord Hot Springs and Mickey Springs (-27.8 and -27.6, respectively). The Ỏ13C of CH4 for springs north of Borax Lake (-33.6) indicates a small amount of thermogenic methane may be contributed by thermal alteration of organics in basinal sediments. The Ỏ13C contents for C02 at Alvord Hot Springs and Borax Lake are within the range expected for atmospheric, fumarolic, or mantle derived C02 (-6.5 and -6.6, respectively). The Ỏ13C content of C02 from Mickey Springs is isotopically lighter than gas released from fumaroles or the mantle (-9.4). N2/Ar ratios for Mickey Springs and Borax Lake gases (39.2 and 40.8, respectively) indicate interaction with airsaturated ground water during flow through the the zone of aeration. Helium is enriched relative to Ar and N2 in gas discharges from Alvord Hot Springs, indicating longer fluid residence times and/or increased crustal interaction at high temperatures. Ratios of B/Cl indicate the fluid reservoir is hosted in volcanic rocks. The Li/Cs ratios for the Borax Lake thermal area are consistent with a reservoir located in rhyoli tic rocks. The 228Ra/226Ra content of Borax Lake thermal fluids (1.14 ± 0.13 dpm/kg) indicates interaction with volcanic rocks for Borax Lake. The 228Ra/226Ra content of thermal fluids from Alvord Hot Springs and Mickey Springs (0.38~0.02 and 0.17 ~ 0.09) are lower than those expected for volcanic rocks and may indicate local uranium accumulation in the reservoir or zones of upflow. The 87Sr / 86Sr values for thermal waters and stratigraphic uni ts indicate the fluid reservoir is located in volcanic rocks beneath Steens Basalt. Equilibration of fluids in these units argues for thermal water circulation depths of 2 to 2.5 km in the Borax Lake thermal area, greater than 3 km in the Alvord Hot Springs area and 1 to 2 km in the Mickey Springs area. Data presented in this study do not preclude a single large deep reservoir system discharging at these three thermal areas in the Alvord basin. Differences in the chemical and isotopic composition of discharge from the three thermal areas are produced during upf low from the reservoir. During upflow, thermal waters follow a complex pathway of vertical and lateral fractures which includes short residence times in shallow reservoirs before reaching the surface. Boiling, mixing with condensate, oxidation, mixing with 1-3% tritium-bearing, near-surface cold water, relative differences in flow rate and volume, and slow cooling without vigorous boiling are processes that modify fluid composition during upflow from the deep geothermal reservoir. Close