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• 1. [Article] Geology of the Columbia River Basalt in Silver Falls State Park, Oregon

  Silver Falls State Park is near the southern extent of the Columbia River Basalt Group as mapped in western Oregon. The flows in the park were identified as belonging to subdivisions of the Columbia River ...

  Citation × Citation Citation Abstract Copy Title: Geology of the Columbia River Basalt in Silver Falls State Park, Oregon Author: Norman, Elizabeth Storm Year: 1980 Silver Falls State Park is near the southern extent of the Columbia River Basalt Group as mapped in western Oregon. The flows in the park were identified as belonging to subdivisions of the Columbia River Basalt Group on the basis of physical characteristics and trace element geochemistry. The sequence of flows present is as follows: 3-4 flows of the Low-Mg chemical type of the Grande Ronde Basalt, 2 flows of the High-Mg chemical type of the Grande Ronde Basalt, 3 flows of the Frenchman Springs Member of the Wanapum Basalt, and one flow of anomolous geochemistry. The flows dip west to southwest two to three degrees on the limb of an open anticline. Two related trends are represented in the jointing pattern of the flows, N 20 W and N 70 E. A paleostream appearing to follow one of these trends eroded 90 m into the Low-Mg and High-Mg flows before its valley was obscured by the incursion of a Frenchman Springs flow. The possibility arises that this stream drainage may provide access to the coast via the coast range for the Frenchman Springs basalts. Title: Geology of the Columbia River Basalt in Silver Falls State Park, Oregon Author: Norman, Elizabeth Storm Year: 1980 Silver Falls State Park is near the southern extent of the Columbia River Basalt Group as mapped in western Oregon. The flows in the park were identified as belonging to subdivisions of the Columbia River Basalt Group on the basis of physical characteristics and trace element geochemistry. The sequence of flows present is as follows: 3-4 flows of the Low-Mg chemical type of the Grande Ronde Basalt, 2 flows of the High-Mg chemical type of the Grande Ronde Basalt, 3 flows of the Frenchman Springs Member of the Wanapum Basalt, and one flow of anomolous geochemistry. The flows dip west to southwest two to three degrees on the limb of an open anticline. Two related trends are represented in the jointing pattern of the flows, N 20 W and N 70 E. A paleostream appearing to follow one of these trends eroded 90 m into the Low-Mg and High-Mg flows before its valley was obscured by the incursion of a Frenchman Springs flow. The possibility arises that this stream drainage may provide access to the coast via the coast range for the Frenchman Springs basalts. Close

• 2. [Article] Potential Impacts of Formation Waters on the Integrity of Class H Cement and Reservoir Rock in Carbon (Co-)Sequestration Settings

  The focus of this research is to characterize the risk of carbon sequestration under downhole conditions with regards to wellbore cement integrity. The primary research objective was to understand the ...

  Citation × Citation Citation Abstract Copy Title: Potential Impacts of Formation Waters on the Integrity of Class H Cement and Reservoir Rock in Carbon (Co-)Sequestration Settings Author: Verba, Circe Year: 2013 The focus of this research is to characterize the risk of carbon sequestration under downhole conditions with regards to wellbore cement integrity. The primary research objective was to understand the geochemical interactions of simulated sequestration brines and wellbore cement. There are four key focuses of this study with regards to cement interaction: 1) Simulated brines saturated with Supercritical CO2 and CO2-O2; 2) Adjacent formation host rock under sequestration conditions; 3) Geochemical modeling using CHIM-XPT based on the experimental studies of points 1) and 2) above; 4) Geomechanical strength tests of CO2 exposed cements. First, the interaction of cement with supercritical CO2, CO2-saturated brines, and CO2-O2 mixtures at 50 °C, 85 °C, and 28.9 MPa was evaluated. Cement exposed to a lower salinity brine (1 M) had a larger alteration depth (1.25 mm) compared to cement exposed to a higher salinity brine (2.2 M) (0.836 mm). CO2-O2 exposed cements displayed alteration depths of 1.6 mm at 85 °C and 0.7 mm at 50 °C for 1 M. The cement exposed to the 2.17 M solution had an alteration extending 1.685 mm. The second focus studied the influence of adjacent formations and observed mineral trapping in the Grande Ronde Basalt-cement. Studies of Mt. Simon Sandstone-cement interaction provided evidence for high CO2 storage capacity. The third focus is geochemical modeling using CHIM-XPT. Pure CO2 saturated brines yielded a pH of 3.0 at 1 M and 3.85 at 2.17 M. The CO2-O2 gas run calculated a pH of 3.96 at 1 M and 3.85 at 2.17 M. The Pasco solution after exposure had a pH of 6.97 and an estimated dissolved 161 g of CO2 (g). The pH of the Illinois Basin brine and Mt. Simon sandstone [and cement paste] was 5.8 with an estimated 139 g of CO2 consumed. Lastly, geomechanical tests on CO2 exposed cements indicated that addition of oxygen or changes in temperature play a key role in compressive and tensile strength, decreasing strength by 20-35%. This research highlighted the importance of representing the in-situ wellbore environment when conducting laboratory experiments. This dissertation includes previously published and unpublished co-authored material. Title: Potential Impacts of Formation Waters on the Integrity of Class H Cement and Reservoir Rock in Carbon (Co-)Sequestration Settings Author: Verba, Circe Year: 2013 The focus of this research is to characterize the risk of carbon sequestration under downhole conditions with regards to wellbore cement integrity. The primary research objective was to understand the geochemical interactions of simulated sequestration brines and wellbore cement. There are four key focuses of this study with regards to cement interaction: 1) Simulated brines saturated with Supercritical CO2 and CO2-O2; 2) Adjacent formation host rock under sequestration conditions; 3) Geochemical modeling using CHIM-XPT based on the experimental studies of points 1) and 2) above; 4) Geomechanical strength tests of CO2 exposed cements. First, the interaction of cement with supercritical CO2, CO2-saturated brines, and CO2-O2 mixtures at 50 °C, 85 °C, and 28.9 MPa was evaluated. Cement exposed to a lower salinity brine (1 M) had a larger alteration depth (1.25 mm) compared to cement exposed to a higher salinity brine (2.2 M) (0.836 mm). CO2-O2 exposed cements displayed alteration depths of 1.6 mm at 85 °C and 0.7 mm at 50 °C for 1 M. The cement exposed to the 2.17 M solution had an alteration extending 1.685 mm. The second focus studied the influence of adjacent formations and observed mineral trapping in the Grande Ronde Basalt-cement. Studies of Mt. Simon Sandstone-cement interaction provided evidence for high CO2 storage capacity. The third focus is geochemical modeling using CHIM-XPT. Pure CO2 saturated brines yielded a pH of 3.0 at 1 M and 3.85 at 2.17 M. The CO2-O2 gas run calculated a pH of 3.96 at 1 M and 3.85 at 2.17 M. The Pasco solution after exposure had a pH of 6.97 and an estimated dissolved 161 g of CO2 (g). The pH of the Illinois Basin brine and Mt. Simon sandstone [and cement paste] was 5.8 with an estimated 139 g of CO2 consumed. Lastly, geomechanical tests on CO2 exposed cements indicated that addition of oxygen or changes in temperature play a key role in compressive and tensile strength, decreasing strength by 20-35%. This research highlighted the importance of representing the in-situ wellbore environment when conducting laboratory experiments. This dissertation includes previously published and unpublished co-authored material. Close