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• 1. [Article] The Production of Organic Nitrates in Portland Oregon and the Columbia River Gorge

  This work studied the production of aerosol-phase organic nitrates in both Portland and the Columbia River Gorge (CRG). Ozone and NOx species were investigated for correlation with organic nitrate aerosol, ...

  Citation × Citation Citation Abstract Copy Title: The Production of Organic Nitrates in Portland Oregon and the Columbia River Gorge Author: Neill, Holly Ann Year: 2013 This work studied the production of aerosol-phase organic nitrates in both Portland and the Columbia River Gorge (CRG). Ozone and NOx species were investigated for correlation with organic nitrate aerosol, as they function as precursors to the production of organic nitrates. These ambient gas-phase measurements were collected in the same locations as high-volume (Hi-Vol) filters samples, in an urban and rural gorge setting to investigate correlations at the origin of the pollution plume and downwind. A novel Soxhlet extraction method for Hi-Vol filters was developed based on literature and EPA standard methods. Analysis for nitrate production was done by segregating data based on times when the wind blew out of Portland and down the CRG versus times when flow was not westerly. Filters were then compared to ambient gas-phase measurements and derived NO3 radical production rates to look for trends. Wind direction had a strong influence on the concentrations of precursor molecules in the CRG. On days with a westerly wind direction into the gorge, concentrations of the measure aerosol organic nitrates were similar at both sides. This suggests some contribution of a broader regional production of organic nitrates. There was some correlation between the production rate of NO3 radicals and the measured organic nitrate aerosol, suggesting a role for NO3 + VOC production of organic nitrates that later partition to the aerosol phase. This information will better illuminate the fate of nitrogen downwind of pollution sources. The information will also help to create a better understanding of the way topography and meteorological conditions can influence the flow of pollution. Understanding the downwind oxidative chemistry that happens in the CRG would better support both pollution prevention and mitigation efforts. Title: The Production of Organic Nitrates in Portland Oregon and the Columbia River Gorge Author: Neill, Holly Ann Year: 2013 This work studied the production of aerosol-phase organic nitrates in both Portland and the Columbia River Gorge (CRG). Ozone and NOx species were investigated for correlation with organic nitrate aerosol, as they function as precursors to the production of organic nitrates. These ambient gas-phase measurements were collected in the same locations as high-volume (Hi-Vol) filters samples, in an urban and rural gorge setting to investigate correlations at the origin of the pollution plume and downwind. A novel Soxhlet extraction method for Hi-Vol filters was developed based on literature and EPA standard methods. Analysis for nitrate production was done by segregating data based on times when the wind blew out of Portland and down the CRG versus times when flow was not westerly. Filters were then compared to ambient gas-phase measurements and derived NO3 radical production rates to look for trends. Wind direction had a strong influence on the concentrations of precursor molecules in the CRG. On days with a westerly wind direction into the gorge, concentrations of the measure aerosol organic nitrates were similar at both sides. This suggests some contribution of a broader regional production of organic nitrates. There was some correlation between the production rate of NO3 radicals and the measured organic nitrate aerosol, suggesting a role for NO3 + VOC production of organic nitrates that later partition to the aerosol phase. This information will better illuminate the fate of nitrogen downwind of pollution sources. The information will also help to create a better understanding of the way topography and meteorological conditions can influence the flow of pollution. Understanding the downwind oxidative chemistry that happens in the CRG would better support both pollution prevention and mitigation efforts. Close

• 2. [Article] Effects of Runoff Sensitivity and Catchment Characteristics on Regional Actual Evapotranspiration Trends in the Conterminous US

  An understanding of the role of hydro-climatic and geographic regimes on regional actual evapotranspiration (AET) change is essential to improving our knowledge on predicting water availability in a changing ...

  Citation × Citation Citation Abstract Copy Title: Effects of Runoff Sensitivity and Catchment Characteristics on Regional Actual Evapotranspiration Trends in the Conterminous US Author: Jung, Il-Won, Chang, Heejun, Risley, John Year: 2013 An understanding of the role of hydro-climatic and geographic regimes on regional actual evapotranspiration (AET) change is essential to improving our knowledge on predicting water availability in a changing climate. This study investigates the relationship between AET change for a 60 year period (1951–2010) and the runoff sensitivity in 255 undisturbed catchments over the US. The runoff sensitivity to climate change is simply defined as the relative magnitude between runoff and precipitation changes with time. Runoff sensitivity can readily explain the conflicting directions of AET changes under similar precipitation change. Under increasing precipitation, AET decreases when runoff is increasing more rapidly than precipitation based on the water balance. Conversely, AET increases when runoff is decreasing more rapidly than precipitation. This result indicates that runoff sensitivity to climate change is a key factor for understanding regional water availability change at the catchment scale. In addition, a stepwise multiple regression analysis and a geographically weighted regression analysis show that the portion of evergreen forest and the mean elevation of a catchment may play a secondary role in the spatial pattern of the AET change, and the relative importance of such explanatory variables may change over space. Title: Effects of Runoff Sensitivity and Catchment Characteristics on Regional Actual Evapotranspiration Trends in the Conterminous US Author: Jung, Il-Won, Chang, Heejun, Risley, John Year: 2013 An understanding of the role of hydro-climatic and geographic regimes on regional actual evapotranspiration (AET) change is essential to improving our knowledge on predicting water availability in a changing climate. This study investigates the relationship between AET change for a 60 year period (1951–2010) and the runoff sensitivity in 255 undisturbed catchments over the US. The runoff sensitivity to climate change is simply defined as the relative magnitude between runoff and precipitation changes with time. Runoff sensitivity can readily explain the conflicting directions of AET changes under similar precipitation change. Under increasing precipitation, AET decreases when runoff is increasing more rapidly than precipitation based on the water balance. Conversely, AET increases when runoff is decreasing more rapidly than precipitation. This result indicates that runoff sensitivity to climate change is a key factor for understanding regional water availability change at the catchment scale. In addition, a stepwise multiple regression analysis and a geographically weighted regression analysis show that the portion of evergreen forest and the mean elevation of a catchment may play a secondary role in the spatial pattern of the AET change, and the relative importance of such explanatory variables may change over space. Close